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Diffusion Coefficient of Tin(II) Methanesulfonate in Ionic Liquid and Methane Sulfonic Acid (MSA) Solvent

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Abstract

Voltammetry and chronoamperometry for the electrodeposition of tin from Tin(II) methane sulfonate mixed with ionic liquid and methane sulfonate acid at room temperature was studied. Cyclic voltammetry shows redox waves of Tin(II), which proves that the electrodeposition of tin from Tin(II) methane sulfonate is a diffusion-controlled process. The diffusion coefficient of Tin(II) ions in the solvent mixture showed good agreement from both voltammetry and chronoamperometry results. The diffusion coefficient of Tin(II) in the mixture was much smaller than in aqueous solution, and it depends on the anion of the ionic liquid.

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Authors and Affiliations

  1. Department of Chemistry, University of Malaya, Kuala Lumpur, 50603, Malaysia

    Kok Kee Yang (M.Sc. Student), M. R. Mahmoudian (PhD Student), Mehdi Ebadi (PhD Student) & Wan Jeffrey Basirun (Academic/Researcher)

  2. Department of Material Science and Engineering, Malaysia University of Science and Technology, 47301 Petaling Jaya, Selangor, Malaysia

    Hun Lee Koay (PhD Student)

Authors
  1. Kok Kee Yang
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  2. M. R. Mahmoudian
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  3. Mehdi Ebadi
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  4. Hun Lee Koay
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  5. Wan Jeffrey Basirun
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Correspondence to Wan Jeffrey Basirun.

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Manuscript submitted March 4, 2011.

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Yang, K.K., Mahmoudian, M.R., Ebadi, M. et al. Diffusion Coefficient of Tin(II) Methanesulfonate in Ionic Liquid and Methane Sulfonic Acid (MSA) Solvent. Metall Mater Trans B 42, 1274–1279 (2011). https://doi.org/10.1007/s11663-011-9560-z

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  • DOI: https://doi.org/10.1007/s11663-011-9560-z

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