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Thermodynamic Modeling of the Al-Ti-V Ternary System

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Abstract

The sub-binary systems Al-Ti, Ti-V, and Al-V are reviewed and adopted from the previous assessments, the thermodynamic analysis of the Al-Ti-V ternary system is performed by the CALPHAD approach, and a set of self-consistent thermodynamic parameters of the ternary system are obtained. Furthermore, the isothermal sections of this system at 1073 K, 1173 K, 1273 K, 1373 K, and 1473 K (800 °C, 900 °C, 1000 °C, 1100 °C, and 1200 °C) and the ternary invariant equilibria are calculated and compared with the corresponding experimental data, and all are in good agreement with most of the experimental results. Thus, the optimized thermodynamic parameters in this study may provide more accurate guidance to develop the new alloys involving it.

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Acknowledgments

Thanks are due to Dr. S.L. Chen, CompuTherm LLC, and Professor J.Y. Zhang, Shanghai University, for the helpful discussions of this work. This work is financially supported by the National Nature Science Foundation of China (Grant Nos. 51074105, 51374142 and 51225401), the Science and Technology Fund of Scientific Committee of Shanghai (Grant Nos. 11520500100 and 11DZ2283400), and the open project of the State Key Laboratory of New Ferrous Metallurgy Technology (Grant No. KF12-05).

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Authors and Affiliations

  1. Shanghai Key Laboratory of Modern Metallurgy & Materials Processing, Shanghai University, Shanghai, 200072, P.R. China

    Xionggang Lu (Professor), Na Gui (Master Candidate), Aitao Qiu (Master Candidate), Guangxin Wu (Associate Professor) & Chonghe Li (Professor)

  2. Shanghai Engineering Technology Research Center of Special Casting, Shanghai, P.R. China

    Xionggang Lu (Professor) & Chonghe Li (Professor)

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  1. Xionggang Lu
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Correspondence to Chonghe Li.

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Lu, X., Gui, N., Qiu, A. et al. Thermodynamic Modeling of the Al-Ti-V Ternary System. Metall Mater Trans A 45, 4155–4164 (2014). https://doi.org/10.1007/s11661-014-2317-y

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