Abstract
A medium-carbon vanadium microalloyed steel (38MnSiVS5) with three different aluminum levels (0.006, 0.020, and 0.03 wt pct) was used to examine the interaction of vanadium, aluminum, and nitrogen during the heating and cooling cycle for forging. The thermal cycle was simulated using a Gleeble® 1500. Hold times varied from 5 to 45 minutes and temperature varied from 1323 K to 1523 K (1050 °C to 1250 °C). Thermal simulation specimens and as-received material were characterized by quantitative metallography, hardness, and chemical analysis of electrolytically extracted precipitates. The hardness was observed to be relatively constant for all aluminum levels after all thermal simulations at and above 1423 K (1150 °C). Hardness, pearlite fraction, and austenite grain size decreased with increasing aluminum content at the two lowest temperatures examined, which were 1323 K and 1373 K (1050 °C and 1100 °C). The amount of vanadium precipitated in the lowest aluminum steel was very consistent, approximately 70 pct, for the thermal simulations. The amount of precipitated vanadium decreased with increasing amount of aluminum nitride for the 0.03 wt pct Al level.
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G. Krauss, Steels: Processing, Structure, and Performance, Materials Park, OH:ASM International, 2005.
C.J. Van Tyne: in ASM Handbook Volume 15: Metalworking: Bulk Forming, S.L. Semiatin, ed., ASM International, Materials Park, OH, 2005, pp. 241–60.
W. Morrison: The Use of Vanadium in Steel, Guilin, China, 2000, pp. 25–35.
T. Gladman, The Physical Metallurgy of Microalloyed Steels, London, UK: Institute of Materials, 1997.
D. Naylor: Materials Science Forum, vol. 284–286, 1998, pp. 83–94.
M.D. Head, ed.: Bar Steels: Steel Products Manual, Association for Iron and Steel Technology, Warrendale, PA, 2010.
E.T. Turkdogan, “Causes and Effects of Nitride and Carbonitride Precipitation During Continuous Casting,” Iron & Steelmaker, vol. 16, no. 5, May 1989, pp. 61-75.
T.N. Baker, “Processes, Microstructure and Properties of Vanadium Microalloyed Steels,” Materials Science and Technology, vol. 25, 2009, pp. 1083-1107.
A. DeArdo, M. Hua, K. Cho, and C. Garcia, “On Strength of Microalloyed Steels: An Interpretive Review,” Materials Science and Technology, vol. 25, 2009, pp. 1074–1082.
T. Gladman, Grain Size Control, London, UK: Maney Publishing, 2004.
J.N. Cordea and R.E. Hook, “Recrystallization Behavior in Deformed Austenite of High Strength Low Alloy (HSLA) Steels,” Metall. Trans., vol. 1, 1970, pp. 111-118.
F. Wlison and T. Gladman, “Aluminum Nitride in Steel,” International Materials Reviews, vol. 33, 1988, pp. 221-286.
M. Sennour and C. Esnouf, “Contribution of Advanced Microscopy Techniques to Nano-Precipitates Characterization: Case of AlN Precipitation in Low-Carbon Steel,” ActaMaterialia, vol. 51, 2003, pp. 943-957.
H.O. Pierson, Handbook of Refractory Carbides and Nitrides, Westwood, NJ: Noyes Publications, 1996.
B. Engl and E.J. Drewes: in Technology of Continuously Annealed Cold-Rolled Sheet Steel, R. Pradhan, eds., 1985, pp. 17–18.
K. Ushioda, H.G. Suzuki, H. Komatsu, and K. Esaka, “Influence of Sulfur on AIN Precipitation During Cooling after Solidification and Resulting Hot Shortness in Low Carbon Steel,” The Journal of the Japan Institute of Metals, vol. 59, 1995, pp. 373–380.
L.D. Frawley, R. Priestner, and P.D. Hodgson: THERMEC’97: International Conference on Thermomechanical Processing of Steels and Other Materials, 1997, vol. 2, pp. 2169–75.
C.W. Siyasiya and W.E. Stumpf, “The Influence of Sulphur Content on the Static Recrystallisation of Cold Worked Low Carbon Aluminium-killed Strip Steels,” Materials Science and Engineering: A, vol. 494, 2008, pp. 188-195.
R.E. Reed-Hill and R. Abbaschian, Physical Metallurgy Principles, Boston, MA: PWS Publishing Company, 1994.
F.B. Pickering: Mater. Sci. Eng., 1992, vol. 7.
S. Zajac, “Precipitation of MicroalloyCarbo-nitrides Prior, During, and After Austenite/Ferrite Transformation,” Materials Science Forum, vol. 500-501, 2005, pp. 75–86.
S. Zajac, T. Siwecki, W.B. Hutchinson, and R. Lagneborg, “Strengthening Mechanisms in Vanadium Microalloyed Steels Intended for Long Products,” ISIJ International, vol. 38, 1998, pp. 1130-1139.
X. Li, L. Zhao, X. Wang, and Y. Zhao, “Precipitation and Hetero-nucleation Effect of V(C,N) in V-microalloyed Steel,” Journal of Wuhan University of Technology–Materials Science Edition, vol. 23, 2008, pp. 844-849.
S. Zajac, R. Lagneborg, and T. Siwecki: Microalloying ‘95, Iron and Steel Society, 1995, pp. 11–14.
R. Lagneborg and S. Zajac, “A Model for Interphase Precipitation in V-microalloyed Structural Steels,” Metallurgical and Materials Transactions A, vol. 32A, 2001, pp. 39–50.
T. Ochi, T. Takahashi, and H. Takada: 30th Mechanical Working and Steel Processing Conference, vol. 16, 1989, pp. 23–26.
F. Ishikawa, T. Takahashi, and T. Ochi, “Intragranular Ferrite Nucleation in Medium-Carbon Vanadium Steels,” Metallurgical and Materials Transactions A, vol. 25A, 1994, pp. 929–936.
Y. Sawada, R.P. Foley, S.W. Thompson, and G. Krauss: 35th Mechanical Working and Steel Processing Conference, vol. 31, 1993, pp. 263–286.
J.A. Garrison, J.G. Speer, S.W. Thompson, R.J. Glodowski, and K.P Williams: Iron & Steel Technology, 2006, vol. 3, pp. 43–51.
Y. Du, R. Wenzel, and R. Schmid-Fetzer, “Thermodynamic Analysis of Reactions in the Al-N-Ta and Al-N-V Systems,” Calphad, vol. 22, 1998, pp. 43-58.
R. Radis and E. Kozeschnik: Materials Science Forum, Vol. Advanced Materials Forum V, 2010, pp. 605–11.
R. Radis and E. Kozeschnik, “Kinetics of AlN Precipitation in Microalloyed Steel,” Modeling and Simulation in Materials Science and Engineering, vol. 18, no. 5, Jul. 2010, pp. 1-16.
R. Radis and E. Kozeschnik, “Concurrent Precipitation of AlN and VN in Microalloyed Steel,” Steel Research International, vol. 81, 2010, pp. 681-685.
R.E. Haimbaugh, Practical Induction Heat Treating, Materials Park, OH: ASM International, 2001.
H. Chandler, ed.: Heat Treater’s Guide: Practices and Procedures for Irons and Steels, ASM International, Materials Park, OH, 1995.
R.L. Higginson and C.M. Sellars, Worked Examples in Quantitative Metallography, London, UK:Maney Publishing, 2003.
F. Kurosawa, I. Tanaka, K. Sato, and T. Otsuki, “Simultaneous Determination of Metallic Elements in Precipitates and Inclusions Extracted from Steel by Inductively Coupled Plasma-Atomic Emission Spectrometry,” SpectrochimicaActa Part B: Atomic Spectroscopy, vol. 36, 1981, pp. 727-733.
A. Rivas, D. Matlock, and J. Speer, “Quantitative Analysis of Nb in Solution in a Microalloyed Carburizing Steel by Electrochemical Etching,” Materials Characterization, vol. 59, 2008, pp. 571-577.
W. Ozgowicz, A. Kurc, and G. Nawrat, “Identification of Precipitations in Anodically Dissolved High-Strength Microalloyed Weldox Steels,” Archives of Materials Science, vol. 31, 2008, pp. 95–100.
J. Lu, J.B. Wiskel, O. Omotoso, H. Henein, and D. G. Ivey, “Matrix Dissolution Techniques Applied to Extract and Quantify Precipitates from a Microalloyed Steel,” Metallurgical and Materials Transactions A, vol. 42A, 2011, pp. 1767-1784.
K. Poorhaydari and D.G. Ivey, “Precipitate Volume Fraction Estimation in High Strength Microalloyed Steels,” Canadian Metallurgical Quarterly, vol. 48, 2009, pp. 115-122.
K. Poorhaydari and D. G. Ivey, “Microstructural Examination of a Grade 100 Microalloyed Steel and Correlation with Yield Strength,” Canadian Metallurgical Quarterly, vol. 48, 2009, pp. 443-454.
F. Kurosawa, I. Taguchi, and R. Matsumoto, “Observation of Precipitates and Metallographic Grain Orientation in Steel by a Non-aqueous Electrolyte-Potentiostatic Etching Method,” The Journal of the Japan Institute of Metals, vol. 43, 1979, pp. 1068-1077.
F. Kurosawa, I. Taguchi, and R. Matsumoto, “Observation and Analysis of Carbides in Steels Using Non-aqueous Electrolyte-Potentiostatic Etching Method,” The Journal of the Japan Institute of Metals, vol. 44, 1980, pp. 1288-1295.
F. Kurosawa, I. Taguchi, and R. Matsumoto, “Observation and Analysis of Nitrides in Steels Using the Non-aqueous Electrolyte-Potentiostatic Etching Method,” The Journal of the Japan Institute of Metals, vol. 45, 1980, pp. 63-71.
J.J. Moore, Chemical Metallurgy, 1st ed., London, UK: Butterworth & Co., 1981.
G F. Vander Voort, Metallography: Principles and Practice, Materials Park, OH: ASM International, 1999, p. 393.
E.E. Underwood, Quantitative Stereology, Addison-Wesley Publishing Co, Reading, MA, 1970.
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Support for this work by the Advanced Steel Processing and Products Research Center at the Colorado School of Mines and by FIERF in the form of 2010–2011 FIERF fellowship for L.M. Rothleutner is gratefully acknowledged.
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Manuscript submitted December 15, 2012.
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Rothleutner, L.M., Cryderman, R. & Van Tyne, C.J. Influence of Temperature and Holding Time on the Interaction of V, Al, and N in Microalloyed Forging Steels. Metall Mater Trans A 45, 4594–4609 (2014). https://doi.org/10.1007/s11661-014-2375-1
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DOI: https://doi.org/10.1007/s11661-014-2375-1