Abstract
The influencing factors for liquid phase catalytic oxidation of mine gas to methanol (in form of CH3COOCH3) are studied using the self-established experimental apparatus. The results show that CH3COOCH3 (target product) is obtained by using CH3COOH as reaction solvent, and the yield of target product increases with the increasing of reaction temperature, gas pressure and reaction time. In the mine gas-Pd(OAc)2-CH3COOH system, the yield of CH3COOCH3 increases with the increasing of addition of Pd(OAc)2 which is redox catalyst for mine gas conversion. The yield of CH3COOCH3 will be greatly improved by composite additional oxidant which is obtained by equimolar mix of p-benzoquinone with NO2.
Similar content being viewed by others
References
An Zengjian (2008) Selective Oxidation of Methane at Mild Conditions and Liquid Phase [M]. Dalian Instiute of Chemical Physics, Chinese Academy of Sciences. Dalian, China (in Chinese).
Bosch E., Rathore R., and Kochi J.K. (1994) Novel catalysis of hydroquinone autooxidation with nitrogen oxides [J]. Journal of Organic Chemistry. 59, 2529–2536.
Chen Lin (2010) Applied Basic Research on Cold Plasma-catalytic Oxidation of Methane to Methanol [D]. Hangzhou, Zhejiang University, China (in Chinese).
Fan Yafang, Wang Chunlei, Ma Ding, and Bao Xinhe (2010) Selective oxidation of methane to methanol over palladium-metallophthalocyanine composite catalysts at room temperature [J]. Chinese Journal of Catalysis. 31, 302–306 (in Chinese)
Kao L.C., Huston A.C., and Sen A. (1991) Low-temperature palladium (II)-catalyzed solution-phase oxidation of methane to methanol derivative [J]. Journal of the American Chemical Society. 113, 700–701.
Lin M. and Sen A. (1992) A highly catalytic system for the direct oxidation of lower alkanes by dioxygen in aqueous medium [J]. Journal of the American Chemical Society. 114, 7307–7308.
Porth S., Bats J.W., Trauner D., Giester G., and Mulzer J. (1999) Insight into the mechanism of the saegusa oxidation: Isolation of a novel palladium (0) Tetraolefin Complex [J]. Angewandte Chemie International Edition. 38, 2015–2016.
Xu Feng and Zhu Lihua (2012) Kinetic influence on partial oxidation of methane to methanol in liquid phase by V2O5 catalyst [J]. Journal of Heilongjiang Institute of Science and Technology. 22, 14–16 (in Chinese).
Yamanaka I., Soma M., and Otsuka K. (1995) Oxidation of methane to methanol with oxygen catalyzed by Europium trichloride at room temperature [J]. Journal of the Chemical Society-Chemical Communications. 21, 2235–2236.
Yoshihiko I., Toshikazu H., and Takeo S. (1978) Synthesis of Alpha, Beta-unsaturated carbonyl compounds by palladium (II) catalyzed dehydrosilylation of silyl enol ethers [J]. Journal of Organic Chemistry. 43, 1011–1013.
Zhang Jin, Chen Liyu, and Hong Lin (2008) Methane partial oxidation catalyzed by I2 in acetic acid solution [J]. Chemical Industry and Engineering Progress. 27, 473–475 (in Chinese).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Zhu, L., Xu, F., Bi, Y. et al. Influencing factors for catalytic oxidation of mine gas to methanol in liquid phase. Chin. J. Geochem. 33, 183–186 (2014). https://doi.org/10.1007/s11631-014-0676-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11631-014-0676-0