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Defects and Plastic-Deformation Modes of Bulk-Metallic Glasses

  • Symposium: Bulk Metallic Glasses VII
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Abstract

Results of the investigation of the point-defect manifestation in the recovery kinetics of Zr41Ti14Cu12.5Ni10Be22.5 and Zr52.5Ti5Cu17.9Ni14.6Al10 bulk-metallic glasses (BMGs) irradiated with 2.5 MeV electrons at 80 K (–193.15 °C) are presented. An observation of the pronounced annealing stages at 155 K and 130 K (–118.15 °C and –143.15 °C), and 225 K (–48.15 °C), shows that irradiation generates stable point defects in BMGs. The ultrasonic vibrations (USVs) of different amplitudes were used to investigate their effects on the cluster boundaries. The Kaiser effect is chosen as a tool for examining the boundary-slip initiation and impact of vibrations on the intercluster-boundary structure. Both the acoustic-emission activity and strength decrease due to the specimen pretreatment by USV. This effect is interpreted as a result of boundary softening under the USV. The inherent tensile strength of a Zr41Ti14Cu12.5Ni10Be22.5 BMG (in atomic percent) in the as-cast state was determined by means of high-field mechanical loading using the field-ion microscopy. It was revealed that the strength is characterized by a strong size effect in a nanometer-scale range as a result of the manifestation of the structural nanoheterogeneities and, in part, the existence of the cluster boundaries.

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References

  1. A.S. Bakai, I.M. Mikhailovskii, T.I. Mazilova and N. Wanderka: Low Temp. Phys., 2002, vol. 28, pp. 400–05.

    Google Scholar 

  2. J. Luo, H. Duan, C. Ma, S. Pand, and T. Zhang: Mater. Trans., 2006, vol. 47 (2), pp. 450–53.

    Article  CAS  Google Scholar 

  3. Y. Petrusenko, A. Bakai, I. Neklyudov, I. Mikhailovskij, S. Bakai, P.K. Liaw, L. Huang, and T. Zhang: J. Alloys Compd., 2010, vol. 504, pp. S198–S200.

    Article  Google Scholar 

  4. A.S. Bakai, S.A. Bakai, I.M. Mikhailovskii, I.M. Neklyudov, P.I. Stoev, and M.-P. Macht: JETP Lett., 2002, vol. 76, p. 218.

    Article  CAS  Google Scholar 

  5. A.S. Bakai, I.M. Neklyudov, P.I. Stoev, J. Eckert, and M.-P. Macht: J. Non-Cryst. Solids, 2007, vol. 353, pp. 3769–71.

    Article  CAS  Google Scholar 

  6. A.S. Bakai, S.A. Bakai, G.N. Malik, V.M. Gorbatenko, V.M. Netesov, and V.A. Emlyaninov: Prob. Atomic Sci. Tech., Series: Physics of Radiation Effect and Radiation Materials Science, 2005, No. 4, pp. 104–07.

  7. I.M. Mikhailovskij, P.Y. Poltinin, and L.I. Fedorova: Sov. Phys. Solid State, 1981, vol. 23, p. 757.

    Google Scholar 

  8. M.K. Miller, A. Cerezo, M.G. Hetherington, and G.D.W. Smith: Atom-Probe Field Ion Microscopy, Oxford University Press, Oxford, United Kingdom, 1996.

    Google Scholar 

  9. T.T. Tsong: Atom-Probe Field Ion Microscopy, Cambridge University Press, Cambridge, United Kingdom, 1990.

    Book  Google Scholar 

  10. Yu. Petrusenko, A. Bakai, V. Borysenko, D. Barankov, O. Astakhov, and M.-P. Macht: Mater. Res. Soc. Symp. Proc., 2008, vol. 1048, Z05-13.

  11. Y. Petrusenko, A. Bakai, I. Neklyudov, V. Borysenko, D. Barankov, O. Astakhov, and M.-P. Macht: Prob. Atomic Sci. Tech., Series: Physics of Radiation Effect and Radiation Materials Science, 2008, No. 2, pp. 62–65.

  12. Y. Petrusenko, A. Bakai, V. Borysenko, A. Astakhov, and D. Barankov: Intermetallics, 2009, vol. 17, pp. 246–48.

    Article  CAS  Google Scholar 

  13. A.S. Bakai: Prog. Phys. Met., 2002, vol. 3 (1), pp. 87–106.

    CAS  Google Scholar 

  14. V. Borysenko, Yu. Petrusenko, and D. Barabkov: Mater. Res. Soc. Proc., 2010, vol. 1215, V17-04.

  15. A. Inoue: Bulk Amorphous Alloys. Preparation and Fundamental Characteristics, Trans Tech Publications Ltd, Aedermannsdorf, Switzerland, 1998.

  16. A.Y. Vinogradov and V.F. Khonik: Philos. Mag., 2004, vol. 84, p. 2147.

    Article  CAS  Google Scholar 

  17. A.S. Bakai: Polycluster Amorphous Solids, Energoatomizdat, Moscow, 1987.

    Google Scholar 

  18. A.S. Bakai: in Glassy Metals III, H. Beck and H.-J. Guentherodt, eds., Springer-Verlag, Heidelberg, 1994, p. 9.

  19. A. Kelly and N.H. Macmillan: Strong Solids, Clarendon Press, Oxford, United Kingdom, 1986.

    Google Scholar 

  20. B. Yang, C.T. Liu, and T.G. Nieh: Appl. Phys. Lett., 2006, vol. 88, p. 221911.

    Article  Google Scholar 

  21. H. Bei, Z.P. Lu, and E.P. George: Phys. Rev. Lett., 2004, vol. 93, p. 125504.

    Article  CAS  Google Scholar 

  22. C.R. Krenn, D. Roundy, M.L. Cohen, D.C. Chrzan, and J.W. Morris: Phys. Rev. B, 2002, vol. 65, p. 134111.

    Article  Google Scholar 

  23. A.S. Bakai, V.V. Kul’ko, I.M. Mikhailovskij, V.B. Rabukhin, and O.A. Velikodnaja: J. Non-Cryst. Solids, 1995, vol. 182, p. 315.

    Article  Google Scholar 

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Acknowledgments

Some of the authors (YP, AB, IN, and SB) acknowledge the support of the Ukraine State Program “Nano-Technologies and Nano-Materials” through Project No. 1.1.1.48. The authors are grateful to Valeriy Borysenko, Oleksandr Astakhov, and Dmitro Barankov for performing electron irradiation and recovery studies of Zr-based BMGs, to Petro Stoyev for mechanical and acoustical tests of BMGs, and to Natalia Pavlichenko for the manuscript preparation.

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Correspondence to Yuri Petrusenko.

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Manuscript submitted April 30, 2010.

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Petrusenko, Y., Bakai, A., Neklyudov, I. et al. Defects and Plastic-Deformation Modes of Bulk-Metallic Glasses. Metall Mater Trans A 42, 1511–1515 (2011). https://doi.org/10.1007/s11661-011-0693-0

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