Skip to main content
SpringerLink
Log in

Thermodynamic evaluation and optimization of the MnO-Al2O3 and MnO-Al2O3-SiO2 systems and applications to inclusion engineering

  • Published:
Metallurgical and Materials Transactions B Aims and scope Submit manuscript

Abstract

All available thermodynamic and phase-diagram data have been critically evaluated and optimized for the liquid-slag phase and for all solid phases at 1 bar pressure from 298 K to above the liquidus temperatures for the systems MnO-Al2O3 and MnO-Al2O3-SiO2, and a database of model parameters has been prepared. The modified quasichemical model was employed for the molten-slag phase. Calculations using the database were performed with applications to inclusion engineering for Mn/Si killed steel.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. www.factsage.com, Montreal, 2002.

  2. E. Jak, S. Degterov, P. Hayes, and A.D. Pelton: Can. Metall. Q., 1998, vol. 37, pp. 41–47.

    Article  CAS  Google Scholar 

  3. E. Jak, S. Degterov, P. Wu, P. Hayes, and A.D. Pelton: Metall. Mater. Trans. B, 1997, vol. 28B, pp. 1011–18.

    Article  CAS  Google Scholar 

  4. S. Degterov and A.D. Pelton: Metall. Mater. Trans. B, 1997, vol. 28B, pp. 235–42.

    Article  CAS  Google Scholar 

  5. S. Degterov and A.D. Pelton: J. Phase Equilibria, 1996, vol. 17, pp. 476–87.

    CAS  Google Scholar 

  6. S. Degterov and A.D. Pelton: J. Phase Equilibria, 1996, vol. 17, pp. 488–94.

    CAS  Google Scholar 

  7. G. Eriksson, P. Wu, M. Blander, and A.D. Pelton: Can. Metall. Q., 1994, vol. 33, pp. 13–22.

    CAS  Google Scholar 

  8. P. Wu, G. Eriksson, and A.D. Pelton: J. Am. Ceram. Soc., 1993, vol. 76, pp. 2065–75.

    Article  CAS  Google Scholar 

  9. P. Wu, G. Eriksson, and A.D. Pelton: J. Am. Ceram. Soc., 1993, pp. 2059–63.

  10. G. Eriksson and A.D. Pelton: Metall. Trans. B, 1993, vol. 24B, pp. 807–816.

    CAS  Google Scholar 

  11. G. Eriksson and A.D. Pelton: Metall. Trans. B, 1993, vol. 24B, pp. 795–805.

    CAS  Google Scholar 

  12. A.D. Pelton and M. Blander: Proc. 2nd Int. Symp. on Metallurgical Slags and Fluxes, TMS-AIME, Warrendale, PA, 1984, pp. 281–91.

    Google Scholar 

  13. A.D. Pelton and M. Blander: Metall. Trans. B, 1986, vol. 17B, pp. 805–15.

    CAS  Google Scholar 

  14. A.D. Pelton and P. Chartrand: Metall. Mater. Trans. A, 2001, vol. 32A, pp. 1355–60.

    Article  CAS  Google Scholar 

  15. A.D. Pelton, S.A. Degterov, G. Eriksson, C. Robelin, and Y. Dessureault: Metall. Mater. Trans. B, 2000, vol. 31B, pp. 651–60.

    Article  CAS  Google Scholar 

  16. K.T. Jacob: Can. Metall. Q., 1981, vol. 20, pp. 89–92.

    CAS  Google Scholar 

  17. W. Oelsen and G. Heynert: Arch. Eisenhuttenwes., 1955, vol. 26, pp. 567–75.

    CAS  Google Scholar 

  18. R. Hay, J. White, and A.B. McIntosh: J. West. Scot. Iron Steel Inst., 1934–35, vol. 42, pp. 99–104.

    Google Scholar 

  19. I.A. Novokhatskii, L.M. Lenev, A.A. Savinskaya, and A.V. Gorokh: Z. Neorg. Khim., 1966, vol. 11, pp. 427–28.

    CAS  Google Scholar 

  20. Y. Zhao, K. Morita, and N. Sano: Metall. Mater. Trans. B, 1995, vol. 26B, pp. 1013–17.

    CAS  Google Scholar 

  21. L.M. Lenev and I.A. Novokhatskii: Izv. Akad. Nauk. SSSR Metally, 1966, vol. 3, pp. 73–78.

    Google Scholar 

  22. S. Dimitrov, A. Weyl, and D. Janke: Steel Res., 1995, vol. 66, pp. 87–92.

    CAS  Google Scholar 

  23. C.K. Kim and A. McLean: Metall. Trans. B, 1979, vol. 10B, pp. 575–84.

    CAS  Google Scholar 

  24. M. Timucin and A. Muan: J. Am. Ceram. Soc., 1992, vol. 75, pp. 1399–406.

    Article  CAS  Google Scholar 

  25. I. Barin: Thermochemical Data of Pure Substances, VCH, Weinheim, Germany, 1989.

    Google Scholar 

  26. Thermicheskie Konstanty, Veshchestv (Thermal Constants of Substances), V.P. Glushko, ed., 1965, vol. 1, 1966, vol. 2, 1968, vol. 3, 1970, vol. 4, 1971, vol. 5, 1972, vol. 6 (1), 1973, vol. 6 (2), 1974, vol. 7, 1978, vol. 8, 1979, vol. 9, 1981, vol. 10; Akad. Nauk USSR, Viniti, Moscow.

  27. R.A. Sharma and F.D. Richardson: Trans. TMS-AIME, 1965, vol. 233, pp. 1586–92.

    CAS  Google Scholar 

  28. G. Eriksson, P. Wu, and A.D. Pelton: CALPHAD J., 1993, vol. 17, pp. 189–206.

    Article  CAS  Google Scholar 

  29. R.B. Snow: J. Am. Ceram. Soc., 1943, vol. 26, pp. 11–20.

    Article  CAS  Google Scholar 

  30. G. Roghani, E. Jak, and P. Hayes: Metall. Mater. Trans. B, 2002, vol. 33B, pp. 827–38.

    CAS  Google Scholar 

  31. R.G. Berman: J. Petrology, 1988, vol. 29, pp. 445–522.

    CAS  Google Scholar 

  32. T. Fujisawa and H. Sakao: Tetsu-to-Hagané, 1977, vol. 63, pp. 1504–11.

    CAS  Google Scholar 

  33. Sakao: Tetsu-to-Hagané, 1970, vol. 56, pp. S621-S624.

    Google Scholar 

  34. H. Ohta and H. Suito: Metall. Mater. Trans. B, 1996, vol. 27B, pp. 263–70.

    CAS  Google Scholar 

  35. Y.-B. Kang and H.-G. Lee: Pohang University of Science and Technology, Pohang, 2003, unpublished work.

  36. D.-H. Woo, Y.-B. Kang, and H.-G. Lee: Metall. Mater. Trans. B, 2002, vol. 33B, pp. 915–20.

    CAS  Google Scholar 

  37. I.-H. Jung, S.A. Decterov and A.D. Pelton: Metall. Mater. Trans. B, in press.

  38. T. Fujisawa and H. Sakao: Tetsu-to-Hagané, 1977, vol. 63, pp. 1494–503.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. the Department of Materials Science and Engineering, Pohang University of Science and Technology, Pohang, 790-784, Kyungbuk, Korea

    In-Ho Jung (Researcher) & Youn-Bae Kang (Researcher)

  2. the Centre de Recherche en Calcul Thermochimique, École Polytechnique de Montréal, PQ H3C 3A7, Montreal, Canada

    Sergei A. Decterov (Research Professor) & Arthur D. Pelton (Professor and Director)

Authors
  1. In-Ho Jung
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Youn-Bae Kang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Sergei A. Decterov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Arthur D. Pelton
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jung, IH., Kang, YB., Decterov, S.A. et al. Thermodynamic evaluation and optimization of the MnO-Al2O3 and MnO-Al2O3-SiO2 systems and applications to inclusion engineering. Metall Mater Trans B 35, 259–268 (2004). https://doi.org/10.1007/s11663-004-0027-3

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11663-004-0027-3

Keywords

Search

Navigation