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Effect of Thermomechanical Treatment on Functional Properties of Biodegradable Fe-30Mn-5Si Shape Memory Alloy

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Abstract

The structure, martensitic γ ↔ ε transformation temperatures, Young’s modulus, mechanical properties, and electrochemical behavior of Fe-30Mn-5Si (wt pct) biodegradable shape memory alloy subjected to various thermomechanical treatments (TMT) comprising hot rolling or cold rolling with post-deformation annealing were characterized by optical microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, differential scanning calorimetry, tensile testing, open circuit potential, and polarization curves measurements in Hanks’ solution, as compared to reference heat treatment. The optimum combination of mechanical properties (low Young’s modulus, high tensile strength, and appropriate ductility) for biomechanical compatibility was obtained after TMT with hot rolling at 600 and 800 °C due to the formation of favorable dynamically polygonized and recrystallized structures and decrease in the γ↔ε transformation starting temperature down to the human body temperature. The TMT did not show a significant effect on the corrosion rate as compared to the appropriate corrosion rate after the reference heat treatment. It is concluded that the TMT with hot rolling at 600 or 800 °C, which provides an optimum combination of the required corrosion rate in the simulation body fluid with high biomechanical compatibility, can be considered a promising treatment of Fe-30Mn-5Si biodegradable alloy for bone implants.

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Acknowledgments

The authors are thankful to Prof. Vladimir Brailovski from the Ecole de Technologie Superieure (Montreal) for his assistance in carrying out the DSC and mechanical tests. The work was carried out with the financial support of the Russian Science Foundation (Project # 19-79-10270), and RFBR (Project # 18-08-01193 A) in part of electrochemical characterization method optimization.

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  1. National University of Science and Technology “MISIS”, 4 Leninskiy prospekt, Moscow, Russia, 119049

    S. Prokoshkin, Y. Pustov, Y. Zhukova, P. Kadirov, S. Dubinskiy, V. Sheremetyev & M. Karavaeva

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  1. S. Prokoshkin
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Manuscript submitted September 10 2020; accepted February 17, 2021.

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Prokoshkin, S., Pustov, Y., Zhukova, Y. et al. Effect of Thermomechanical Treatment on Functional Properties of Biodegradable Fe-30Mn-5Si Shape Memory Alloy. Metall Mater Trans A 52, 2024–2032 (2021). https://doi.org/10.1007/s11661-021-06217-5

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