Skip to main content

Advertisement

Log in

Correlation of microstructure with hardness and wear resistance of VC/steel surface-alloyed materials fabricated by high-energy electron-beam irradiation

  • Published:
Metallurgical and Materials Transactions A Aims and scope Submit manuscript

Abstract

Correlation of microstructure with hardness and wear resistance of VC/carbon steel surface-alloyed materials fabricated by high-energy electron-beam irradiation was investigated. The mixtures of VC powders and flux (50 pct MgO-50 pct CaO or CaF2) were deposited on a plain carbon steel substrate, and subsequently irradiated using a high-energy electron beam. The surface-alloyed layers of 1.2 to 3 mm in thickness were homogeneously formed without defects, and contained a large amount (about 10 vol pct) of VC precipitates in the bainitic or martensitic matrix. This microstructural modification including the formation of hard precipitates and hardened matrix in the surface-alloyed layers improved hardness and wear resistance. Particularly in the surface-alloyed material fabricated with the lower input energy density, the wear resistance was greatly enhanced over the steel substrate because of the increased size and volume fraction of VC particles, although the thickness of the surface-alloyed layer decreased. Microstructural modifications including melting, solidification, precipitation, and phase transformation of the surface-alloyed layer were also predicted from a thermal transfer modeling and a Fe-V-C ternary phase diagram. The predicted results were found consistent with those data from actual electron-beam irradiation and microstructural analysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. L.E. Toth: Transition Metal Carbides Nitrides, Academic Press, New York, NY, 1971, pp. 1–28.

    Google Scholar 

  2. J.H. Lee, J.C. Oh, J.W. Park, H.C. Lee, and S. Lee: Iron Steel Inst. Jpn. Int., 2001, vol. 41, pp. 859–65.

    CAS  Google Scholar 

  3. J.E. Krzanowski and R.E. Leuchtner: J. Am. Ceram. Soc., 1997, vol. 80, pp. 1277–80.

    Article  CAS  Google Scholar 

  4. Y. Herrera, I.C. Grigorescu, J. Ramirez, C. Di Rauso, and M.H. Staia: Surf. Coat. Technol., 1998, vols. 108–109, pp. 308–11.

    Article  Google Scholar 

  5. T. Zhang, H. Huang, C. Ji, J. Chen, G. Sun, H. Zhang, and X. Zhang: Surf. Coat. Technol., 1994, vol. 65, pp. 148–53.

    Article  CAS  Google Scholar 

  6. M. Bamberger: Int. Mater. Rev., 1998, vol. 43, pp. 189–203.

    CAS  Google Scholar 

  7. J.D. Ayers, R.J. Schaefer, and W.P. Robey: J. Met., 1981, vol. 33, pp. 19–23.

    CAS  Google Scholar 

  8. Y. Wang, F. Li, G. Zeng, and D. Feng: Mater. Des., 1999, vol. 20, pp. 19–22.

    Google Scholar 

  9. J.C. Oh, K. Euh, S. Lee, Y. Koo, and N.J. Kim: Scripta Mater., 1998, vol. 39, pp. 1389–94.

    Article  CAS  Google Scholar 

  10. K. Euh, S. Lee, and K. Shin: Metall. Mater. Trans. A, 1999, vol. 30 A, pp. 3143–51.

    Google Scholar 

  11. K. Euh, S.-H. Choo, and S. Lee: Metall. Mater. Trans. A, 2000, vol. 31 A, pp. 2849–55.

    Google Scholar 

  12. E. Rimini: in Surface Modification and Alloying by Laser, Ion, and Electron Beams, J.M. Poate, G. Foti, and D.C. Jacobson, eds., Plenum Press, New York, NY, 1983, p. 15.

    Google Scholar 

  13. M. von Allmen: in Laser Annealing Semiconductors, J.M. Poate and J.W. Mayer, eds., Academic Press, New York, NY, 1982, p. 43.

    Google Scholar 

  14. A.F. Baisman, S.B. Vasserman, M.G. Golkovski, V.D. Kedo, and R.A. Salimov: About Surface Hardening by Concentrated Electron Beam at Atmosphere, Budker Institute of Nuclear Physics, Preprint No. 88–73, Novosibirsk, Russia, 1988, pp. 5–31.

  15. L. Davis: An Introduction to Welding Fluxes for Mild and Low Carbon Steels, The Welding Institute, Cambridge, United Kingdom, 1981, pp. 1–16.

    Google Scholar 

  16. M. Bauccio: ASM Engineered Materials Reference Book, 2nd ed., ASM INTERNATIONAL, Materials Park, OH, 1994, pp. 283–84.

    Google Scholar 

  17. Y.I. Golubenko, M.E. Veis, N.K. Kuksanov, S.A. Kuznetsov, B.M. Korabelnikov, A.B. Malinin, P.I. Nemytov, V.V. Prudnikov, S.E. Petrov, R.A. Salimov, V.G. Cherpkov, and S.N. Fadeev: Accelerators of ELV-Type; Status, Development, Applications, BudkerINP 97-7, Budker Institute of Nuclear Physics, Novosibirsk, Russia, 1997, pp. 1–28.

    Google Scholar 

  18. R. Ito, P. Andreo, and T. Tabata: Radiat. Phys. Chem., 1993, vol. 42, pp. 761–64.

    Article  CAS  Google Scholar 

  19. G. Petzow: Metallographic Etching, ASM, Metals Park, OH, 1978, p. 65.

    Google Scholar 

  20. ASTM Standard Practice for Conducting Dry Sand/Rubber Wheel Abrasion Tests, ASTM G65-85, ASTM, Philadelphia, PA, 1985.

  21. O.N. Carlson, A.H. Ghaneya, and J.F. Smith: Phase Diagrams of Binary Vanadium Alloys, J.F. Smith, ed., ASM INTERNATIONAL, Metals Park, OH, 1989, pp. 33–42.

    Google Scholar 

  22. E.K. Storms: The Refractory Carbides, Academic Press, NY, 1967, pp. 47–60.

    Google Scholar 

  23. B.D. Cullity: Elements of X-ray Diffraction, 2nd ed., Addison-Wesley Pub. Co., Reading, MA, 1978, pp. 350–68.

    Google Scholar 

  24. R.L. Burden and J.D. Faires: Numerical Analysis, 6th ed., Books/Cole Pub. Co., Pacific Grove, CA, 1997, pp. 443–57.

    Google Scholar 

  25. D. Suh, S. Lee, and Y. Koo: Metall. Mater. Trans. A, 1997, vol. 28 A, pp. 637–47.

    Article  Google Scholar 

  26. V. Raghavan: Phase Diagrams of Ternary Iron Alloys, Part 1, ASM INTERNATIONAL, Metals Park, OH, 1987, p. 111.

    Google Scholar 

  27. V. Raghavan: Bull. Alloy Phase Diagrams, 1984, vol. 5, pp. 293–99.

    CAS  Google Scholar 

  28. S.-H. Choo, S. Lee, and S.-J. Kwon: Metall. Mater. Trans. A, 1999, vol. 30A, pp. 3131–41.

    CAS  Google Scholar 

  29. K.C. Hwang, S. Lee, and E. Lee: Tetsu-to-Hagané, 1997, vol. 83, pp. 37–42.

    Google Scholar 

  30. B.-J. Lee and D.N. Lee: Calphad, 1991, vol. 15, pp. 293–306.

    Article  CAS  Google Scholar 

  31. C.E. Jackson: WRC Bull., 1977, vol. 190, pp. 1–25.

    Google Scholar 

  32. K. Euh, J. Lee, S. Lee, Y. Koo, and N.J. Kim: Scripta Mater., 2001, vol. 45, pp. 1–6.

    Article  CAS  Google Scholar 

  33. D. Suh, S. Lee, Y. Koo, and H.C. Lee: Metall. Mater. Trans. A, 1996, vol. 27A, pp. 3149–61.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Euh, K., Lee, S. Correlation of microstructure with hardness and wear resistance of VC/steel surface-alloyed materials fabricated by high-energy electron-beam irradiation. Metall Mater Trans A 34, 59–69 (2003). https://doi.org/10.1007/s11661-003-0208-8

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11661-003-0208-8

Keywords

Navigation