Abstract
Arsenic (As) contamination in groundwater is a major problem in many countries, which causes serious health issues. In this paper, a novel method has been developed for the simultaneous removal of ROX and As(III/V) using the modified sorghum straw biochar (MSSB). The MSSB was characterized by X-ray diffraction, scanning electron microscopy, Fourier Transform Infrared, and Brunauer–Emmet–Teller (BET) surface area. The removal performance of MSSB for ROX, arsenite [As(III)], and arsenate (As(V)) was investigated using batch experiments. At pH of 5, the arsenic concentration of 1.0 mg/L, adsorbent dose of 1.0 g/L, the maximum adsorption capacities of ROX, As(III), and As(V) were 12.4, 5.3, and 23.0 mg/g, respectively. The adsorption behaviors were fit well with the Langmuir and the pseudo-second-order rate model. The results showed that MSSB acted as a highly effective adsorbent to simultaneously remove the composite pollution system consisted of ROX and As(III/V) in aqueous solutions, providing a promising method in environmental restoration applications.
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Acknowledgements
This work was supported by the National Natural Science Foundation of China (Grant Nos. 41773136 and 41703129), Innovation Talent Support Project of Liaoning (Grant No. LR2017073), the National Key Rand D Program of China (No. 2017YFD0800301), the basic research projects of Source-sink transformation of arsenic and roxarsone in sediments (XXLJ 2019007).
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Zang, S., Zuo, Y., Wang, J. et al. Adsorption removal of roxarsone, arsenite(III), and arsenate(V) using iron-modified sorghum straw biochar and its kinetics. Acta Geochim 40, 409–418 (2021). https://doi.org/10.1007/s11631-021-00466-2
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DOI: https://doi.org/10.1007/s11631-021-00466-2