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Microstructural Evolution of the Interdiffusion Zone between U-9 Wt Pct Mo Fuel Alloy and Zr-1 Wt Pct Nb Cladding Alloy Upon Annealing

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Abstract

Diffusion couple formed between U-9 wt pct Mo and Zr-1 wt pct Nb alloys, proposed as fuel and clad materials, respectively, in nuclear research reactors, was annealed to investigate the microstructural evolution of the interdiffusion zone (IZ) as a function of temperature. A layered-type IZ microstructure was observed, the mechanism of development of which was elucidated. Mo2Zr phase, present as dispersoids, in the U-rich part of the as-bonded IZ evolved into a continuous layer and into a “massive” morphology upon annealing. The discontinuous precipitation reaction in the matrix adjoining the Mo2Zr phase, instigated by Mo depletion, generated lamellae of α-U phase within the γ-U(Mo,Zr) matrix. Zr-rich α-Zr(U) precipitates were observed in U-rich U-Mo-Zr matrix in the IZ next to the U-9Mo base material due to the clustering tendency of the matrix phase. The IZ next to Zr-1Nb base material comprised a “basket weave” microstructure of α-Zr laths with β-Zr(Nb,U) interlath boundaries, wherein an omega like transformation of the latter to δ-UZr2 was also noticed. The growth rates of the IZ were orders of magnitude lower when compared with the ones reported between the compositionally similar U-10 wt pct Mo alloy and the presently used Al or Al-Si cladding alloys.

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Acknowledgments

The authors are thankful to the Nuclear Fuel Complex (Hyderabad, India) for providing the Zr-1Nb material used in this work.

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Authors and Affiliations

  1. Mechanical Metallurgy Division, Bhabha Atomic Research Centre, Trombay, Mumbai, 400 085, India

    S. Neogy & D. Srivastava

  2. Materials Science Division, Bhabha Atomic Research Centre, Trombay, Mumbai, 400 085, India

    A. Laik & G. K. Dey

  3. Atomic Fuels Division, Bhabha Atomic Research Centre, Trombay, Mumbai, 400 085, India

    M. T. Saify & S. K. Jha

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  1. S. Neogy
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Manuscript submitted October 1, 2016.

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Neogy, S., Laik, A., Saify, M.T. et al. Microstructural Evolution of the Interdiffusion Zone between U-9 Wt Pct Mo Fuel Alloy and Zr-1 Wt Pct Nb Cladding Alloy Upon Annealing. Metall Mater Trans A 48, 2819–2833 (2017). https://doi.org/10.1007/s11661-017-4033-x

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