Abstract
In order to understand the mechanism of the massive type of phase transformation, it is essential to study its critical limit in the phase diagram and to analyze the results with theoretical models. The model, based on the interaction between solute atoms and the migrating interface, is described in detail and applied to binary alloys. The importance of the relation between the mobility of the interface relative to the atomic mobilities inside the interface is emphasized. Specimens with a constant heat or carbon content offer valuable experimental variables. It is, thus, possible to force the interface to advance slowly.
Similar content being viewed by others
References
T.B. Massalski: Phase Transformations, Seminar of the American Society of Metals 1968, ASM, Metals Park, OH, 1970, pp. 433–86.
A. Borgenstam and M. Hillert: Acta Mater., 2000, vol. 48, pp. 2765–75.
H.I. Aaronson, C. Laird, and K.R. Kinsman: Scripta Metall., 1968, vol. 2, pp. 259–64.
K. Lücke and K. Detert: Acta Metall., 1957, vol. 5, pp. 628–35.
K. Lücke and H. Stüwe: Recovery and Recrystallization of Metals, Interscience, New York, NY, 1963, pp. 131–59.
J.W. Cahn: Acta Metall., 1962, vol. 10, pp. 789–98.
M. Hillert: The Mechanism of Phase Transformations in Crystalline Solids, Monograph No. 33, Institute of Metals, London, 1969, pp. 231–47.
M. Hillert and B. Sundman: Acta Metall., 1976, vol. 24, pp. 731–43.
M. Hillert: Acta Mater., 1999, vol. 47, pp. 4481–4505.
M. Hillert, J. Odqvist, and J. Ågren: Scripta Mater., in press.
D. Turnbull: Trans. AIME, 1951, vol. 191, pp. 661–67.
M. Hillert and M. Schalin: Acta Mater., 2000, vol. 48, pp. 461–68.
D.A. Karlyn, J.W. Cahn, and M. Cohen: Trans. TMS-AIME, 1969, vol. 245, pp. 197–207.
M. Hillert: Metall. Trans. A, 1984, vol. 15A, pp. 411–19.
E.B. Hawbolt and T.B. Massalski: Metall. Trans., 1970, vol. 1, pp. 2315–22.
T.B. Massalski, A.J. Perkins, and J. Jaklovsky: Metall. Trans., 1972, vol. 3, pp. 687–94.
T.B. Massalski, J.H. Perepezko, and J. Jaklovsky: Mater. Sci. Eng., 1975, vol. 18, pp. 193–98.
F.W. Jones and W.I. Pumphrey: J. Iron Steel Inst., 1949, vol. 163, pp. 121–31.
M. Suehiro, J. Ågren, and Z.-K. Liu: Acta Metall. Mater., 1996, vol. 44, pp. 4241–51.
A. Hultgren: Trans. ASM, 1947, vol. 39, pp. 915–89.
A. Hultgren: Kungl. Vet. Akad. Handl., 1953, vol. 4 (3).
M. Hillert: “Paraequilibrium,” Internal Report, Swedish Institute of Metals Research, Stockholm, 1953.
M. Hillert: Phase Equilibria, Phase Diagrams and Phase Transformations—Their Thermodynamic Basis, Cambridge University Press, Cambridge, United Kingdom, 1998.
K. Oi, C. Lux, and G.R. Purdy: Acta Mater., 2000, vol. 48, pp. 2147–55.
N.E. Hannerz: Bachelor’s Thesis, KTH, Stockholm, 1961; cited by M. Hillert: Suppl. Trans. Iron Steel Inst. Jpn., 1971, vol. 11, pp. 1153–59.
G.R. Purdy, D.H. Weichert, and J.S. Kirkaldy: Trans. AIME, 1964, vol. 230, pp. 1025–34.
Z.-K. Liu and J. Ågren: Acta Mater., 1989, vol. 37, pp. 3157–63.
Z.-K. Liu: Metall. Mater. Trans. A, 1997, vol. 28A, pp. 1625–31.
M. Suehiro: Proc. Int. Conf. in Solid-Solid Phase Transformations ’99 (JIMIC-3), M. Koiwa, K. Otsuka, and T. Miyazaki, eds., The Japan Institute of Metals, Sendai, Japan, 1999, pp. 1465–69.
G.R. Purdy and Y.J.M. Brechet: Acta Mater., 1995, vol. 43, pp. 3763–74.
M. Enomoto: Acta Mater., 1999, vol. 47, pp. 3533–40.
A. Borgenstam and M. Hillert: Acta Mater., 1997, vol. 45, pp. 2079–91.
G.J. Shiflet and H.I. Aaronson: Metall. Trans. A, 1990, vol. 21A, pp. 1413–32.
W.T. Reynolds, Jr., F.Z. Li, C.K. Shui, and H.I. Aaronson: Metall. Trans. A, 1990, vol. 21A, pp. 1433–63.
K.R. Kinsman and H.I. Aaronson: Transformations and Hardenability in Steels, Climax Molybdenum Co., Ann Arbor, MI, 1967, pp. 33–38.
Author information
Authors and Affiliations
Additional information
This article is based on a presentation made at the symposium entitled “The Mechanisms of the Massive Transformation,” a part of the Fall 2000 TMS Meeting held October 16–19, 2000, in St. Louis, Missouri, under the auspices of the ASM Phase Transformations Committee.
Rights and permissions
About this article
Cite this article
Hillert, M. Critical limit for massive transformation. Metall Mater Trans A 33, 2299–2308 (2002). https://doi.org/10.1007/s11661-002-0353-5
Issue Date:
DOI: https://doi.org/10.1007/s11661-002-0353-5