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AlNiYCo Amorphous Matrix Composites Induced by Bismuth and Lead Additions

Metallurgical and Materials Transactions A volume 42, pages 4100–4105 (2011)Cite this article

Abstract

(Al85Ni5Y8Co2)98Bi2 and (Al85Ni5Y8Co2)98(Bi50Pb50)2 alloys are rapidly solidified using the single-roller melt-spinning method. Al85Ni5Y8Co2 amorphous matrix composites containing faceted BiY particles are synthesized by the liquid-solid reaction between added bismuth and constituents of the molten Al-Ni-Y-Co glass-forming alloy. The microstructure of the rapidly quenched (Al85Ni5Y8Co2)98(Bi50Pb50)2 multiphase composites consists of Al-based amorphous matrix and crystalline Pb-rich and BiY particles. The Pb-rich particles stem from liquid-liquid and monotectic reactions induced by lead addition. The phase constitution and microstructure are investigated by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The reaction-induced crystalline BiY and Pb-rich particles are uniformly distributed in the amorphous matrix. The microstructure formation of the rapidly quenched alloys was discussed.

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Acknowledgments

One of the authors (JH) gratefully acknowledges the financial support from the Knowledge Innovation Program of the Chinese Academy of Sciences, National Natural Science Foundation of China (Grant No. 50704032), and the Alexander von Humboldt Foundation. Special thanks are due to Professor L. Ratke for his valuable comments.

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Authors and Affiliations

  1. Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 110016, People’s Republic of China

    Jie He (Associate Professor), Hongxiang Jiang (M.Sc. Candidate) & Jiuzhou Zhao (Professor)

  2. IFW Dresden, Institute for Complex Materials, Dresden, 01069, Germany

    Jie He (Associate Professor), Norbert Mattern (Professor) & Jürgen Eckert (Professor)

  3. TU Dresden, Institute of Materials Science, Dresden, 01062, Germany

    Jürgen Eckert (Professor)

Authors
  1. Jie He
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  2. Hongxiang Jiang
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  3. Jiuzhou Zhao
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  4. Norbert Mattern
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  5. Jürgen Eckert
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Correspondence to Jie He.

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Manuscript submitted March 26, 2011.

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He, J., Jiang, H., Zhao, J. et al. AlNiYCo Amorphous Matrix Composites Induced by Bismuth and Lead Additions. Metall Mater Trans A 42, 4100–4105 (2011). https://doi.org/10.1007/s11661-011-0815-8

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  • DOI: https://doi.org/10.1007/s11661-011-0815-8

Keywords

  • Amorphous Matrix
  • White Particle
  • 98Bi2 Alloy
  • Monotectic Reaction
  • Scan Electron Microscopy Backscatter Electron