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Solubility of Nitrogen in High Manganese Steel (HMnS) Melts: Interaction Parameter between Mn and N

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Abstract

Nitrogen solubility in Fe-Mn melts was measured using a N2 bubbling and sampling method at temperatures from 1823 K to 1923 K (1550 °C to 1650 °C) for manganese content to about 25 mass pct. The effect of temperature on the nitrogen solubility was well described based on the thermodynamic behavior of Fe-Mn system. Furthermore, the interaction parameter between Mn and N was evaluated as a function of temperature. The present results can be used in thermodynamic analyses of the formation of nitride compounds such as AlN or TiN in high manganese steel melts for example, transformation induced plasticity (TRIP) and twin induced plasticity (TWIP) aided steels as well as high Mn-N alloyed stainless steels.

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We would like to thank Prof. YOUN-BAE KANG, Graduate Institute of Ferrous Technology (GIFT), POSTECH, Pohang, Korea, for providing nitrogen analyses of the samples. Also, we would like to thank Prof. TAKAHIRO MIKI, Department of Metallurgy, Tohoku University, Sendai, Japan, for providing an old reference.

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Authors and Affiliations

  1. School of Materials Science and Engineering, University of Ulsan, Ulsan, 680-749, Korea

    Jae Hong Shin (Graduate Student) & Joo Hyun Park (Assistant Professor)

  2. Department of Material Science and Engineering, Korea University, Seoul, 136-713, Korea

    Joonho Lee (Associate Professor)

  3. Department of Materials Science and Engineering, Yonsei University, Seoul, 120-749, Korea

    Dong Joon Min (POSCO Professor and Head of Department)

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  1. Jae Hong Shin
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  2. Joonho Lee
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  3. Dong Joon Min
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  4. Joo Hyun Park
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Correspondence to Joo Hyun Park.

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Manuscript submitted: June 8, 2011.

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Shin, J.H., Lee, J., Min, D.J. et al. Solubility of Nitrogen in High Manganese Steel (HMnS) Melts: Interaction Parameter between Mn and N. Metall Mater Trans B 42, 1081–1085 (2011). https://doi.org/10.1007/s11663-011-9582-6

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