Skip to main content
SpringerLink
Log in

Thermodynamics of surfaces and adsorption in the Fe-O and Fe-O-N systems at 1823 K

  • Published:
Metallurgical and Materials Transactions B Aims and scope Submit manuscript

Abstract

The present investigation calculates the surface tension and adsorption functions of the Fe-O and Fe-O-N melts at 1823 K using the modified form of Butler’s equations and the derived values of the surface interaction parameters of the systems. The calculated values are found to be in good agreement with those of the experimental data of the systems. The present analysis indicates a characteristic saturation behavior of oxygen in the Fe-O system at 1823 K, whereas a linear adsorption behavior is observed in the Fe-N system. An inverse relationship in the adsorption behavior, which exists between oxygen and nitrogen in the Fe-O-N system, is similar to that observed in our earlier study of the Fe-S-N system.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M. Inouye and T. Choh: Trans. Iron Steel Inst. Jpn., 1968, vol. 8, pp. 134–45.

    Google Scholar 

  2. R.J. Fruehan and L.J. Martonik: Metall. Trans. B, 1980, vol. 11B, pp. 615–21.

    CAS  Google Scholar 

  3. Y.K. Rao and H.G. Lee: Ironmaking and Steelmaking, 1985, vol. 12 (5), pp. 209–20.

    CAS  Google Scholar 

  4. T.P. Battle and R.D. Pehlke: Ironmaking and Steelmaking, 1986, vol. 13 (4), pp. 176–89.

    CAS  Google Scholar 

  5. J. Zhu and K. Mukai: Iron Steel Inst. Jpn., 1998, vol. 38 (3), pp. 220–28.

    CAS  Google Scholar 

  6. J.W. Hooijmans and G. Den Ouden: Welding J., 1992, pp. 377s–380s.

  7. J.A.V. Butler: Proc. R. Soc., 1932, vol. 135A, pp. 348–75.

    Google Scholar 

  8. J.P. Hajra and M. Divakar: Metall. Mater. Trans. B, 1996, vol. 27B, pp. 241–53.

    Article  CAS  Google Scholar 

  9. M. Divakar and J.P. Hajra: Steel Res., 1997, vol. 68 (10), pp. 417–23.

    CAS  Google Scholar 

  10. F.A. Halden and W.D. Kingery: J. Phys. Chem., 1955, vol. 59, pp. 557–59.

    Article  CAS  Google Scholar 

  11. P. Sahoo, T. DebRoy, and M.J. McNallan: Metall. Trans. B, 1988, vol. 19B, pp. 483–91.

    CAS  Google Scholar 

  12. D.R. Poirier, H. Yin, M. Suzuki, and T. Emi: Iron Steel Inst. Jpn., 1998, vol. 38 (3), pp. 229–38.

    CAS  Google Scholar 

  13. M. Divakar, J.P. Hajra, A. Jakobsson, and S. Seetharaman: Metall. Mater. Trans. B, 2000, vol. 31B, pp. 267–76.

    Article  CAS  Google Scholar 

  14. N. Takiuchi, T. Taniguchi, N. Shinozaki, and K. Mukai: J. Jpn. Inst. Met., 1991, vol. 55 (1), pp. 44–49.

    CAS  Google Scholar 

  15. J. Zhu and K. Mukai: Iron Steel Inst. Jpn. Int., 1998, vol. 38 (10), pp. 1039–44.

    CAS  Google Scholar 

  16. Van Tszin-tan, R.A. Karasev, and A.M. Samarin: Russ. Metall. Fuels, 1960, vol. 1, pp. 21–27.

    Google Scholar 

  17. K.M. Gupt, V.I. Yavoiski, A.F. Vishkaryov, and S.A. Blijnukov: Trans. Ind. Inst. Met., 1976, vol. 29 (4), pp. 286–91.

    CAS  Google Scholar 

  18. A.W. Cramb and I. Jimbo: Steel Res., 1989, vol. 60 (3), pp. 157–65.

    CAS  Google Scholar 

  19. P. Kozakevitch and G. Urbain: Mem. Sci. Rev. Metall., 1961, vol. 58 (12), pp. 517–34.

    CAS  Google Scholar 

  20. I. Jimbo and A.W. Cramb: Iron Steel. Inst. Jpn. Int., 1992, vol. 32 (1), pp. 26–35.

    CAS  Google Scholar 

  21. G.K. Sigworth and J.F. Elliott: Met. Sci., 1974, vol. 8, pp. 298–310.

    CAS  Google Scholar 

  22. J.P. Hajra and M. Divakar: Metall. Mater. Trans. B, 1999, vol. 30B, pp. 429–33.

    Article  CAS  Google Scholar 

  23. P. Kozakevitch and G. Urbain: Mem. Sci. Rev. Metall., 1961, vol. 58 (12), pp. 931–47.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. the Department of Metallurgical and Materials Engineering, The University of Alabama, 35487-0202, Tuscaloosa, AL

    D. Mantha (Postdoctoral Research Fellow)

  2. the Department of Metallurgy, Indian Institute of Science, 560 012, Bangalore, India

    J. P. Hajra (Professor)

Authors
  1. D. Mantha
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. P. Hajra
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mantha, D., Hajra, J.P. Thermodynamics of surfaces and adsorption in the Fe-O and Fe-O-N systems at 1823 K. Metall Mater Trans B 32, 423–427 (2001). https://doi.org/10.1007/s11663-001-0027-5

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11663-001-0027-5

Keywords

Search

Navigation