Estimation of evaporation losses based on stable isotopes of stream water in a mountain watershed

Acta Geochimica volume 40, pages176–183(2021)Cite this article

Abstract

Water stable isotopes (δ2H and δ18O) can record surface water evaporation, which is an important hydrological process for understanding watershed structure and function evolution. However, the isotopic estimation of water evaporation losses in the mountain watersheds remains poorly explored, which hinders understanding spatial variations of hydrological processes and their relationships with the temperature and vegetation. Here we investigated δ2H, δ18O, and d-excess values of stream water along an altitude gradient of 2130 to 3380 m in Guan’egou mountain watershed at the east edge of the Qinghai-Tibet Plateau in China. The mean δ2H (− 69.6 ‰ ± 2.6 ‰), δ18O (− 10.7 ‰ ± 0.3 ‰), and d-excess values (16.0 ‰ ± 1.4 ‰) of stream water indicate the inland moisture as the major source of precipitation in study area. Water stable isotopes increase linearly with decreasing altitudes, based on which we estimated the fractions of water evaporation losses along with the altitude and their variations in different vegetations. This study provides an isotopic evaluation method of water evaporation status in mountain watersheds, the results are useful for further understanding the relationship between hydrological processes and ecosystem function under the changing climate surrounding the Qinghai-Tibet Plateau.

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References

  1. Beria H, Larsen JR, Ceperley NC, Michelon A, Vennemann T, Schaefli B (2018) Understanding snow hydrological processes through the lens of stable water isotopes. WIREs Water. https://doi.org/10.1002/wat2.1311

    Article  Google Scholar 

  2. Brown RA, Pasternack GB (2014) Hydrologic and topographic variability modulate channel change in mountain rivers. J Hydrol 510:551–564. https://doi.org/10.1016/j.jhydrol.2013.12.048

    Article  Google Scholar 

  3. Cappa CD, Hendricks MB, DePaolo DJ, Cohen RC (2003) Isotopic fractionation of water during evaporation. J Geophys Res. https://doi.org/10.1029/2003jd003597

    Article  Google Scholar 

  4. Chahine MT (1992) The hydrological cycle and its influence on climate. Nature 359:373–380. https://doi.org/10.1038/359373a0

    Article  Google Scholar 

  5. Clark ID, Fritz P (1997) Environmental isotopes in hydrogeology. Lewis Publishers, New York

    Google Scholar 

  6. Craig H (1961) Isotopic variations in meteoric waters. Science 133:1702–1703. https://doi.org/10.1126/science.133.3465.1702

    Article  Google Scholar 

  7. Cui J, Tian L, Biggs TW, Wen R (2017) Deuterium-excess determination of evaporation to inflow ratios of an alpine lake: Implications for water balance and modeling. Hydrol Process 31:1034–1046. https://doi.org/10.1002/hyp.11085

    Article  Google Scholar 

  8. Dansgaard W (1964) Stable isotopes in precipitation. Tellus 16:436–468. https://doi.org/10.3402/tellusa.v16i4.8993

    Article  Google Scholar 

  9. Edwards PJ, Williard KW, Schoonover JE (2015) Fundamentals of watershed hydrology. J Contemp Water Res Educ 154:3–20. https://doi.org/10.1111/j.1936-704X.2015.03185.x

    Article  Google Scholar 

  10. Fan Y et al (2019) Hillslope hydrology in global change research and earth system modeling. Water Resour Res 55:1737–1772. https://doi.org/10.1029/2018wr023903

    Article  Google Scholar 

  11. Froehlich K, Kralik M, Papesch W, Rank D, Scheifinger H, Stichler W (2008) Deuterium excess in precipitation of Alpine regions - moisture recycling. Isotopes Environ Health Stud 44:61–70. https://doi.org/10.1080/10256010801887208

    Article  Google Scholar 

  12. Gat JR (1996) Oxygen and hydrogen isotopes in the hydrologic cycle. Annu Rev Earth Planet Sci 24:225–262. https://doi.org/10.1146/annurev.earth.24.1.225

    Article  Google Scholar 

  13. Gehre M, Strauch G (2003) High-temperature elemental analysis and pyrolysis techniques for stable isotope analysis. Rapid Commun Mass Sp 17:1497–1503. https://doi.org/10.1002/rcm.1076

    Article  Google Scholar 

  14. Gibson JJ, Birks SJ, Yi Y (2016) Stable isotope mass balance of lakes: a contemporary perspective. Quaternary Sci Rev 131:316–328. https://doi.org/10.1016/j.quascirev.2015.04.013

    Article  Google Scholar 

  15. Gibson JJ, Edwards TWD (2002) Regional water balance trends and evaporation-transpiration partitioning from a stable isotope survey of lakes in northern Canada. Global Biogeochem Cy 16: 10–1–10–14. https://doi.org/10.1029/2001gb001839

  16. Gibson JJ, Edwards TWD, Bursey GG (1993) Estimating evaporation using stable isotopes: quantitative results and sensitivity analysis for two catchments in Northern Canada: paper presented at the 9th Northern Res. Basin Symposium/Workshop (Whitehorse/Dawson/Inuvik, Canada - August 1992). Hydrol Res 24:79–94. https://doi.org/10.2166/nh.1993.0015

    Article  Google Scholar 

  17. Gibson JJ, Reid R (2010) Stable isotope fingerprint of open-water evaporation losses and effective drainage area fluctuations in a subarctic shield watershed. J Hydrol 381:142–150. https://doi.org/10.1016/j.jhydrol.2009.11.036

    Article  Google Scholar 

  18. Guo X, Wang L, Tian L (2016) Spatio-temporal variability of vertical gradients of major meteorological observations around the Tibetan Plateau. Int J Climatol 36:1901–1916. https://doi.org/10.1002/joc.4468

    Article  Google Scholar 

  19. He S, Richards K (2016) Stable isotopes in monsoon precipitation and water vapour in Nagqu, Tibet, and their implications for monsoon moisture. J Hydrol 540:615–622. https://doi.org/10.1016/j.jhydrol.2016.06.046

    Article  Google Scholar 

  20. Hren MT, Bookhagen B, Blisniuk PM, Booth AL, Chamberlain CP (2009) δ18O and δD of streamwaters across the Himalaya and Tibetan Plateau: implications for moisture sources and paleoelevation reconstructions. Earth Planetary Sci Lett 288:20–32. https://doi.org/10.1016/j.epsl.2009.08.041

    Article  Google Scholar 

  21. Jasechko S, Sharp ZD, Gibson JJ, Birks SJ, Yi Y, Fawcett PJ (2013) Terrestrial water fluxes dominated by transpiration. Nature 496:347–350. https://doi.org/10.1038/nature11983

    Article  Google Scholar 

  22. Jiang H et al (2004) The influence of vegetation type on the hydrological process at the landscape scale. Can J Remote Sens 30:743–763. https://doi.org/10.5589/m04-033

    Article  Google Scholar 

  23. Jiao Y, Liu C, Gao X, Xu Q, Ding Y, Liu Z (2019) Impacts of moisture sources on the isotopic inverse altitude effect and amount of precipitation in the Hani Rice Terraces region of the Ailao Mountains. Sci Total Environ 687:470–478. https://doi.org/10.1016/j.scitotenv.2019.05.426

    Article  Google Scholar 

  24. Kammer PM, Schöb C, Eberhard G, Gallina R, Meyer R, Tschanz C (2013) The relationship between soil water storage capacity and plant species diversity in high alpine vegetation. Plant Ecol Divers 6:457–466. https://doi.org/10.1080/17550874.2013.783142

    Article  Google Scholar 

  25. Kong Y, Wang K, Li J, Pang Z (2019) Stable isotopes of precipitation in China: a consideration of moisture sources. Water. https://doi.org/10.3390/w11061239

    Article  Google Scholar 

  26. Körner C (2007) The use of “altitude” in ecological research. Trends Ecol Evol 22:569–574. https://doi.org/10.1016/j.tree.2007.09.006

    Article  Google Scholar 

  27. Li Q, Xie Z (2006) Analyses on the characteristics of the vertical lapse rates of temperature, taking Tibetan Plateau and its adjacent area as an example. J Shihezi Univ (Nat Sci) 24:719–723 (in Chinese with English abstract)

    Google Scholar 

  28. Li Z et al (2016) Contributions of local terrestrial evaporation and transpiration to precipitation using δ18O and D-excess as a proxy in Shiyang inland river basin in China. Glob Planet Change 146:140–151. https://doi.org/10.1016/j.gloplacha.2016.10.003

    Article  Google Scholar 

  29. Li ZJ, Li ZX, Song LL, Ma JZ (2020) Characteristic and factors of stable isotope in precipitation in the source region of the Yangtze River. Agr Forest Meteorol. https://doi.org/10.1016/j.agrformet.2019.107825

    Article  Google Scholar 

  30. Li Z et al (2015) Can monsoon moisture arrive in the Qilian Mountains in summer? Quat Int 358:113–125. https://doi.org/10.1016/j.quaint.2014.08.046

    Article  Google Scholar 

  31. Liu Z, Tian L, Yao T, Yu W (2007) Seasonal deuterium excess in Nagqu precipitation: influence of moisture transport and recycling in the middle of Tibetan Plateau. Environ Geol 55:1501–1506. https://doi.org/10.1007/s00254-007-1100-4

    Article  Google Scholar 

  32. Liu Z, Tian L, Yao T, Yu W (2010) Characterization of precipitation δ18O variation in Nagqu, central Tibetan Plateau and its climatic controls. Theor Appl Climatol 99:95–104. https://doi.org/10.1007/s00704-009-0125-x

    Article  Google Scholar 

  33. Luz B, Barkan E, Yam R, Shemesh A (2009) Fractionation of oxygen and hydrogen isotopes in evaporating water. Geochim et Cosmochim Acta 73:6697–6703. https://doi.org/10.1016/j.gca.2009.08.008

    Article  Google Scholar 

  34. Majoube M (1971) Oxygen-18 and deuterium fractionation between water and steam (in French). J Chim Phys PCB 68:1423–1436

    Article  Google Scholar 

  35. Marston RA (2008) Land, life, and environmental change in mountains. Ann Assoc Am Geogr 98:507–520. https://doi.org/10.1080/00045600802118491

    Article  Google Scholar 

  36. McGuire K, McDonnell J (2007) Stable isotope tracers in watershed hydrology. Blackwell Publishers, Boston

    Google Scholar 

  37. Meng Y, Liu G (2013) Stable isotopic information for hydrological investigation in Hailuogou watershed on the eastern slope of Mount Gongga, China. Environ Earth Sci 69:29–39. https://doi.org/10.1007/s12665-012-1931-5

    Article  Google Scholar 

  38. Meng Y, Liu G (2016) Isotopic characteristics of precipitation, groundwater, and stream water in an alpine region in southwest China. Environ Earth Sci. https://doi.org/10.1007/s12665-016-5697-z

    Article  Google Scholar 

  39. Pfahl S, Sodemann H (2014) What controls deuterium excess in global precipitation? Clim Past 10:771–781. https://doi.org/10.5194/cp-10-771-2014

    Article  Google Scholar 

  40. Ren W, Yao T, Xie S, He Y (2017) Controls on the stable isotopes in precipitation and surface waters across the southeastern Tibetan Plateau. J Hydrol 545:276–287. https://doi.org/10.1016/j.jhydrol.2016.12.034

    Article  Google Scholar 

  41. Shen H, Poulsen CJ (2019) Precipitation δ18O on the Himalaya-Tibet orogeny and its relationship to surface elevation. Clim Past 15:169–187. https://doi.org/10.5194/cp-15-169-2019

    Article  Google Scholar 

  42. Skrzypek G, Mydłowski A, Dogramaci S, Hedley P, Gibson JJ, Grierson PF (2015) Estimation of evaporative loss based on the stable isotope composition of water using Hydrocalculator. J Hydrol 523:781–789. https://doi.org/10.1016/j.jhydrol.2015.02.010

    Article  Google Scholar 

  43. Sundqvist MK, Sanders NJ, Wardle DA (2013) Community and ecosystem responses to elevational gradients: processes, mechanisms, and insights for global change. Annu Rev Ecol Evol Syst 44:261–280. https://doi.org/10.1146/annurev-ecolsys-110512-135750

    Article  Google Scholar 

  44. Tian L et al (2007) Stable isotopic variations in west China: A consideration of moisture sources. J Geophys Res-Atmos. https://doi.org/10.1029/2006jd007718

    Article  Google Scholar 

  45. Tian L, Yao T, Numaguti A, Duan K (2001a) Relation between stable isotope in monsoon precipitation in southern Tibetan Plateau and moisture transport history. Sci China Ser D 44:267–274. https://doi.org/10.1007/bf02911996

    Article  Google Scholar 

  46. Tian L, Yao T, Sun W, Stievenard M, Jouzel J (2001b) Relationship between δD and δ18O in precipitation on north and south of the Tibetan Plateau and moisture recycling. Sci China Ser D 44:789–796. https://doi.org/10.1007/bf02907091

    Article  Google Scholar 

  47. Wang Y (2016) Study on geoheritage landscape features and formation of Guan’egou Geopark. Chengdu University of Technology, Gansu province, China Sichuan Province (in Chinese with English abstract)

    Google Scholar 

  48. Wassenaar LI, Athanasopoulos P, Hendry MJ (2011) Isotope hydrology of precipitation, surface and ground waters in the Okanagan Valley, British Columbia, Canada. J Hydrol 411:37–48. https://doi.org/10.1016/j.jhydrol.2011.09.032

    Article  Google Scholar 

  49. Wen R, Tian L, Weng Y, Liu Z, Zhao Z (2012) The altitude effect of δ18O in precipitation and river water in the Southern Himalayas. Chinese Sci Bull 57:1693–1698. https://doi.org/10.1007/s11434-012-4992-7

    Article  Google Scholar 

  50. Wu GL, Zhang ZN, Wang D, Shi ZH, Zhu YJ (2014) Interactions of soil water content heterogeneity and species diversity patterns in semi-arid steppes on the Loess Plateau of China. J Hydrol 519:1362–1367. https://doi.org/10.1016/j.jhydrol.2014.09.012

    Article  Google Scholar 

  51. Wu H et al (2019a) Spatial and temporal variability of stable isotopes (δ18O and δ2H) in surface waters of arid, mountainous Central Asia. Hydrol Process 33:1658–1669. https://doi.org/10.1002/hyp.13429

    Article  Google Scholar 

  52. Wu H, Wu J, Song F, Abuduwaili J, Saparov AS, Chen X, Shen B (2019b) Spatial distribution and controlling factors of surface water stable isotope values (δ18O and δ2H) across Kazakhstan, Central Asia. Sci Total Environ 678:53–61. https://doi.org/10.1016/j.scitotenv.2019.03.389

    Article  Google Scholar 

  53. Xing B, Liu Z, Liu G, Zhang J (2015) Determination of runoff components using path analysis and isotopic measurements in a glacier-covered alpine catchment (upper Hailuogou Valley) in southwest China. Hydrol Process 29:3065–3073. https://doi.org/10.1002/hyp.10418

    Article  Google Scholar 

  54. Yang K, Ye B, Zhou D, Wu B, Foken T, Qin J, Zhou Z (2011) Response of hydrological cycle to recent climate changes in the Tibetan Plateau. Clim Change 109:517–534. https://doi.org/10.1007/s10584-011-0099-4

    Article  Google Scholar 

  55. Yang X, Xu B, Yang w, Qu D, Lin P, (2009) Study of altitudinal lapse rates of δ18O in precipitation/river water with seasons on the southeast Tibetan Plateau. Chin Sci Bull 54:2742–2750. https://doi.org/10.1007/s11434-009-0496-5

    Article  Google Scholar 

  56. Yao T et al (2013) A review of climatic controls on δ18O in precipitation over the Tibetan Plateau: Observations and simulations. Rev Geophy 51:525–548. https://doi.org/10.1002/rog.20023

    Article  Google Scholar 

  57. Yin G, Fan X, Guo J, Yang J (2000) Isotope tracer on water cycle system in Jiuzhaigou, Sichuan. Acta Geograp Sinica 55 (in Chinese with English abstract)

  58. Zhang W et al (2010) Using stable isotopes to determine the water sources in alpine ecosystems on the east Qinghai-Tibet plateau, China. Hydrol Process 24:3270–3280. https://doi.org/10.1002/hyp.7754

    Article  Google Scholar 

  59. Zhou S, Nakawo M, Sakai A, Matsuda Y, Duan K, Pu J (2007) Water isotope variations in the snow pack and summer precipitation at July 1 Glacier, Qilian Mountains in northwest China. Chinese Sci Bull 52:2963–2972. https://doi.org/10.1007/s11434-007-0401-z

    Article  Google Scholar 

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Acknowledgements

We thank the assistance and support by Tanchang County People's Government, Forestry Bureau of Tanchang County, and Guan’egou National Forest Park on the field work. This study was supported by National Natural Science Foundation of China (No. 41730855), State Key Project of Research and Development Plan (2016YFA0600802).

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  1. School of Earth System Science, Tianjin University, Tianjin, 300072, China

    Zhongcong Sun, Chaochen Hu, Di Wu & Xueyan Liu

  2. College of Forestry, Gansu Agricultural University, Lanzhou, 730070, Gansu Province, China

    Guopeng Chen

  3. Key Laboratory of Biosafety, Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment, Nanjing, 210042, Jiangsu, China

    Xiaoqiang Lu

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  1. Zhongcong Sun
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Sun, Z., Hu, C., Wu, D. et al. Estimation of evaporation losses based on stable isotopes of stream water in a mountain watershed. Acta Geochim 40, 176–183 (2021). https://doi.org/10.1007/s11631-021-00452-8

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Keywords

  • Water stable isotopes
  • Mountain watersheds
  • Water evaporation losses
  • Altitude effect
  • Rayleigh fractionation