Skip to main content
SpringerLink
Log in

Effect of Vacuum-Sintering Temperature on Magnetic and Mechanical Properties of TiC-TiN-Ni-Mo-C Cermets

  • Published:
Metallurgical and Materials Transactions A Aims and scope Submit manuscript

Abstract

The effect of vacuum-sintering temperature (Tvs), ranging from 1390 °C to 1470 °C, on magnetic and mechanical properties of TiC-10TiN-30Ni-6Mo-4C (mol pct) cermet was investigated in the present article. Room-temperature (RT) magnetization and maximum susceptibility decreased with increasing Tvs up to 1450 °C, and then increased. This was mainly attributed to the fact that Ti content in the Ni-based binder phase increased with increasing Tvs up to 1450 °C, suppressing ferromagnetism of the Ni matrix. RT ferromagnetism disappeared at Tvs ≥ 1430 °C. Transverse rupture strength (TRS) reached a peak value at Tvs = 1430 °C, and hardness did not significantly vary with Tvs.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. S.Y. Zhang: Mater. Sci. Eng. A, 1993, vol. 163, pp. 141–48.

    Article  Google Scholar 

  2. X.Y. Ren, Z.J. Peng, Y.B. Hu, C.B. Wang, Z.Q. Fu, W. Yue, L.H. Qi, and H.Z. Miao: Tribol. Int., 2013, vol. 66, pp. 35–43.

    Article  Google Scholar 

  3. J. Larsen-Basse: Mater. Sci. Eng. A, 1988, vol. 105, pp. 395–400.

    Article  Google Scholar 

  4. H. Kolaska: Wire, 1990, vol. 40, pp. 343–46.

    Google Scholar 

  5. G. Östberg, K. Buss, M. Christenesen, S. Norgren, H.-O. André, D. Mari, G. Wahnström, and I. Reineck: Int. J. Refract. Met. Hard Mater., 2006, vol. 24, pp. 135–44.

    Article  Google Scholar 

  6. P. Ettmayer, H. Kolaska, W. Lengauer, and K. Dreyer: Int. J. Refract. Met. Hard Mater., 1995, vol. 13, pp. 343–51.

    Article  Google Scholar 

  7. E.B. Clark and N. Roebuck: Int. J. Refract. Met. Hard Mater., 1992, vol. 11 pp. 23–33.

    Article  Google Scholar 

  8. Y. Iyori and H. Yokoo: “Cermet Alloys and Composite Mechanical Parts Made by Employing Them,” U.S. Patent No. 4,983,212, Jan. 1991.

  9. Q.Z. Xu, J. Zhao, X. Ai, W.Z. Qin, D.W. Wang, and W.M. Huang: J. Alloys Compd., 2015, vol. 649, pp. 885–90.

    Article  Google Scholar 

  10. X.B. Zhang, N. Liu, and C.L. Rong: Mater. Charact., 2008, vol. 59, pp. 1690–96.

    Article  Google Scholar 

  11. J. Jung and S. Kang: Acta Mater., 2004, vol. 52, pp. 1379–86.

    Article  Google Scholar 

  12. J. Zackrisson, H.-O. Andrén, and U. Rolander: Metall. Mater. Trans. A, 2001, vol. 32A, pp. 85–94.

    Article  Google Scholar 

  13. Z.H. Guo, J. Xiong, M. Yang, J. Wang, L. Sun, Y.M. Wu, J.Z. Chen, and S.J. Xiong: Int. J. Refract. Met. Hard Mater., 2009, vol. 27, pp. 781–83.

    Article  Google Scholar 

  14. J. Stöhr and H.C. Siegmann: Magnetism: From Fundamentals to Nanoscale Dynamics, Series in Solid-State Sciences, Springer, New York, NY, 2006, p. 483.

    Google Scholar 

  15. P. Elumalai, H.N. Vasan, M. Verelst, P. Lecante, V. Carles, and P. Tailhades: Mater. Res. Bull., 2002, vol. 37, pp. 353–63.

    Article  Google Scholar 

  16. M. Leonowicz, E. Macejewska, A.D. Pomogailo, and G.I. Dzhardimalieva: Mater. Sci. Forum., 2010, vols. 636–637, pp. 671–75.

    Article  Google Scholar 

  17. V.R. Dizaji, M. Rahmani, M.F. Sani, Z. Nemati, and J. Akbari: Int. J. Mach. Tool. Manuf., 2007, vol. 47, pp. 768–72.

    Article  Google Scholar 

  18. T. Viatte, S. Bolognini, T. Cutard, G. Feusier, D. Mari, and W. Benoit: Int. J. Refract. Met. Hard Mater., 1999, vol. 17, pp. 79–89.

    Article  Google Scholar 

  19. J.X. Yang, Z.Y. Xiao, X.H. Miao, X.B. Wang, and F. Yang: Int. J. Refract. Met. Hard Mater., 2015, vol. 52, pp. 6–11.

    Article  Google Scholar 

  20. S.K. Putatunda, J. Yang, and R.B. Gundlach: Mater. Des., 2005, vol. 26 pp. 534–44.

    Article  Google Scholar 

  21. Z.H. Huang: Cemented Carbide, 2002, vol. 19, pp. 26–28.

    Google Scholar 

  22. M. Zhang, Q.Q. Yang, W.H. Xiong, L.Y. Zheng, B. Huang, S. Chen, and Z.H. Yao: J. Alloys Compd., 2015, vol. 650, pp. 700–04.

    Article  Google Scholar 

  23. J.F. Shackelford, Y.H. Han, S. Kim, and S.H. Kwon: CRC Materials Science and Engineering Handbook, 4th ed., CRC Press, Boca Raton, 2016, pp. 15–23.

    Google Scholar 

  24. Q.Q. Yang, W.H. Xiong, G.P. Zhang, and B. Huang: J. Am. Ceram. Soc., 2015, vol. 98, pp. 1005–12.

    Article  Google Scholar 

  25. N. Liu, S. Chao, and X.M. Huang: J. Eur. Ceram. Soc., 2006, vol. 26, pp. 3861–70.

    Article  Google Scholar 

  26. J.K. Yang and H.C. Lee: Mater. Sci. Eng. A, 1996, vol. 209, pp. 213–17.

    Article  Google Scholar 

  27. W.M. Haynes: CRC Handbook of Chemistry and Physics, 95th ed., CRC Press, Boca Raton, 2015, pp. 4-77–4-96.

    Google Scholar 

  28. G.B. Dong, J. Xiong, M. Yang, Z.X. Guo, W.C. Wan, and C.H. Yi: J. Cent. South Univ., 2013, vol. 20, pp. 851–58.

    Article  Google Scholar 

  29. S. Chen, W.H. Xiong, Z.H. Yao, G.P. Zhang, X. Chen, B. Huang, and Q.Q. Yang: Int. J. Refract. Met. Hard Mater., 2014, vol. 47, pp. 139–44.

    Article  Google Scholar 

  30. P.T. Phong, D.H. Manh, L.C. Hoan, T.V. Ngai, N.X. Phuc, and In-Ja Lee: J. Alloys Compd., 2016, vol. 662, pp. 557–65.

    Article  Google Scholar 

  31. S. Uporov, S. Estemirova, V. Bykov, and V. Mitrofanov: Metall. Mater. Trans. A, 2016, vol. 47A, pp. 39–47.

    Article  Google Scholar 

  32. Q.Q. Yang, W.H. Xiong, S.Q. Zhou, M. Zhang, B. Huang, and S. Chen: Mater. Des., 2017, vol. 115, pp. 255–61.

    Article  Google Scholar 

  33. M.G. Gee, M.J. Reece, and B. Roebuck: J. Hard Mater., 1992, vol. 3, pp. 119–42.

    Google Scholar 

  34. F. Kajzar and G. Parette: Phys. Rev. B, 1979, vol. 20, pp. 2002–13.

    Article  Google Scholar 

  35. W.S. Chan, K. Mitsuoka, H. Miyajima, and S. Chikazumim: J. Phys. Soc. Jpn., 1980, vol. 48, pp. 822–29.

    Article  Google Scholar 

  36. E.R. Stover and J.Wulff: Trans. TMS-AIME, 1959, vol. 215, pp. 127–36.

    Google Scholar 

  37. V. Suresh Babu, A.S. Pavlovic, and M.S. Seehra: J. Appl. Phys., 1996, vol. 79, pp. 5230–32.

    Article  Google Scholar 

  38. F.A. Khan, M.A. Asgar, and P. Nordblad: J. Magn. Magn. Mater., 1997, vol. 174, pp. 121–26.

    Article  Google Scholar 

  39. V.S. Sarma, J. Eickemeyer, L. Schultz, and B. Holzapfel: Scripta Mater., 2004, vol. 50, pp. 953–57.

    Article  Google Scholar 

  40. H.P.J. Wijn: Magnetic Properties of Metals d-Elements, Alloys and Compounds, Springer, 1991, p. 24.

    Book  Google Scholar 

  41. S. Blundell: Magnetism in Condensed Matter, Oxford University Press, New York, 2001, pp. 145–84.

    Google Scholar 

  42. H.W. Xiong, Y.X. Wu, Z.Y. Li, X.P. Gan, K.C. Zhou, and L.Y. Chai: Ceram. Int., 2018, vol. 44, pp. 805–13.

    Article  Google Scholar 

  43. N. Liu, Y.D. Xu, H. Li, G.H. Li, and L.D. Zhang: J. Eur. Ceram. Soc., 2002, vol. 22, pp. 3861–70.

    Google Scholar 

  44. Q.Q. Yang, W.H. Xiong, S.Q. Li, and L. Jun: J. Alloys Compd., 2011, vol. 509, pp. 68–72.

    Google Scholar 

  45. Y. Zheng, M. You, W.H. Xiong, W.J. Liu, and S.X. Wang: Mater. Chem. Phys., 2003, vol. 82, pp. 877–81.

    Article  Google Scholar 

  46. Z.M. Shi, D.Y. Zhang, S. Chen, and T.L. Wang: J. Alloys Compd., 2013, vol. 568, pp. 68–72.

    Article  Google Scholar 

Download references

Acknowledgments

The present work was financially supported by the Innovative Team Project of Ministry of Education of China (No. IRT1244) and the Major Innovation Program of Hubei Province of China (No. 2016AAA067), and the project was supported by the State Key Laboratory of Powder Metallurgy, Central South University. The authors thank the Analytical and Testing Center, Huazhong University of Science and Technology, for providing the experimental facilities.

Author information

Authors and Affiliations

  1. State Key Laboratory of Material Processing and Die and Mould Technology, Huazhong University of Science and Technology, Wuhan, 430074, P.R. China

    Man Zhang, Qingqing Yang, Weihao Xiong, Shiquan Zhou, Shengqing Wang, Haifeng Luo & Linji Ruan

  2. State Key Laboratory of Powder Metallurgy, Central South University, Changsha, 410083, P.R. China

    Qingqing Yang

Authors
  1. Man Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Qingqing Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Weihao Xiong
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Shiquan Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Shengqing Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Haifeng Luo
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Linji Ruan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Qingqing Yang.

Additional information

Manuscript submitted April 22, 2017.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhang, M., Yang, Q., Xiong, W. et al. Effect of Vacuum-Sintering Temperature on Magnetic and Mechanical Properties of TiC-TiN-Ni-Mo-C Cermets. Metall Mater Trans A 49, 3550–3555 (2018). https://doi.org/10.1007/s11661-018-4659-3

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11661-018-4659-3

Search

Navigation