Abstract
The effects of tailoring FeCo alloys with addition of ternary elements Pt, Pd, Mn, Ir, and Re have been investigated. In the composition range of 30 to 70 pct Co, FeCo alloys undergo a continuous order-disorder phase transition at a maximum temperature of 730 °C at the equiatomic composition. The effects of temperature and composition on the degree of long-range order in six alloys (Fe70Co30, Fe67Co30Pt3, Fe67Co30Pd3, Fe67Co30Mn3, Fe67Co30Ir3, and Fe67Co30Re3; at. pct) were compared using neutron diffraction. The transition goes along with growing of antiphase domains during the heating process.
Similar content being viewed by others
References
T. Sourmail: Prog. Mater. Sci., 2005, vol. 50, pp. 816–80.
R.S. Sundar and S.C. Deevi: Int. Mater. Rev., 2005, vol. 50, pp. 157–92.
A. Diaz-Ortiz, R. Drautz, M. Fähnle, H. Dosch, and J.M. Sanchez: Phys. Rev. B, 2006, vol. 73, pp. (224208-1)-(224208-15).
F. Pfeifer and C. Radeloff: J. Magn. Mater., 1980, vol. 19, pp. 190–207.
J.P. Neumann: Acta Metall., 1980, vol. 28, pp. 1165–70.
M.J. Marcinkowski and H. Chessin: Philos. Mag., 1964, vol. 10, pp. 837–59.
I.A. Abrikosov, P. James, O. Eriksson, P. Söderlind, A.V Ruban, H.L. Skiver, and B. Johansson: Phys. Rev. B, 1996, vol. 54, pp. 3380–84.
T. Nishizawa and K. Ishida: in Binary Alloy Phase Diagrams, T.B. Massalski, ed., Metals Park, OH, ASM, 1990, vol. 2, pp. 1186–87.
A.I.C. Persiano and R.D. Rawlings: Phys. Status Solidi A, 1987, vol. 103, pp. 547–56.
A. Williams, G.H. Kwei, T. Ortiz, M. Karnowski, and W.K. Warburton: J. Mater. Res., 1990, vol. 5, pp. 1197–1200.
C. Shull and S. Siegel: Phys. Rev., 1949, vol. 75 (7), pp. 1008–10.
B.D. Cullity: Elements of X-Ray Diffraction, 2nd ed., Addison-Wesley Publishing Co., Reading, MA, 1978, pp. 391–94.
R. Gilles, M. Hoelzel, M. Schlapp, F. Elf, B. Krimmer, H. Boysen, and H. Fuess: Z. Kristllogr., 2006, No. 23, pp. 183–86.
M. Hoelzel, A. Senyshyn, R. Gilles, H. Boysen, and H. Fuess: Neutron News, 2007, vol. 18 (4), pp. 23–26.
M. Hofmann, R. Schneider, G.A. Seidl, J. Rebelo-Kornmeier, R.C. Wimpory, U. Garbe, and H.-G. Brokmeier: Physica, 2006, vols. B385–B386, pp. 1035–37.
J.A. Oyedele and M.F. Collins: Phys. Rev. B, 1977, vol. 16 (7), pp. 3208–12.
D.W. Clegg and R.A. Buckley: Met. Sci. J., 1973, vol. 7, pp. 48–54.
D.S. Gaunt and M.F. Sykes: J. Phys. A, 1977, vol. 6, pp. 1517–26.
B.E. Warren: X-Ray Diffraction, Dover Publications, Inc., New York, NY, 1990.
J.A. Rogers, H.M. Flower, and R.D. Rawlings: Met. Sci., 1975, vol. 9, pp. 32–35.
R.A. Buckley: Met. Sci., 1975, vol. 9, pp. 243–47.
Acknowledgments
The authors thank Alexander Schmidt and Alois Pscheidt for their support on the high-temperature furnace.
Author information
Authors and Affiliations
Corresponding author
Additional information
This article is based on a presentation given in the symposium “Neutron and X-Ray Studies of Advanced Materials,” which occurred February 15–19, 2009, during the TMS Annual Meeting in San Francisco, CA, under the auspices of TMS, TMS Structural Materials Division, TMS/ASM Mechanical Behavior of Materials Committee, TMS: Advanced Characterization, Testing, and Simulation Committee, and TMS: Titanium Committee.
Rights and permissions
About this article
Cite this article
Gilles, R., Hofmann, M., Gao, Y. et al. Probing the Relationship of Long-Range Order in Nanodomain FeCo Alloys with Ternary Additions Using Neutron Diffraction. Metall Mater Trans A 41, 1144–1150 (2010). https://doi.org/10.1007/s11661-009-9933-y
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11661-009-9933-y