Abstract
Alumina composites incorporating with 0, 5, 10 15, 20, and 25 vol pct of TiC were consolidated by the spark plasma sintering at 1673 K (1400 °C). The effects of increasing TiC compositions on electrical and mechanical properties of the composites were investigated at room temperature. The dc electrical conductivity behavior demonstrates a transition from insulator to conductor around 12.5 vol pct of TiC in the framework of percolation theory. The conductivity attains a maximum value of ≈230 S/m at 25 vol pct of TiC sufficient to machine the composite by electro discharging machining. The Vickers hardness and fracture toughness of the composites increase with the addition of TiC vol pct, whereas elastic modulus decreases. The results indicate that crack deflection, crack bridging, and crack branching by the TiC particles are responsible for the significantly improved fracture toughness of the composites.
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R. M. Erb, R. Libanori, N. Rothfuchs, A. R. Studart, Science 2012, 335, 199–204.
W. Acchar, C.R.F.D. Camara, C.A.A. Cairo, and M. Filgueira: Mater. Res., 2012, vol. 15, pp. 821–24.
C.-H. Lee, H.-H. Lu, C.-A. Wang, P. K. Nayak, J.-L. Huang, J. Am. Ceram. Soc. 2011, 94, 959–67.
A. Krell, P. Blank, L. M. Berger, V. Richter, Am. Ceram. Soc. Bull. 1999, 78, 65–73.
R. Paluri and S. Ingole: JOM, 2011, vol. 63, pp. 77–83.
E. Medvedovski, Ceram. Int. 2006, 32, 369–75.
E. Refugio-García, D. Hernández-Silva, E. Terrés-Rojas, J. A. Rodríguez-García, E. Rocha-Rangel, Mater. Res. 2012, 15, 898–902.
J. R. Martinelli, F. F. Sene, Ceram. Int. 2000, 26, 325–35.
K. Lozano, L. Espinoza, K. Hernandez, A. R. Adhikari, G. Radhakrishnan, P. M. Adams, J. Appl. Phys. 2009, 105, 103511.
F. Calignano, L. Denti, E. Bassoli, A. Gatto, L. Iuliano, Int J Adv Manuf Technol 2013, 66, 1757–68.
C. G. Raptis, A. Patsidis, G. C. Psarras, EXPRESS POLYMER LETTERS 2010, 4, 234–43.
L. Tsetseris, S. T. Pantelides, Acta Mater. 2008, 56, 2864–71.
E. D. Whitney, P. N. Vaidyanathan, Am. Ceram. Soc. Bull. 1988, 67, 943–1072.
T. Nagano, H. Kato, F. Wakai, J. Am. Ceram. Soc. 1991, 74, 2258–62.
K. F. Cai, D. S. McLachlan, N. Axen, R. Manyatsa, Ceram. Int. 2002, 28, 217–22.
J. Gong, Z. Zhao, H. Miao, Z. Guan, Scr. Mater. 2000, 43, 27–31.
R. P. Wahi, B. Ilschner, J Mater Sci 1980, 15, 875–85.
Y.-W. Kim, J.-G. Lee, J. Am. Ceram. Soc. 1989, 72, 1333–37.
M. P. Borom, and M. Lee, Advanced Ceramic Materials 1986, 1, 335–40.
Y. Zhang, L. Wang, W. Jiang, G. Bai, and L. Chen: Mater. Trans., 2005, vol. 46, pp. 2015–19.
A. Goldstein, A. Singurindi, J. Am. Ceram. Soc. 2000, 83, 1530–32.
D. S. Perera, M. Tokita, S. Moricca, J. Eur. Ceram. Soc. 1998, 18, 401–04.
L. Gao, J. S. Hong, H. Miyamoto, S. D. D. L. Torre, J. Eur. Ceram. Soc. 2000, 20, 2149–52.
N. Tamari, I. Kondoh, T. Tanaka, N. Tokunaga, M. Kawahara, M. Tokita, K. Tezuka, T. Yamamoto, J. Ceram. Soc. Jpn. 1997, 105, 911–14.
G. R. Anstis, P. Chantikul, B. R. Lawn, D. B. Marshall, J. Am. Ceram. Soc. 1981, 64, 533–38.
A. Bellosi, G. De Portu, S. Guicciardi, J. Eur. Ceram. Soc. 1992, 10, 307–15.
D. Stauffer, A. Aharony, Introduction To Percolation Theory, Taylor & Francis, London 1994.
I. Webman, J. Jortner, M. H. Cohen, Physical Review B 1975, 11, 2885–92.
S. Harvey, Z. Richard, The Journal of Chemical Physics 1970, 53, 3759–61.
U. Abdurakhmanov, S. Sharipov, Y. Rakhimova, M. Karabaeva, M. Baydjanov, J. Am. Ceram. Soc. 2006, 89, 2946–48.
K. S. Deepa, S. K. Nisha, P. Parameswaran, M. T. Sebastian, J. James, Appl. Phys. Lett. 2009, 94, 142902.
I. BALBERG, D. AZULAY, D. TOKER, O. MILLO, International Journal of Modern Physics B 2004, 18, 2091–121.
Y. M. Luo, S. Q. Li, J. Chen, R. G. Wang, J. Q. Li, W. Pan, J. Am. Ceram. Soc. 2002, 85, 3099–101.
S. Ping: Phys. Rev. B, 1980, vol. 21, pp. 2180–95.
B. E. Kilbride, J. N. Coleman, J. Fraysse, P. Fournet, M. Cadek, A. Drury, S. Hutzler, S. Roth, W. J. Blau, J. Appl. Phys. 2002, 92, 4024–30.
S. Lopez-Esteban, C. F. Gutierrez-Gonzalez, G. Mata-Osoro, C. Pecharroman, L. A. Diaz, R. Torrecillas, J. S. Moya, Scr. Mater. 2010, 63, 219–22.
W. D. Kingery, H. K. Bowen, D. R. Uhlmann, Introduction to ceramics, Wiley, 1976.
G. H. Li, Z. X. Hu, L. D. Zhang, Z. R. Zhang, J. Mater. Sci. Lett. 1998, 17, 1185–86.
R.-x. Shi, J. Li, Y.-s. Yin, H.-y. Ge, Materials Science and Engineering: A 2011, 528, 5341–47.
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This research was supported by the Research Center, College of Engineering King Saud University.
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Manuscript submitted March 20, 2014.
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Ahmad, K., Pan, W. Enhanced Electrical and Mechanical Properties of Alumina-Based TiC Composites by Spark Plasma Sintering. Metall Mater Trans A 45, 6271–6276 (2014). https://doi.org/10.1007/s11661-014-2550-4
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DOI: https://doi.org/10.1007/s11661-014-2550-4