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Modeling of Cu Precipitation in Fe–Cu and Fe–Cu–Mn Alloys Under Neutron and Electron Irradiation

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Abstract

Irradiation-induced formation of Cu-rich precipitates embrittles reactor pressure vessel steels. In the present work, a cluster dynamics model is used to model the precipitation of Cu-rich precipitates in Fe–Cu and Fe–Cu–Mn model alloys under neutron and electron irradiation at about 300 °C (573 K). The model includes radiation-enhanced diffusion and mobile Cu-rich clusters, which have been suggested to play important roles in Cu precipitation kinetics in Fe-based alloys. Precipitation at low temperatures is accelerated by radiation-enhanced diffusion, due to excess vacancies produced by displacement damages. Previous modeling work of thermal precipitation in Fe–Cu alloys at higher temperatures suggests that Cu clusters are mobile, and that this mobility must be accounted for to predict the observed precipitation kinetics. Here, the present work extends the mobile cluster model to treat precipitation in Fe–Cu and Fe–Cu–Mn alloys under neutron and electron irradiation. Comparison of the properly parameterized model predictions with the experimental observations shows that treating radiation-enhanced cluster mobility is necessary to predict Cu precipitation kinetics under irradiation. The developed precipitation model can reasonably describe the selected reliable experimental data. The model parameter determination for the physically based model includes extensive sensitivity studies, and suggests that the present approach still needs refinement to provide an accurate model that is fully consistent with the known microscopic measurements.

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Acknowledgments

This work was done at University of Wisconsin-Madison and has been supported by the US Department of Energy Office of Nuclear Energy's Light Water Reactor Sustainability Program, Materials Aging and Degradation Pathway. The author would like to express his cordial thanks to Professor Dane Morgan from University of Wisconsin-Madison for mentorship and Professor G. Robert Odette from University of California, Santa Barbara for helpful discussions related to this work.

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  1. School of Civil Aviation, Northwestern Polytechnical University, Xi’an, 710072, Shaanxi, P.R. China

    Senlin Cui

  2. Department of Materials Science and Engineering, University of Wisconsin-Madison, Madison, WI, 53706, USA

    Senlin Cui

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Cui, S. Modeling of Cu Precipitation in Fe–Cu and Fe–Cu–Mn Alloys Under Neutron and Electron Irradiation. Metall Mater Trans A (2024). https://doi.org/10.1007/s11661-024-07357-0

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