The effect of small molybdenum additions, 0.66 and 2.3 at. pct, on the microstructure, tensile, and creep behavior of a nominally Ti-24Al-17Nb (at. pct) alloy was investigated. The alloy containing 2.3 at. pct Mo contained higher body-centered-cubic (bcc) phase volume fractions, which was expected as Mo stabilizes the bcc phase. Constant load, tensile-creep experiments were performed in the stress range of 29 to 275 MPa and the temperature range of 650 °C to 710 °C, in both air and vacuum environments. In-situ creep experiments were performed inside a scanning electron microscope chamber in order to identify the deformation evolution from surface observations. From these experiments, it was evident that α 2 intergranular cracking was prevalent and initiated the fracture process where the crack path followed the α 2 grain boundaries. The Ti-24Al-17Nb-2.3Mo (at. pct) alloy exhibited significantly lower creep rates than the Ti-24Al-17Nb-0.66Mo (at. pct) alloy, and this was associated with less contiguity of the α 2 phase.
Similar content being viewed by others
REFERENCES
C.J. Cowen, C.J. Boehlert: Phil. Mag., 2006, vol. 86 (1), pp. 99–124
H.T. Kestner-Weykamp, C.W. Ward, T.F. Broderick, M.J. Kaufman: Scripta Metall., 1989, vol. 23, pp. 1697–1702
L.A. Bendersky, W.J. Boettinger, A. Roysburd: Acta Metall. Mater., 1991, vol. 39, pp. 1059–69
C.G. Rhodes: AF TR No. WL-TR-97-4082, P.R. Smith ed., Air Force Research Laboratory Materials and Manufacturing Directorate, Dayton, OH, 1997, pp. 83–100
C.J. Boehlert, B.S. Majumdar, V. Seetharaman, D.B. Miracle: Metall. Mater. Trans. A, 1999, vol. 30A, pp. 2305–23
M.G. Mendiratta, H.A. Lipsitt: J. Mater. Sci., 1980, vol. 15, p. 2985–90
G. Malakondaiah, P.R. Rao: Acta Metall.,1981, vol. 29, p. 1263–75
R.S. Mishra, D. Banerjee: Mater. Sci. Eng. A, 1990, vol. 130, pp. 151–64
H. Conrad, M. Doner, and B. DeMeester: in Titanium Science and Technology, R.I. Jaffee, and H.M. Burte, eds., Plenum, New York, NY, 1973, pp. 969–1005
T.K. Nandy, R.S. Mishra, D. Banerjee: Scripta Metall. Mater., 1993, vol. 28, pp. 569–74.
T.K. Nandy, R.S. Mishra, A.K. Gogia, D. Banerjee: Scripta Metall. Mater., 1995, vol. 32, pp. 851–56.
T.K. Nandy, D. Banerjee: Intermetallics, 2000, vol. 8, pp. 915–28
C.J. Boehlert, D.B. Miracle: Metall. Mater. Trans. A, 1999, vol. 30, pp. 2349–67
P.R. Smith and J.A. Graves: Proc. Orthorhombic Titanium Matrix Composite Workshop, WL-TR-95-4068, Wright-Patterson Air Force Base, OH, 1995, pp. 139–50
A.K. Gogia, T.K. Nandy, K. Muralheedharan, D. Banerjee: Mater. Sci. Eng., 1992, vol. A159, pp. 73–86.
M.J. Blackburn and M.P. Smith: Improved Toughness Alloys Based on Titanium Aluminides, WRDC-TR-89-4095, Wright-Patterson Air Force Base, OH, 1989, pp. 162–72
C.J. Boehlert, B.S. Majumdar, S. Krishnamurthy, D.B. Miracle: Metall. Mater. Trans. A, 1997, vol. 28A, pp. 309–23
B.S. Majumdar, C.J. Boehlert, A.K. Rai, and D.B. Miracle: High Temperature Ordered Intermetallic Alloys-VI, Materials Research Society Symposia Proceedings, J. Horton, I. Baker, S. Hanada, R.D. Noebe, and D.S. Schwartz, eds., Materials Research Society, Pittsburgh, PA, 1995, vol. 364, pp. 1259–65
B.S. Majumdar, C.J. Boehlert, and D.B. Miracle: Proc. Orthorhombic Titanium Matrix Composites Workshop, WL-TR-95-4068, Wright-Patterson Air Force Base, OH, 1995, pp. 65–82
C.J. Boehlert, B.S. Majumdar, and D.B. Miracle: Fatigue and Fracture of Ordered Intermetallics II, W.O. Soboyejo, T.S. Srivatsan, and R.O. Ritchie, eds., TMS, Warrendale, PA, 1995, pp. 135–53
C.J. Boehlert, B.S. Majumdar, and D. Eylon: Key Eng. Mater., 1997, vols. 127–131 Part I, 1997, pp. 843–50
S.M. Russ, C.J. Boehlert, D. Eylon: Mater. Sci. Eng., 1995, vols. A192–A193, pp. 483–89
S. Krishnamurthy, P.R. Smith, D.B. Miracle: Scripta Metall., 1994, vol. 31, pp. 653–58.
J.R. Porter, J.A. Hall, J.C. Chesnutt, and C.G. Rhodes: Advanced Ti-Based MMC Development, Interim Report, WL-TR-95-4034, Wright-Patterson Air Force Base, OH, 1995
S. Krishnamurthy, P.R. Smith, and D.B. Miracle: Metal Matrix Composites, Proc. 10th Int. Conf. of Composite Materials, A. Poursartip, and K.N. Street, eds., Woodhead Publishing, Ltd., Cambridge, United Kingdom, 1995, vol. 2, pp. 739–46
S. Krishnamurthy, P.R. Smith, and D.B. Miracle: Proc. Orthorhombic Titanium Matrix Composites Workshop, WL-TR-95-4068, Wright-Patterson Air Force Base, OH, 1995, pp. 83–105
J.W. Zhang, C.S. Lee, D.X. Zou, S.Q. Li, J.K.L. Lai: Metall. Mater. Trans. A, 1998, vol. 29A, pp. 559–64
J.F. Edd and J.T. Niemann: in Titanium Matrix Composites, WL-TR-92-4035, P.R. Smith and W.C. Revelos, eds., Wright-Patterson Air Force Base, OH, 1992, pp. 158–73
P.R. Smith, A. Rosenberger, M.J. Shepard, R. Wheeler: J. Mater. Sci., 2000, vol. 35, pp. 3169–79
C.G. Rhodes, P.R. Smith, W.H. Hanusiak, M.J. Shephard: Metall. Mater. Trans. A, 2000, vol. 31A, pp. 2931–41
C.F. Yolton, J.P. Beckman: Mater. Sci. Eng., 1995, vols. A192–A193, pp. 597–603
C.J. Boehlert, C.J. Cowen, S. Tamirisakandala, D.J. McEldowney, D.B. Miracle: Scripta Mater., 2006, vol. 55, pp. 465–68
P.R. Smith, W.J. Porter: J. Mater. Sci., 1997, vol. 32, p. 6215–20
S. Krishnamurthy, P.R. Smith, D.B. Miracle: Mater. Sci. Eng., 1998, vol. A243, pp. 285–89
G.A. Hartman, and S.M. Russ: in Metal Matrix Composites: Testing, Analysis and Failure Modes, W.S. Johnson, ed., ASTM, Philadelphia, PA, 1989, pp. 43–53
P.R. Smith, A. Rosenberger, M.J. Shepard: Scripta Metall., 1999, vol. 41 (2), pp. 221–28
C.J. Cowen, C.J. Boehlert: Intermetallics, 2006, vol. 14 (4), pp. 412–22
J. Rusing, C. Herzig, Intermetallics, 1996, vol. 4, p. 647–57
P.R. Smith, W.J. Porter, W.J. Kralik, and J.A. Graves: Metal Matrix Composites, Proc. 10th Int. Conf. of Composite Materials, A. Poursartip, K.N. Street, eds., Woodhead Publishing, Ltd., Cambridge, United Kingdom, 1995, vol. 2, pp. 731–38
ACKNOWLEDGMENTS
The authors acknowledge Dr. Michael J. Shephard (Air Force Research Laboratory) and Mr. Paul R. Smith (Research Applications Incorporated) for their assistance.
Author information
Authors and Affiliations
Corresponding author
Additional information
Manuscript submitted July 27, 2006.
Rights and permissions
About this article
Cite this article
QUAST, J., BOEHLERT, C. Comparison of the Microstructure, Tensile, and Creep Behavior for Ti-24Al-17Nb-0.66Mo (Atomic Percent) and Ti-24Al-17Nb-2.3Mo (Atomic Percent) Alloys. Metall Mater Trans A 38, 529–536 (2007). https://doi.org/10.1007/s11661-006-9074-5
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11661-006-9074-5