Abstract
Common steels of both hypo- and hypereutectoid compositions form pearlitic or martensitic constituents when cooled from austenite temperature in air or in water. Here, we provide evidence that this is not the case in an ultrafine-grained hypereutectoid steel. In this system, when the grain size was reduced to a scale of 2 to 4 μm, normal pearlite could not be obtained when the steel was cooled in air; instead, nanometer-sized granular cementite and ferrite were formed in the eutectoid transformation. When the cooling rate was increased by quenching in saltwater, martensite was no longer formed; instead, fine lamellar pearlite was formed. This research indicates that these abnormal phase transformations were related to the rapid diffusion present in the ultrafine-grained steel, which changed the diffusive transformations.
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References
R.W. Cahn: Physical Metallurgy, North-Holland Publishing Company, Amsterdam, the Netherlands, 1970, pp. 598–610.
W.F. Hosford: Physical Metallurgy, Taylor & Francis Group, Oxfordshire, UK, 2005, pp. 287–93.
P. Haasen: Physical Metallurgy, Cambridge University Press, Cambridge, UK, 1978, pp. 77–95.
P.P. Chatterjee, S.K. Pabi, and I.J. Manna: Appl. Phys., 1999, vol. 86, pp. 5912–14.
C. Hayzelden and B. Cantor: Acta Metall., 1986, vol. 34, pp. 233–42.
T.N. Durlu: J. Mater. Sci. Lett., 1997, vol. 16, pp. 320–21.
S. Kajiwara, S. Ohno, and K. Honma: Phil. Mag. A, 1991, vol. 63, pp. 625–44.
C. Kuhrt and L. Schultz: J. Appl. Phys., 1993, vol. 73, pp. 1975–80.
H. Kitahara, N. Tsuji, and Y. Minamino: Mater. Sci. Eng. A, 2006, vol. 438, pp. 233–36.
Y. Ivanisenko, I. MacLaren, X. Sauvage, R.Z. Valiev, and H.J. Fecht: Acta Mater., 2006, vol. 54, pp. 1659–69.
S. Ohsaki, K. Hono, H. Hidaka, and S. Takaki: Scripta Mater., 2005, vol. 52, pp. 271–76.
J.P. Lokker, A.J. Bottger, W.G. Sloof, F.D. Tichelaar, G.C.A.M. Janssen, and S. Radelaar: Acta Mater., 2001, vol. 49, pp. 1339–49.
Y.H. Zhou, M. Harmelin, and J. Bigot: Mater. Sci. Eng. A, 1991, vol. 133, pp. 775–79.
H.B. Wang, Q.Z. Liu, J.H. Zhang, and T.Y. Hsu: Nanotechnology, 2003, vol. 14, pp. 696–700.
R.Z. Valiev: Mater. Sci. Eng. A, 1997, vol. 234, pp. 59–66.
Y. Fukuda, K. Oh-Ishi, Z. Horita, and T.G. Langdon: Acta Mater., 2002, vol. 50, pp. 1359–68.
J. Kim, I. Kim, and D.H. Shin: Scripta Mater., 2001, vol. 45, pp. 421–26.
Y. Saito, H. Utsunomiya, N. Tsuji, and T. Sakai: Acta Mater., 1999, vol. 47, pp. 579–83.
N. Tsuji, R. Ueji, and Y. Minamino: Scripta Mater., 2002, vol. 47, pp. 69–76.
Y. Ivanisenko, R.K. Wunderlich, R.Z. Valiev, and H.J. Fecht: Scripta Mater., 2003, vol. 49, pp. 947–52.
Y. Ivanisenko, W. Lojkowski, R.Z. Valiev, and H.J. Fecht: Acta Mater., 2003, vol. 51, pp. 5555–70.
K. Oh-ishi, H.W. Zhang, T. Ohkubo, and K. Hono: Mater. Sci. Eng. A, 2007, vol. 456, pp. 20–27.
J.R. Groza and A. Zaraliangos: Mater. Sci. Eng. A, 2000, vol. 287, pp. 171–77.
S. Paris, E. Gaffet, F. Bernard, and Z.A. Munir: Scripta Mater., 2004, vol. 50, pp. 691–96.
Q. Jiang, S.H. Zhang, and J.C. Li: Solid State Commun., 2004, vol. 130, pp. 581–84.
M.K. Kuang and S.P. Yang: Bainite in Steels, Press of Shanghai Science and Technology, Shanghai, 1990, pp. 50–56.
W.P. Tong, N.R. Tao, Z.B. Wang, and K. Lu: Science, 2003, vol. 299, pp. 686–88.
J.W. Zhu, Y. Xu, and Y.N. Liu: Mater. Sci. Eng. A, 2004, vol. 385, pp. 440–44.
T. Furuhara, K. Kikumoto, H. Saito, T. Sekine, T. Ogawa, S. Morito, and T. Maki: ISIJ Int., 2008, vol. 48, pp. 1038–45.
A. Ankara: J. Iron Steel Inst., 1970, vol. 208, p. 819.
M.D. Uchic, D.M. Dimiduk, J.N. Florando, and W.D. Nix: Science, 2004, vol. 305, pp. 986–89.
T. Waitz, T. Antretter, F.D. Fischer, N.K. Simha, and H.P. Karnthaler: J. Mech. Phys. Sol., 2007, vol. 55, pp. 419–44.
A.M. Glezer, E.N. Blinova, V.A. Pozdnyakove, and A.V. Shelyakove: J. Nanoparticle Res., 2003, vol. 5, pp. 551–60.
B.E. Sundquist: Acta Metall., 1968, vol. 16, p. 1413–19.
D.A. Poter and K.E. Easterling: Phase Transformations in Metals and Alloys, 2nd ed., CSC Press, Boca Raton, FL, 1992, pp. 265–71.
Wikipedia: The Free Encyclopedia, http://en.wikipedia.org
P. Michel: Scripta Mater., 2005, vol. 52, pp. 709–12.
N. Katsumi, A. Markus, and S.Ingo: Acta Mater., 2006, vol. 54, pp. 3665–72.
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The authors are grateful for the financial support provided by the Natural Science Foundation of China through Grant No. 50871082.
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Manuscript submitted May 16, 2010.
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Liu, Y., He, T., Peng, G. et al. Pearlitic Transformations in an Ultrafine-Grained Hypereutectoid Steel. Metall Mater Trans A 42, 2144–2152 (2011). https://doi.org/10.1007/s11661-011-0608-0
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DOI: https://doi.org/10.1007/s11661-011-0608-0