Abstract
G.R. Belton was the leader in developing our understanding of the kinetics of metallurgical reactions. Selected recent kinetic studies, based on this understanding and the application of the results to actual processes, are presented in this article. In particular, the rates of reaction of carbon and carbon in iron with CO2 and H2O gases and FeO in slag are reviewed and applied to the iron smelting process. In addition, our basic understanding of the kinetics of the nitrogen reaction with iron is reviewed, and the results are used in comprehensive models, which can predict the nitrogen content in steel as a function of operating variables in the basic oxygen furnace, electric arc furnace (EAF), and vacuum degassing.
Similar content being viewed by others
References
D.R. Sain and G.R. Belton: Metall. Trans. B, 1976, vol. 7B, p. 235; 1978, vol. 9B, pp. 403–07.
R.J. Fruehan and L.J. Martonik: Metall. Trans., 1974, vol. 5, pp. 1027–32.
A.W. Cramb and G.R. Belton: Metall. Trans. B, 1981, vol. 12B, pp. 699–704.
F.J. Mannion and R.J. Fruehan: Metall. Trans. B, 1989, vol. 20B, pp. 853–61.
R.J. Fruehan, G.R. Belton, F.J. Mannion, and Y. Sasaki: Metall. Trans. B, 1992, vol. 23B, pp. 45–51.
T. Nagasaka and R.J. Fruehan: Metall. Mater. Trans. B, 1994, vol. 25B, pp. 245–53.
S.R. Story and R.J. Fruehan: Metall. Mater. Trans. B, 2000, vol. 31B, pp. 43–54.
D.J. Min and R.J. Fruehan: Metall. Trans. B, 1992, vol. 23B, pp. 29–37.
C. Molloseau and R.J. Fruehan: Steelmaking Proc. ISS, 2000, vol. 83, Pittsburgh, PA, pp. 303–13.
B. Sarma, A.W. Cramb, and R.J. Fruehan: Metall. Mater. Trans. B, 1996, vol. 27B, pp. 717–30.
S.R. Story, B. Sarma, R.J. Fruehan, A.W. Cramb, and G.R. Belton: Metall. Mater. Trans. B, 1998, vol. 29B, pp. 929–32.
B. Sarma and R.J. Fruehan: Proc. Molten Slags, Fluxes and Salts 1997 Conf., Sydney, Australia, 1997, ISS, Warrendale PA.
A. Aukrust: “AISI Direct Steelmaking,” Final Technical Report, DOE/ID/12847-7, U.S. Department of Energy, Washington, DC, Aug. 1994.
R. Pehlke and J.F. Elliott: Trans. TMS-AIME, 1963, vol. 227, pp. 844–55.
M. Inouye and T. Choh: Trans. Iron Steel Inst. Jpn., 1998, vol. 8, pp. 134–45.
R.J. Fruehan and L.J. Martonik: Metall. Trans. B, 1980, vol. 11B, pp. 615–21.
M. Byrne and G.R. Belton: Metall. Trans. B, 1983, vol. 14B, pp. 441–49.
P.G. Glaws and R.J. Fruehan: Metall. Trans. B, 1985, vol. 16B, pp. 551–59.
P.C. Glaws and R.J. Fruehan: Trans. ISS, I&SM, 1987, Jan., p. 55.
P.C. Glaws and G.J.W. Kor: in Making Shaping and Treating of Steel, Steelmaking Volume, R.J. Fruehan, ed., AISE Foundation, 1998, Pittsburgh, PA.
D. Goldstein and R.J. Fruehan: Metall. Mater. Trans. B, 1999, vol. 30B, pp. 945–56.
D. Goldstein and R.J. Fruehan: Trans. ISS, I&SM, 1999, vol. 26 (2), pp. 49–61.
R.J. Fruehan, P.C. Glaws, and B. Lally: Trans. ISS-AIME, I&SM, 1987, Apr., pp. 31–36.
N. Bannenberg, D. Bergman, H. Wagner, and H. Gaye: Proc. 6th Int. Iron and Steel Congr., Nagoya, Japan, 1990, pp. 603–10.
H. Uljon and R.J. Fruehan: Trans. ISS-AIME, in press.
M. Sano and K. Mori: Trans. Steel Inst. Jpn., 1980, vol. 20, pp. 668–74 and 675–81.
Author information
Authors and Affiliations
Additional information
This article is based on a presentation made in the “Geoffrey Belton Memorial Symposium,” held in January 2000, in Sydney, Australia, under the joint sponsorship of ISS and TMS.
Rights and permissions
About this article
Cite this article
Fruehan, R.J., Goldstein, D., Sarma, B. et al. Recent advances in the fundamentals of the kinetics of steelmaking reactions. Metall Mater Trans B 31, 891–898 (2000). https://doi.org/10.1007/s11663-000-0064-5
Issue Date:
DOI: https://doi.org/10.1007/s11663-000-0064-5