Abstract
Beta-Ti alloys contain sufficient concentrations of β stabilizing alloy additions to permit retention of the metastable β phase after cooling to room temperature. Decomposition of the metastable β phase results in the formation of several possible phases, at least two of which are metastable. Concurrently, equilibrium α phase often forms first by heterogeneous nucleation at the α grain boundaries with an accompanying precipitate free zone observed adjacent to the grain boundary α. The grain boundary regions are softer than the precipitation hardened matrix. As a consequence, fracture follows the prior β grain boundaries, especially in high-strength conditions. This fracture mode results in low tensile ductility and/or fracture toughness. This article will describe methods of minimizing or eliminating grain boundary α formation by using metastable transition precipitates to nucleate α more rapidly. The effects on fracture behavior also will be described.
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U. Krupp, W. Floer, J.F. Lei, Y.M. Hu, H.J. Christ, A. Schick, and C.P. Fritzen: Philos. Mag., 2002, vol. 82 (17/18), pp. 3321–32.
G. Lütjering, J. Albrecht, C. Sauer, and T. Krull: Mater. Sci. Eng., A., 2007, vol. 468–470 (Special Issue SI), pp. 201–09.
J.O. Peters and G. Lütjering: Metall. Mater. Trans. A., 2001, vol. 32A, pp. 2805–18.
A.L. Pilchak, R.E.A. Williams, and J.C. Williams: Metall. Mater. Trans. A., 2010, vol. 41A, pp. 106–24.
J.C. Williams and G. Lütjering: Titanium, 2nd ed., Springer, Berlin, Germany, 2007, pp. 32.
S. Nag, R. Banerjee, R. Srinivasan, J.Y. Hwang, M. Harper, and H.L. Fraser: Acta Mater., 2009, vol. 57 (7), pp. 2136–47.
F. Prima, P. Vermaut, G. Texier, D. Ansel, and T. Gloriant: Scripta Mater., 2006, vol. 54 (4), pp. 645–48.
J.C. Williams: The Science Technology and Applications of Titanium, Plenum Press, New York, NY, 1973, pp. 1433–94.
S.Z. Zhang, Z.Q. Liu, G.D. Wang, L.Q. Chen, X.H. Liu, and R. Yang: J. Cent. South Univ. Technol., 2009, vol. 16 (3), pp. 354–59.
B. Peterson, P.C. Collins, and H.L. Fraser: Mater. Sci. Eng. A, 2009, vol. 513–514, pp. 357–65.
A.L. Pilchak, D.M. Norfleet, M.C. Juhas, and J.C. Williams: Metall. Mater. Trans., 2008, vol. 39A, pp. 1519–24.
T. Zhai, Y.G. Xu, J.W. Martin, A.J. Wilkinson, and G.A.D. Briggs: Int. J. Fatig., 1999, vol. 21 (9), pp. 889–94.
P.C. Collins, B. Welk, T. Searles, J. Tiley, J.C. Russ, and H.L. Fraser: Mater. Sci. Eng. A., 2009, vol. 508 (1–2), pp. 174–82.
L. Kovarik, S.A. Court, H.L. Fraser, and M.J. Mills: Acta Mater., 2008, vol. 56 (17), pp. 4804–15.
C. Sauer and G. Lütjering: Mater. Sci. Eng. A., 2001, vol. 319 (Special Issue SI), pp. 393–97.
K. Tokaji, K. Ohya, and H. Kariya: Fatigue Frac. Eng. Mater. Struct., 2000, vol. 23 (9), pp. 759–66.
Y.M. Hu, W. Floer, U. Krupp, and H.J. Christ: Mater. Sci. Eng. A., 2000, vol. 278 (1–2), pp. 170–80.
V. Sinha, M.J. Mills, and J.C. Williams: J. Mater. Sci., 2007, vol. 42 (19), pp. 8334–41.
A.P. Woodfield, M.D. Gorman, J.A. Sutliff, and R.R. Corderman: Fatigue Behavior of Titanium Alloys, Eds. R.R. Boyer, D. Eylon, and G. Lütjering, TMS, Warrendale, PA, 1999, pp. 111–18.
A.L Pilchak and J.C. Williams: Metall. Mater. Trans. A., 2010, vol. 41A, pp. 22–25.
D.C. Slavik, J.A. Wert, and R.P. Gangloff: J. Mater. Res., 1993, vol. 8 (10), pp. 2482–91.
V. Sinha, M.J. Mills, and J.C. Williams: Metall. Mater. Trans. A., 2006, vol. 37A, pp. 2015–26.
Y.J. Ro, S.R. Agnew, and R.P. Gangloff: Scripta Mater., 2005, vol. 52 (6), pp. 531–36.
C.C. Wojcik, K.S. Chan, and D.A. Koss: Acta Metall., 1988, vol. 36 (5), pp. 1261–70.
X.H. Wu, J. del Prado, Q. Li, A. Huang, D. Hu, and M.H. Loretto: Acta Mater., 2006, vol. 54 (20), pp. 5233–48.
M. Chu, X. Wu, I.P. Jones, and M.H. Loretto: Mater. Sci. Technol., 2006, vol. 22 (6), pp. 661–66.
J.C. Williams and M.J. Blackburn: Trans. Metall. Soc. AIME, 1969, vol. 245 (10), pp. 2352–55.
J.C. Williams, B.S. Hickman, and H.L. Marcus: Metall. Trans., 1971, vol. 2, pp. 1913.
Acknowledgments
Support for this work is gratefully acknowledged from the U.S. Office of Naval Research D3-D program, Grant. N00014-05-1-0504. The authors would like to thank Adam Pilchak for his valuable discussions.
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Manuscript submitted January 8, 2010.
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Foltz, J.W., Welk, B., Collins, P.C. et al. Formation of Grain Boundary α in β Ti Alloys: Its Role in Deformation and Fracture Behavior of These Alloys. Metall Mater Trans A 42, 645–650 (2011). https://doi.org/10.1007/s11661-010-0322-3
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DOI: https://doi.org/10.1007/s11661-010-0322-3