Abstract
The effect of the addition of 5 at. pct boron on the microstructure and creep behavior of a nominally Ti-22Al-26Nb (at. pct) alloy was investigated. The boron-modified alloy contained boride needles enriched in titanium and niobium, and because to these borides, this material was considered to be a discontinuously reinforced metal matrix composite. These needle-shaped borides made up to 2 pct of the volume and were up to 158-μm long and 22-μm wide. The effect of boron on the mechanical properties was evaluated through in-situ creep testing and tensile testing at room temperature (RT) and 650 °C. Overall, the addition of 5 at. pct boron proved to be detrimental to the tensile and creep behavior. The composite exhibited a brittle failure and lower elongations-to-failure than the monolithic material. The in-situ tensile and creep experiments revealed that the deformation process initiated in the boride needles, which cracked extensively, and significantly greater primary creep strains and creep rates were exhibited by the composite.
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References
Tamirisakandala S., Bhat R.B., Tiley J.S., Miracle D.B. (2005) Scripta Mater. 53: 1421–26
Gorsse S., Miracle D.B. (2006) Acta Mater. 51:2427–42
Boehlert C.J., Cowen C.J., Tamirisakandala S., McEldowney D.J., Miracle D.B. (2006) Scripta Mater. 55:465–68
Boehlert C.J., Majumdar B.S., Seetharaman V., Miracle D.B. (1999) Metall. Trans. A 30A: 2305–23
Cowen C.J., Boehlert C.J. (2006) Phil. Mag. 86: 99–124
Kestner-Weykamp H.T., Ward C.W., Broderick T.F., Kaufman M.J. (1989) Scripta Metall. 23: 1697–1702
Bendersky L.A., Boettinger W.J., Roytburd A. (1991) Acta Metall. Mater. 39: 1959–69
C.G. Rhodes, J.A. Graves, P.R. Smith, and M.R. James: in Structural Intermetallics, R. Darolia, J.J. Lewandowski, C.T. Liu, P.L. Martin, D.B. Miracle, and M.V. Nathal, eds., TMS, Warrendale, PA, 1993, pp. 45-52.
Mendiratta M.G., Lipsitt H.A. (1980) J. Mater. Sci. 15:2985
Malakondaiah G., Rao P.R. (1981) Acta Metall. 29:1263
Mishra R.S., Banerjee D. (1990) Mater. Sci. Eng. A. 130:151–64
H. Conrad, M. Doner, and B. DeMeester: in Titanium Science and Technology, R.I. Jaffee and H.M. Burte, eds., Plenum, New York, NY, 1973, p. 969.
Nandy T.K., Mishra R.S., Banerjee D. (1993) Scripta Metall. Mater. 28: 569–74
Nandy T.K., Banerjee D. (2000) Intermetallics 8: 915–28
Boehlert C.J., Miracle D.B. (1999) Metall. Mater. Trans. A 30A:2349–67
Smith P.R., Rosenberger A., Shepard M.J., Wheeler R. (2000) J. Mater. Sci. 35: 3169–79
Smith P.R., Rosenberger A., Shepard M.J. (1999) Scripta Mater. 41: 221–28
Rhodes C.G., Smith P.R., Hanusiak W.H., Shepard M.J. (2000) Metall. Mater. Trans. A 31:2931–41
R.G. Rowe: in Titanium ’92 Science and Technology, F.H. Froes and I.L. Caplan, eds., TMS, Warrendale, PA, 1993, p. 343
R.G. Rowe and M. Larsen: in Titanium ‘95, P.A. Blenkinsop, W.J. Evans, and H.M. Flower, eds., The University Press, Cambridge, United Kingdom, 1996, pp. 364-71
Boehlert C.J., Miracle D.B. (1999) Metall. Mater. Trans. A 30A: 2349–67
C.J. Boehlert, B.S. Majumdar, V. Seetharaman, D.B. Miracle, and R. Wheeler: in Structural Intermetallics, R. Darolia, J.J. Lewandowski, C.T. Liu, P.L. Martin, D.B. Miracle, and M.V. Nathal, eds., TMS, Warrendale, PA, 1997, pp. 795-804
Tang F., Nakazawa S., Hagiwara M. (2001) Mater. Sci. Eng. A 315: 147–52
Hagiwara M., Emura S., Araoka A. (2003) Mater. Sci. Forum 426–432: 1715–20
Yang S.J., Emura S., Hagiwara M., Nam S.W. (2003) Scripta Mater. 49: 897–902
Hagiwara M., Emura S., Araoka A., Kong B.O., Tang F. (2003) Met. Mater. Int. 9: 265–72
Emura S., Yang S.J., Hagiwara M. (2004) Metall. Mater. Trans. A 35A: 2971–79
C.J. Cowen and C.J. Boehlert: Advanced Materials Research, Trans Tech Publications Ltd, Switzerland, Part 1, 2007, vol. 15–17, pp. 976-981.
Standard Test Methods for Determining Average Grain Size, ASTM Designation E112-96e3, ASTM, West Conshohocken, PA
Panda K.B. Ravi Chandran K.S. (2006) Acta Mater. 54: 1641–57
D.R. Trinkle: Scripta Materialia, 2007, vol. 56, pp. 273–276.
C.J. Cowen, PhD Thesis, Michigan State University, 2006.
Boehlert C.J. (2001) Metall. Mater. Trans. A 32A: 1977–88
Gogia A.K., Nandy T.K., Muraleedharan K., Banerjee D. (1992) Mater. Sci. Eng. A 159: 73–86
Boehlert C.J., Majumdar B.S., Eylon D. (1997) Key Eng. Mater. 127–131: 843–50
C.F. Yolton and J.H. Moll: in Titanium ‘95, P.A. Blenkinsop, W.J. Evans, and H.M. Flower, eds., The University Press, Cambridge, United Kingdom, 1996, p. 2755
M. Hagiwara and S. Emura: Workshop on Titanium Alloys Modified with Boron, Dayton, OH, Oct. 11–13, 2005
Acknowledgments
This work was partially supported by the National Science Foundation through Grant Nos. DMR-0533954 and DMR-030992 and by an American Society of Engineering Education (ASEE) Air Force Research Laboratory (AFRL) Summer Faculty Fellowship (Contract No. F49620-02-C-0015) to CJB. The authors are grateful to Sesh Tamirisakandala, Daniel Miracle, and Fred Yolton for helpful assistance and guidance and Gerald Wynick and Ward Votava for their technical assistance with the EMP analysis.
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Cowen, C., Boehlert, C. Comparison of the Microstructure, Tensile, and Creep Behavior for Ti-22Al-26Nb (At. Pct) and Ti-22Al-26Nb-5B (At. Pct) . Metall Mater Trans A 38, 26–34 (2007). https://doi.org/10.1007/s11661-006-9004-6
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DOI: https://doi.org/10.1007/s11661-006-9004-6