Abstract
Surface energy measurements have been performed on liquid Ga-Sn binary and on Ga-Pb-Sn as well as Ga-Pb-Tl ternary alloys, by the sessile drop technique under ultrahigh vacuum conditions. The purpose of these measurements was to investigate the change in adsorption behavior of Pb in Garich alloys as a consequence of ternary additions. In order to aid in the interpretation of the results, a multilayer model of surface segregation was formulated in the regular solution approximation. The results show evidence of site competition effects between the two solutes, which reduce the surface concentration of Pb in relation to binary Ga-Pb alloys. The effects of Sn on previously studied wetting-related adsorption transitions in Ga-Pb were also investigated. It was concluded that Sn additions are likely to raise the wetting temperature of the Ga-Pb alloy.
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C. Serre, P. Wynblatt, and D. Chatain: Surf. Sci., 1998, vol. 415, pp. 336–45.
M. Hillert: Acta Metall., 1961, vol. 9, pp. 525–35.
J.L. Meijering: Acta Metall., 1966, vol. 14, pp. 251–58.
E. Defay and I. Prigogine: Surface Tension and Adsorption, Longmans, London, 1966.
Y.W. Lee and H.I. Aaronson: Acta Metall., 1980, vol. 28, pp. 539–48.
M.A. Hoffman and P. Wynblatt: Metall. Trans. A, 1989, vol. 20A, pp. 215–23.
M. Guttmann and D. McLean: In Interfacial Segregation, W.C. Johnson and J.M. Blakely, eds., ASM, Metals Park, OH, 1979, pp. 261–348.
P. Wynblatt, A. Saul, and D. Chatain: Acta Mater., 1998, vol. 46, pp. 2337–47.
W.-C. Cheng and P. Wynblatt: Surf. Sci., 1996, vol. 364, pp. 409–16.
T.E. Faber: Introduction to the Theory of Liquid Metals, University Press, Cambridge, United Kingdom, 1972.
I. Prigogine and R. Defay: Thermodynamique Chimique, Editions Desoer, Liège, 1950.
J.W. Cahn: J. Chem. Phys., 1977, vol. 66, pp. 3667–72.
M.J. de Olivera and R.B. Griffiths: Surf. Sci., 1978, vol. 71, pp. 687–94.
R. Pandit, M. Schick, and M. Wortis: Phys. Rev., 1982, vol. B26, pp. 5112–40.
S.C. Hardy: J. Cryst. Growth, 1985, vol. 71, pp. 602–06.
A. Passerone, R. Sangiorgi, and G. Caracciolo: J. Chem. Thermodynamics, 1983, vol. 15, pp. 971–83.
L.D. Lucas: Analyse et Constantes Physico-Chimiques-Form M67, Techniques de I’Ingénieur, Paris, 1984.
I. Ansara and F. Ajersch: J. Phase Equilibria, 1991, vol. 12, pp. 73–77.
T.J. Anderson and I. Ansara: J. Phase Equilibria, 1992, vol. 13, pp. 181–89.
I. Ansara: ENSCP, Grenoble, France, private communication.
I. Karakaya and W.T. Thompson: Bull. Alloy Phase Diagram, 1998, vol. 9, pp. 144–452.
R. Hultgren, P.D. Desai, D.T. Hawkins, M. Gleiser, and K.K. Kelley: Selected Values of the Thermodynamic Properties of Binary Alloys, ASM, Metals Park, OH, 1973.
S.C. Mueller, H. Tostmann, D. Nattland, and W. Freyland: Ber. Bunsenges, Phys. Chem., 1994, vol. 98, pp. 395–598.
D. Nattland, P.D. Poh, S.C. Müller and W. Freyland: J. Phys. Condens. Matter, 1995, vol. 7, pp. L457-L462.
H. Tostmann, E. DiMasi, O.G. Shpyrko, P.S. Pershan, B.M. Ock, and M. Deutsch: Ber. Bunsenges. Phys. Chem., 1998, vol. 102, 1136–41.
D. Chatain and P. Wynblatt: Surf. Sci., 1996, vol. 345, pp. 85–90.
H. Shim, D. Chatain, and P. Wynblatt: Surf. Sci., 1998, vol. 415, pp. 346–50.
D. Chatain, P. Wynblatt, M. De Ruijter, J. De Coninck, and C. Carter: Acta Mater., 1999, vol. 47, pp. 3049–56.
G. Wilde and J.H. Perepezko: Acta Mater., 1999, vol. 47, pp. 3009–21.
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Serre, C., Chatain, D., Muris, M. et al. Surface energy, adsorption, and wetting transitions in ternary liquid alloys. Metall Mater Trans A 32, 2851–2858 (2001). https://doi.org/10.1007/s11661-001-1035-4
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DOI: https://doi.org/10.1007/s11661-001-1035-4