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Organic geochemical characteristics and significance of Permian Gufeng formation siliceous shale in well CSDP-2 of South Yellow Sea central uplift

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Abstract

In order to understand the hydrocarbon generation potential of the siliceous shale in the Permian Gufeng Formation of the South Yellow Sea, the organic geochemistry and organic petrology of the siliceous shale in the Gufeng Formation of the CSDP-2 well were studied and analyzed. It is found that the TOC of the samples is mainly between 9% and 12%, and Tmax is mainly distributed between 510 and 540 °C. The value of the organic microscopic type index (TI) is between 25.71 and 31.00, which is a set of II2 high-quality source rocks with high organic matter abundance in the over mature stage of large-scale gas generation. According to the distribution characteristics of Molecular fossils in siliceous shale of Gufeng Formation of well CSDP-2, bacterial organic matter is the main hydrocarbon generating parent material, and aquatic animal organic matter is an important hydrocarbon generating parent material. The siliceous shale in Gufeng Formation of CSDP-2 well is in the stage of large-scale gas generation; Therefore, the Gufeng Formation in the central uplift of the South Yellow Sea has the material basis for the formation of large-scale shale gas reservoirs. At the same time, the siliceous metasomatism of the siliceous shale reservoir of Gufeng Formation is not conducive to the primary migration of oil, and there is much oil and gas remaining in the reservoir.

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References

  • Brassell SC, Wardroper AMK, Thomson ID et al (1981) Specific acyclic isoprenoids as biological markers of methanogenic bacteria in marine sediments. Nature 290(5808):693–696. https://doi.org/10.1038/290693a0

    Article  Google Scholar 

  • Cai LX, Xiao GL, Wan HQ (2021) Multi-stage accumulation of the meso-paleozoic marine hydrocarbon in central uplift of South Yellow Sea: exploration significance of borehole CSDP-2. J of Jilin Univ (Earth Sci Edit) 51(2):307–324. https://doi.org/10.13278/j.cnki.jjuese.20200256

    Article  Google Scholar 

  • Chen H P (2020) Shale deposits and reservoir characteristics of Gufeng and Dalong formations in Permianin Western Hubei. Chengdu University of Technology

  • Cheng QS, Zhang M, Huang GH (2019) Even-carbon predominance of monomethyl branched alkanes in Humic coal from Junggar basin NW China. Acta Geochimica. https://doi.org/10.1007/s11631-019-00372-8

    Article  Google Scholar 

  • Cheng QS, Chen X, Zhang JH (2022) Organic geochemical characteristics and shale oil geological significance of E1f4 in the GY1 well, Guanzhen subsag Subei Basin. Arab J Geosci 15:376. https://doi.org/10.1007/s12517-021-09121-9

    Article  Google Scholar 

  • Connan J, Cassou AM (1980) Properties of gases and petroleum liquids derived from terrestrial kerogen at various maturation levels. Geochim Cosmochim Acta 44(1):1–23

    Article  Google Scholar 

  • Didk BM, Simoneit BRT, Brassell SC (1978) Organic geochemical indicators of palaeoenvironmental conditions of sedimentation. Nature 272:216–222

    Article  Google Scholar 

  • Ding JH, Zhang JC, Shi G (2021) Sedimentary environment and organic matter enrichment mechanisms of the Upper Permian Dalong formation Shale, Southern Anhui Province China. Oil Gas Geol 42(1):158–172 (in Chinese with English abstract)

    Google Scholar 

  • Fowler MG, Douglas AG (1987) Saturated hydrocarbon biomarkers in oils of Late Precambrian age from Eastern Siberia. Org Geochem 11(3):201–213

    Article  Google Scholar 

  • Grice K, Schouten S, Nissenbaum A (1998) Isotopically heavy carbon in the C21 to C25 regular isoprenoids in halite- rich depositions from the Sdom formation, Dead Sea basin, Israel. Org Geochem 28:349–359

    Article  Google Scholar 

  • Guo TL (2021) Geological characteristics and exploration prospect of carbonate sourcerock gas in Sichuan basin. J Southwest Pet Univ (sci Technol Edit) 43(1):1–16. https://doi.org/10.11885/j.issn.1674-5086.2020.10.20.03

    Article  Google Scholar 

  • Han J, Calvin M (1970) Branched alkanes from blue-green algue. J Chem Soc D Chem Commun 22:1490–1491

    Article  Google Scholar 

  • He Q, Liu J, Xu ZH (2009) Origin and biosynthetic effects on the stable carbon isotopic compositions of 3-methyl and 2-methyl alkanesthyl alkanes in tobacco leaves. Geochimica 38(3):282–288 (in Chinese with English abstract)

    Google Scholar 

  • Heemann V, Brummer U, Paulsen C, Seehofer F (1983) Composition of the leaf surface gum of some Nicotiana species and Nicoyiana tabacum cultivars. Phytochemistry 22(1):133–135

    Article  Google Scholar 

  • Hills IR, Whitehead EV, Anders DE, Cummins JJ, Robinson WE (1966) An optically active triterpane, gammacerane in green river, colorado, oil shale bitumen. Chem Commun 20(20):752–754

    Google Scholar 

  • Hu SZ (2000) New consideration of Gufong formation by stratigraphy check up. Volcanol Mineral Res 21(1):63–68

    Google Scholar 

  • Huang YR, Zhang ZH, Liu JY (2012) Study on Permian-Triassic hydrocarbon generation evaluation and history of late accumulation in Huangqiao-Jurong Area. J Oil Gas Technol 34(3):44–48

    Google Scholar 

  • Huang BJ, Shi RF, Zhao XB, Zhou G (2013) Geological conditions of Paleozoic shale gas formation and its exploration potential in the South Anhui, Lower Yangtze area. J China Coal Soc 38(5):877–882

    Google Scholar 

  • Ji LM, Li JF, Song ZG (2009) Petroleum geological significance of Botryococcus in TriassicYanchang formation. Ordos Basin Petrol Explor Dev 36(2):156–165 (in Chinese with English abstract)

    Google Scholar 

  • Klomp UC (1986) The chemical structure of a pronounced series of iso-alkanes in South Oman crudes. Org Geochem 10:807–814

    Article  Google Scholar 

  • Kolattukudy PE (1969) Plant waxes. Lipids 5(2):259–275

    Article  Google Scholar 

  • Li F, Shi HY, Zan L, Huang YR (2013) Organic geochemistry of Permian source rocks in Nanling-Wuwei area of Anhui. J Geol 37(1):31–40

    Google Scholar 

  • Li HH, Du J, Chen K (2020) The discovery of Permian shale gas in Wufeng area Hubei Province. Geol China 47(6):1932–1933

    Google Scholar 

  • Liao SB, Shi G, Li JQ (2021) Shale gas drilled by well WWD1 in the Wangjiang area of Anhui Province. Geol China 48(5):1657–1658

    Google Scholar 

  • Liu XP, Pan JP, Dong QQ (2011) Geological conditions of Shale gas formation in Paleozoic Subei Area. Nat Gas Geosci 22(6):1087–1095

    Google Scholar 

  • Liu JQ, Xu H, Sun J(2012) A discussion on oil and gas potential in the South Yellow Sea Basin of Lower Yangtze sea area. Marine Geol Front 4:30–37

    Google Scholar 

  • Luo XY, Zhao ZJ (2007) Meng Y L (2007) The application of n-alkanes odd-even carbon number predominance in oil-source rock correlation—an example of the Lower Paleozoic in Tarim basin. Pet Geol Exp 29(1):74–77

    Google Scholar 

  • Ma YS, Cai XY (2006) Exploration achievements and prospects of the Permian Triassic natural gas in northeastern Sichuan basin. Oil Gas Geol 27(6):741–750

    Google Scholar 

  • Meng FY, Chen K, Bao SJ (2017) Determination of marine-continental transitional facies shale gas: a case study of Baye No.1 well in Badong area western Hubei Province. Geology in China 44(2):403–404

    Google Scholar 

  • Moldowan JM, Seifort WK (1983) Identification of extended series of tricyclic terpanes in petroleum. Geochimica Cosmochimica Acta 47:1531–1534

    Article  Google Scholar 

  • Ourisson G, Rohmer MA, Poralla K (1987) Prokaryotic hopanoids and other polyterpenoid sterol surrogates. Ann Rev Microbiol 41(41):301–333

    Article  Google Scholar 

  • Pang YM (2017) Tectonic thermal evolution history of the central uplift of the South sea basin from CSDP-2 drilling well. Institute of Oceanology, Chinese Academy of Sciences, Qingdao

  • Peters KE, Walters CC, Moldwan JM (2005) The biomarker guider, 2nd edn. Cambridge University Press, New York

    Google Scholar 

  • Philp RP (1983) Correlation of crude oils from the San Jorges Basin, Argentina. Geochim Cosmochim Acta 47(2):267–275

    Article  Google Scholar 

  • Philp RP (1985) Fossil fuel biomarkers. Elsevier, New York, pp 1–294

    Google Scholar 

  • Qi JH, Wen ZH (2013) Zhang X H (2013) Lithostratigraphic correlation of mesozoic and Palaeozoic marine strata between South Yellow Sea and Upper Yangtze region. Mar Geol Q Geol 1:109–119

    Google Scholar 

  • Qian Y, Wang ZD, Tuo JC et al (2017) Origin and significance of monomethyl alkanes from Yanchang formation source rocks in Ordos basin. Petrol Geol Exper 39(1):86–93 (in Chinese with English abstract)

    Google Scholar 

  • Risatti JB, Rowland SJ, Yon DA (1984) Stereochemical studies of acyclic isoprenoids—XII. Lipids of methanogenic bacteria and possible contributions to sediments. Org Geochem 6:93–104. https://doi.org/10.1016/0146-6380(84)90030-5

    Article  Google Scholar 

  • Schouten S, Van Der Marc JEC, Maarel HR (1997) 2,6,10,15,19- Pentamethylicosenes in Methanolobus bombayensis, a marine methanogenic archaeon, and in Methanosarcina mazei. Org Geochem 26(5–6):409–414. https://doi.org/10.1016/S0146-6380(97)00011-9

    Article  Google Scholar 

  • Shang HY (1990) Organic geochemistry and fluorescence microscopy. Petroleum Industry Press, Beijing

    Google Scholar 

  • Shi G, Li JQ, Liao SB (2021) Discovery of Permian shale gas in the Wanyoudi-1 well of Xuancheng Anhui Province. Geol in China 48(2):669–670

    Google Scholar 

  • Shiea J, Brassell SC, Ward DM (1990) Mid-chain branched mono-and dimethylakanes in hot spring cyan bacterial mats: a direct biogenic source for branched alkanes in ancient sediments. Org Geochem 15:223–231

    Article  Google Scholar 

  • Sinninghe Damsté JS, Leeuw de JW (1990) Organic sulfur compounds and other biomarkers as indicators of palaeosalinity. Geochemistry of Sulfur in Fossil Fuels. ACS Symposium Series American Chemical Society, (429)

  • Wang TG (1990) A Contribution to some sedimentary environmental biomarkers in crude oils and source rocks in China. Geochimic 03:62–69

    Google Scholar 

  • Wang TG, Sheng GY, Chen JH, Fu JM (1994) Methyl triterpene and methyl tetracycline terpenane and its origin significance. Chin Sci Bull 39(10):933–935 (in Chinese)

    Article  Google Scholar 

  • Wang TG, Sheng GY, Chen JH, Fu JM (1995) Biomarker assemblage of algal coal in Shuicheng, Western Guizhou. China Sci China (series b) 25(11):1219–1225 (in Chinese)

    Google Scholar 

  • Wu K, Ma QF, Feng QL (2015) Stratigraphic division and spatial distribution of the Middle Permian KuFeng formation in the Northern Yangtze block. J Stratigr 39(1):33–39

    Google Scholar 

  • Wu T, Fang CG, He JH (2022) Discovery of Permian shale gas drilled in Maanshan area, Anhui Provinc. Geology in China https://kns.cnki.net/kcms/detail/11.1167.P.20221121.1509.004.html

  • Wu K (2013) Geobiological composition and geological characters of shale gas from the Middle Permian Gufeng Formation in the North Margin of Yangtze. China University of Geosciences

  • Xu WM (1990) On the origins of the Permian Siliceous rocks in Jiangsu-Zhejiang-Anhui Provinces and their relation with the generation of oil and gas. Pet Geol Exp 12(1):44–48

    Google Scholar 

  • Xu H, Zhang HY, Zhang BL (2015) Characteristics of the 26 wells from the basin. Marine Geology Frontiers 31(4):16

    Google Scholar 

  • Zhang MQ, Lu YC (2013) Shale features and gas-source condition in the western Lower Yangtze area. China Offshore Oil and Gas 25(2):9–17

    Google Scholar 

  • Zhang XH, Yang JY, Li G (2014) Basement structure and distribution of Mesozoic-Paleozoic marine strata in the South Yellow Sea basin. Chin J Geophys 12:4041–4051

    Google Scholar 

  • Zhang XH, Xiao GL, Wu ZQ (2017) Understanding and discussion on some geological problems of oil and gas exploration in the South Yellow Sea. Science Press, Beijing

    Google Scholar 

  • Zhang M, Cheng QS (2021) Distribution and signifcance of high abundance C29 regular sterane in the crude oil of Lower Paleozoic in Tarim basin. J Yangtze Univ (Nat Sci Ed) 18(1):11–29. https://doi.org/10.16772/j.cnki.1673-1409.2021.01.001

    Article  Google Scholar 

  • Zhao PR (2021) Reservoir characteristics and gas exploration potential of Permian Mao-1 member of Maokou formation in Jiaoshiba Area. Pet Reserv Eval Dev 11(5):772–781. https://doi.org/10.13809/j.cnki.cn32-1825/te.2021.05.016

    Article  Google Scholar 

  • Zhao PR, Gao B, Guo ZF (2020) Exploration potential of marine-continental transitional and deep-water shelf shale gas in Upper Permian Sichuan Basin. Pet Geol Exp 42(3):335–344

    Google Scholar 

  • Zhu WB, Zhang XH, Zhou DR (2021) New cognition on pore structure characteristics of Permian marine shale in the Lower Yangtze region and its implications for shale gas exploration. Nat Gas Ind 41(7):41–55

    Google Scholar 

  • Zumberge JE (1981) Tricyclic diterpene distribution in the correlation of Paleozoic crude oils from the Williston Basin. Adv Org Geochem, 738–745

  • Chen SB, Zhu YM, Li W (2011) Geological optimization of shale gas and coalbed methane combined research & develop in Yangtze China. J Liaoning Tech Univ (nat Sci) 30(5):672–676

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Funding

This research was financially supported by General program of Shandong Natural Science Foundation (ZR2020MD071); General program of NSFC: (42076220); Science and technology project of PetroChina Zhejiang Oilfield Company (zjyt-2021-kj-008).

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This article is provided by GJ, YC, WJ and YY. The specific research methods and manuscript preparation were completed by CQ.

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Correspondence to Qing-song Cheng.

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Gong, Jm., Cheng, Qs., Yang, Cs. et al. Organic geochemical characteristics and significance of Permian Gufeng formation siliceous shale in well CSDP-2 of South Yellow Sea central uplift. Acta Geochim 42, 765–778 (2023). https://doi.org/10.1007/s11631-023-00600-2

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