Abstract
The effect of Nb and C additions on the phase composition, microstructure, and creep resistance of Fe3Al-type alloys is investigated. Two alloys, which contained (at. pct) (i) 27.6 Al, 1.15 Nb and 0.19 C (Fe balance) and (ii) 27.1 Al, 1.11 Nb, and 0.76 C (Fe balance), were studied in a temperature range from 873 K to 1073 K (600 °C to 800 °C). The carbide in both alloys was identified as Nb6C5. The creep data can be rationalized by introducing a threshold stress, below which, the creep rate is negligible. The threshold stress and an effective stress exponent were found simultaneously by a numerical method. Using the obtained values of the threshold stress, the activation energy of creep was determined to be 328 kJ/mol. The effective stress exponent varied from 2.0 to 3.1. A breakdown of power-law behavior was observed at higher stresses. The transition occurred at the normalized creep rate of \( \dot{\varepsilon }/D = 10^{13} \,{\text{m}}^{ - 2} \), which agrees with the rule suggested by Sherby and Burke and the diffusion coefficient D corresponding to the diffusion of Al in Fe-Al.
Similar content being viewed by others
References
N.S. Stoloff: Mater. Sci. Eng. A, 1998, vol. 258, pp. 1-14.
F. Stein, A. Schneider and G. Frommeyer: Intermetallics. 2003, vol. 11, pp. 71-82.
L. Anthony and B. Fultz: Acta Metall. Mater., 1995, vol. 43, pp. 3885-3891.
M. Palm: J. Alloys Compd., 2009, vol. 475, pp. 173-177.
R. Balasubramaniam: J. Alloys Compd., 1997, vol. 253–254, pp. 148-51.
C.G. McKamey, P.J. Maziasz and J.W. Jones: J. Mater. Res., 1992, vol. 7, pp. 2089-2106.
C.G. McKamey, P.J. Maziasz, G.M. Goodwin and T. Zacharia: Mater. Sci. Eng. A, 1994, vol. 174, pp. 59-70.
C.G. McKamey and P.J. Maziasz: Intermetallics, 1998, vol. 6, pp. 303-314.
D.G. Morris, M.A. Muñoz-Morris and C. Baudin: Acta Mater., 2004, vol. 52, pp. 2827-2836.
D.G. Morris, M.A. Muñoz-Morris, L.M. Requejo and C. Baudin: Intermetallics, 2006, vol. 14, pp. 1204-1207.
D.G. Morris, L.M. Requejo and M.A. Muñoz-Morris: Scripta Mater., 2006, vol. 54, pp. 393-397.
D.G. Morris and M.A. Muñoz-Morris: Mater. Sci. Eng. A, 2012, vol. 552, pp. 134-144.
R.G. Baligidad: J. Mater. Sci., 2004, vol. 39, pp. 5599-5602.
R.G. Baligidad: Mat. Sci. Eng. A, 2004, vol. 368, pp. 131-138.
X.Q. Yu and Y.S. Sun: J. Mater. Sci. Lett., 2001, vol. 20, pp. 1221-1223.
Z.H. Zhang, Y.S. Sun and J. Guo: Scripta Metall. Mater., 1995, vol. 33, pp. 2013-2017.
S. Milenkovic and M. Palm: Intermetallics, 2008, vol. 16, 1212-1218.
L. Falat, A. Schneider, G. Sauthoff and G. Frommeyer: Intermetallics, 2005, vol. 13, pp. 1256-62.
F. Dobeš: Key Eng. Mater., 2011, vol. 465, pp. 443-446.
F. Dobeš: Acta Metal. Slovaca, 2010, vol. 16, pp. 223-228.
D. Connetable, J. Lacaze, P. Maugis and B. Sundman: Computer Coupling of Phase Diagrams and Thermochemistry, 2008, vol. 32, pp. 361–370.
F. Stein and M. Palm: Int. J. Mater. Res., 2007, vol. 98, pp. 580-588.
T.R. Bieler and A.K. Mukherjee: Mater. Sci. Eng. A, 1990, vol. 128, pp. 171-182.
F.A. Mohamed, K.T. Park and E.J. Lavernia: Mater. Sci.Eng. A, 1992, vol. 150, pp. 21-35.
R.S. Mishra, T.R. Bieler and A.K. Mukherjee: Acta Metall. Mater., 1995, vol. 43, pp. 877-891.
K.-T. Park, E.J. Lavernia and F.A. Mohamed: Acta Metall. Mater., 1990, vol. 38, pp. 2149-2159.
G. Gonzáles-Doncel and O.D. Sherby: Acta Metall. Mater., 1993, vol. 41, pp. 2797-2805.
J. Čadek, H. Oikawa and V. Šustek: Mater. Sci. Eng. A, 1995, vol. 190. pp. 9-23.
Y. Li and T.G. Langdon: Acta Mater., 1998, vol. 46, pp. 3937-3948.
A. Arieli and A.K. Mukherjee: Creep and Fracture of Engineering Materials and Structures, B. Wilshire and D.R.J. Owen, eds., Pineridge Press, Swansea, 1981, pp. 97–111.
O.D. Sherby and P.M. Burke: Prog. Mater. Sci., 1967, vol. 13, pp. 325-390.
M. Eggersmann and H. Mehrer: Phil. Mag. A, 2000, vol. A80, pp. 1219-1244.
L.N. Larikov, V.V. Geichenko, and V.M. Falchenko: Diffusion Processes in Ordered Alloys, Amerind Publishing Co, New Delhi, 1981.
D.G. Morris, M.A. Muñoz-Morris and L.M. Requejo: Acta Mater., 2006, vol. 54, pp. 2335-2341.
U. Reimann and G. Sauthoff: Intermetallics, 1999, vol. 7, pp. 437-445.
A. Schneider, L. Falat, G. Sauthoff and G. Frommeyer: Intermetallics, 2003, vol. 11, pp. 443-450.
Acknowledgments
The paper is based on work supported by the Grant Agency of the Czech Republic within the Project 108/12/1452.
Author information
Authors and Affiliations
Corresponding author
Additional information
Manuscript submitted August 5, 2014.
Rights and permissions
About this article
Cite this article
Dobeš, F., Kratochvíl, P., Pešička, J. et al. Microstructure and Creep Behavior of Fe-27Al-1Nb Alloys with Added Carbon. Metall Mater Trans A 46, 1580–1587 (2015). https://doi.org/10.1007/s11661-015-2756-0
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11661-015-2756-0