Abstract
Six soils located within the Polish Carpathians, developed on calcium carbonate–rich sedimentary parent materials and representing various reference groups, were investigated in order to detect the lithic discontinuity. We propose using a multidirectional approach to assess the lithic discontinuity in these soils, one that includes grain size distribution, geochemical composition, heavy mineral content and micromorphology, supported by a traditional soil survey. A further aim of this process was to identify the possible admixture of allochthonous material of aeolian origin. The studied soils presented lithic discontinuities mostly at the contact of underlying calcium carbonate–rich coarsegrained slope deposits with the overlaying colluvium layer having a lower content of rock fragments. The significant changes in grain size distribution, especially in the silt and sand content, as well as high Uniformity Values and partially, high Lithological Discontinuity Index values, confirmed the occurrence of a lithic discontinuity in all studied soils. High heterogeneity in the soil profiles was also confirmed by the distribution of the major oxides; however, their distribution did not clearly indicate the lithic discontinuity. The most visible distinctions were noted from CaO content, which resulted from the deposition of carbonate-free materials (aeolian silts) and their mixing with the calcium carbonate–rich parent material. Furthermore, the analysis of heavy mineral content confirmed the allochthonous origin of the upper (and in some cases also the middle) parts of all profiles, which was manifested by the presence of highly weathering-resistant minerals such as zircon, epidote and various types of garnets. The micromorphological features of some of the studied soils showed distinctiveness within the soil profile, manifested by changes in b-fabric pattern, the occurrence and distribution of secondary carbonate and the coarse and fine coarse and fine ratio. Based on the high content of silt within the upper and middle parts of the soils, the content of Hf and Zr, as well as the higher content of weathering-resistant minerals, admixture of aeolian silt could be considered in some of the studied soils, yet with weak character. However, the dominance of minerals typical for metamorphic and igneous rocks suggested that the supply of aeolian silt was associated with loess covers rather than local sedimentary material.
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Abbreviations
- LDI1, LD2:
-
Lithological Discontinuity Index
- UV1, UV2:
-
Uniformity Values
- Adr/Grs:
-
Andradite/ Grossular
- Alm:
-
Almandine
- Alm/Grs:
-
Almandine/ Grossular
- Ca-Am:
-
Ca-Amphibole
- Ep:
-
Epidote
- Ilm:
-
Ilmenite
- Na-Am:
-
Na-Amphibole
- Ortho-Am:
-
Ortho-Amphibole
- Prp:
-
Pyrope
- Py:
-
Pyrite
- TiOx :
-
Titanium oxide
- Zrn:
-
Zircon
References
Ahr SW, Nordt LC, Driese SG (2012) Assessing lithologic discontinuities and parent material uniformity within the Texas sandy mantle and implications for archaeological burial and preservation potential in upland settings. Quaternary Research (United States)U+ 78(1): 60–71. https://doi.org/10.1016/j.yqres.2012.03.013
Ande OT, Senjobi B (2010) Lithologic discontinuity and pedogenetic characterization on an aberrant toposequence associated with a rock hill in South Western Nigeria. International Journal of the Physical Sciences 5(5): 596–604
Arnold RW (1968) Pedological significance of lithologic discontinuities. - Trans. 9th international Congress of Soil Science 4: 595–603.
Asikainen CA, Francus P, Brigham-Grette J (2007) Sedimentology, clay mineralogy and grain-size as indicators of 65 ka of climate change from El’gygytgyn Crater Lake, Northeastern Siberia. Journal of Paleolimnology 37(1): 105–122. https://doi.org/10.1007/s10933-006-9026-5
Birkeland PW, Shroba RR, Burns SF, et al. (2003) Integrating soils and geomorphology in mountains - an example from the Front Range of Colorado. Geomorphology 55: 329–344. https://doi.org/10.1016/S0169-555X(03)00148-X
Bockheim JG, Douglass DC (2006) Origin and significance of calcium carbonate in soils of southwestern Patagonia. Geoderma 136: 751–762. https://doi.org/10.1016/j.geoderma.2006.05.013.
Bockheim JG, Hartemink AE (2013) Distribution and classification of soils with clay-enriched horizons in the USA. Geoderma 209-210: 153–160. https://doi.org/10.1016/j.geoderma.2013.06.009
Bockheim JG (2016) Genesis of soils with an abrupt textural contrast in the United States. Catena 137: 422–431. https://doi.org/10.1016/j.catena.2015.10.011
Bucci F, Mirabella F, Santangelo M, et al. (2016) Photo-geology of the Montefalco Quaternary Basin, Umbria, Central Italy. Journal of Maps 5647: 1–9. https://doi.org/10.1080/17445647.2016.1210042
Bullock P, Fedoroff N, Jongerius A, et al. (1985) Handbook for Soil Thin Section Description. Waine Research Publications Wolverhampton, UK. pp 152.
Butler BE (1959) Periodic Phenomena in Landscapes as a Basis for Soil Studies. CSIRO, Melbourne, Australia, Soil publication 14.
Caspari T, Baeumler R, Norbu C, et al. (2006) Geochemical investigation of soils developed in different lithologies in Bhutan, Eastern Himalayas. Geoderma 136(1-2): 436–458. https://doi.org/10.1016/j.geoderma.2006.04.017
Chapman SL, Horn ME (1968) Parent material uniformity and origin of silty soils in northwest Arkansas based on zirconium-titanium contents. Soil Science Society of America Journal 32: 265–271. https://doi.org/10.2136/sssaj1968.03615995003200020030x
Chmal H, Traczyk A (1998) Postglacial morphological development of the Karkonosze and Izerskie Mountains in the light of river, limnic and slope sediments analysis. In: Sarosiek J. (Ed.), Geoecological problems of the Karkonosze Mountains. Poznan. pp 81–87. (In Polish, with English abstract)
Costantini EAC, Damiani D (2004) Clay minerals and the development of Quaternary soils in central Italy. Revista Mexicana de Ciencias Geologicas 21(1): 144–159.
Cremeens DL, Mokma DL (1986) Argillic horizon expression and classification in the soils of two Michigan hydrosequences. Soil Science Society of America Journal 50: 1002–1007. https://doi.org/10.2136/sssaj1986.03615995005000040034x
Durand N, Monger HC, Canti MG (2010) Calcium carbonate features. In: Stoops G, Marcelino V, Mees F (eds.), Interpretation of Micromorphological Features of Soils and Regoliths. Elsevier, Amsterdam 149–194. https://doi.org/10.1016/C2009-0-18081-9
FAO (2006) Guidelines for Soil Description. fourth ed. pp109. Rome: FAO.
Fedoroff N, Courty MA, Guo Z (2010) Palaeosoils and Relict Soils. In: Marcelino V, Mees F. (Eds.), Interpretation of Micromorphological Features of Soils and Regoliths. Elsevier, Amsterdam, 623–662. https://doi.org/10.1016/C2009-0-18081-9
Fedo CM, Nesbitt HW, Young GM (1995) Unraveling the effects of potassium metasomatism in sedimentary rocks and paleosols with implications for paleoweathering conditions and provenance. Geology 23: 921–924. https://doi.org/10.1130/0091-7613(1995)023<0921:UTEOPM>2.3.CO;2
Fernández-Lavado C, Furdada G, Marqués MA (2007) Geomorphological method in the elaboration of hazard maps for flash-floods in the municipality of Jucuarán (El Salvador). Natural Hazards and Earth System Science 7: 455–465.
Galović L, Peh Z (2014) Eolian contribution to geochemical and mineralogical characteristics of some soil types in Medvednica Mountain, Croatia. Catena 117: 145–156. https://doi.org/10.1016/j.catena.2013.12.016
GeoLog (2019) https://geolog.pgi.gov.pl/ (Accessed on October 2019).
Gunal H, Ransom MD (2006) Genesis and micromorphology of loess-derived soils from central Kansas. Catena 65(3): 222–236. https://doi.org/10.1016/j.catena.2013.12.01610.1016/j.catena.2005.11.018
Hall R, Davis LG, Willis S, et al. (2005) Radiocarbon, soil, and artifact chronologies for an early southern Oregon coastal site. Radiocarbon 47(3): 383–394.
Holliday VT, Surovell T, Meltzer DJ, et al. (2014) The Younger Dryas impact hypothesis: A cosmic catastrophe. Journal of Quaternary Science 29(6): 515–530. https://doi.org/10.1016/S0016-7061(02)00377-4
Howard JL, Olszewska D (2011) Pedogenesis, geochemical forms of heavy metals, and artifact weathering in an urban soil chronosequence, Detroit, Michigan. Environmental Pollution 159: 754–761. https://doi.org/10.1016/j.envpol.2010.11.028
Ibrahim MA, Lee Burras C, Steele J, et al. (2011) Munterville: A New Soil Series in Iowa. Soil Survey Horizons 52(4): 103–110. https://doi.org/10.2136/ssh2011-52-4-1
IUSS Working Group WRB (2015) World Reference Base for Soil Resources 2014, update 2015. International soil classification system for naming soils and creating legends for soil maps. World Soil Resources Reports No. 106. FAO, Rome, 182.
Jaworska H, Dąbkowska-Naskręt H, Kobierski M (2014) The influence of litho- and pedogenic processes on Luvisols formation of selected area of Vistula Glaciation. Geological Quarterly 58(4): 685–694. https://doi.org/10.7306/gq.1175
Kacprzak A, Derkowski A (2007) Cambisols developed from cover-beds in the Pieniny Mts. (southern Poland) and their mineral composition. Catena 71 (2): 292–297. https://doi.org/10.1016/j.catena.2007.01.004
Kacprzak A, Klimek M, Wójcik-Tabol P, et al. (2010) Lithological discontinuities in the soil catena of Góra Zamkowa at Lanckorona (Wieliczka Foothills, Southern Poland), Prace Geograficzne 123: 83–98.
Kacprzak A, Salamon P (2013) Properties and classification of soils developed from Aeolian and flysch materials in the Wieliczka Foothills (Southern Poland). Gruntoznavstvo 14: 52–62.
Kondracki J (1989) Carpathians. Wydawnictwa Szkolne i Pedagogiczne, Warszawa. (In Polish)
Kowalska J, Mazurek R, Gąsiorek M, et al. (2016) Soil pollution indices conditioned by medieval metallurgical activity - a case study from Krakow (Poland). Environmental Pollution 218: 1023–1036. https://doi.org/10.1016/j.envpol.2016.08.053
Kowalska J, Kajdas B, Zaleski T (2017) Variability of morphological, physical and chemical properties of soils derived from carbonate-rich parent material in the Pieniny Mountains (south Poland). Soil Science Annual 68 (1): 27–38. https://doi.org/10.1515/ssa-2017-0004
Kowalska JB, Zaleski T, Józefowska A, et al. (2019) Soil formation on calcium carbonate-rich parent material in the outer Carpathian Mountains - A case study. Catena 174: 436–451. https://doi.org/10.1016/j.catena.2018.11.025
Krasilnikov PV García Calderóna N, Sedov SN, et al. (2005) The relationship between pedogenic and geomorphic processes inmountainous tropical forested area in Sierra Madre del Sur, Mexico. Catena 62: 14–44. https://doi.org/10.1016/j.catena.2005.02.003
Kuzila MS (1995) Identification of multiple loess units within modern soils of Clay County, Nebraska. Geoderma 65: 45–57. https://doi.org/10.1016/0016-7061(94)00030-E
Küfmann C (2008) Are cambisols in alpine karst autochthonous or Eolian in origin. Arctic, Antarctic, and Alpine Research 40: 506–518. https://doi.org/10.1657/1523-0430(06-091)[KUEFMANN]2.0.CO;2
Liebens J (1999) Characteristics of soils on debris aprons in the Southern Blue Ridge, North Carolina. Physical Geography 20: 27–52. https://doi.org/10.1080/02723646.1999.10642667
Ligęza S (2009) Determination of lithological discontinuities within the soils. Soil Science Annual 60(1): 77–84.
Lityński T, Jurkowska H, Gorlach E (1976) Chemical-Agricultural Analysis. PWN, Warszawa 332 (In Polish).
Loba A, Sykuła M, Kierczak J, et al. (2019) In situ weathering of rocks or aeolian silt deposition: key parameters for verifying parent material and pedogenesis in the Opawskie Mountains — a case study from SW Poland. Journal of Soils and Sediments 20(1):435–451. https://doi.org/10.1007/s11368-019-02377-5
Lorz C, Phillips J (2006) Pedo-Ecological Consequences of Lithological discontinuities in soils. Examples from Central Europe. Journal of Plant Nutrition and Soil Science 169: 573–581. https://doi.org/10.1002/jpln.200521872
Lorz C (2008) Lithological Discontinuous Soils - Archives for the Pedo-Geochemical Genesis of the Soil-Regolith-Complex? Zeitschrift für Geomorphologie, Supplementary Issues 52: 119–132. https://doi.org/10.1127/0372-8854/2008/0052S2-0119
Lorz C, Frühauf M, Mailänder R, Phillips JD (2010) Lithologic discontinuities in cover beds influencing soil evolution and soil properties. Geophysical Research Abstracts 12: 63–68.
Lorz C et al. (2013) Influence of Cover Beds on Soils. In: Kleber A, Terharst B (Eds.), Mid-Latitude Slope Deposits (Cover Beds), Elsevier. pp 95–125.
Marcinkowski B, Mycielska-Dowgiałło E (2013) Heavy-mineral analysis in Polish investigations of Quaternary deposits: a review. Geologos 19: 1–2, 5–23. https://doi.org/10.2478/logos-2013-0002
Martignier L, Adatte T, Verrecchia EP (2012) Bedrock versus superficial deposits in the Swiss Jura Mountains: what is the legitimate soil parent material? Earth Surface Processes and Landforms 38: 331–345. https://doi.org/10.1016/j.aeolia.2015.05.003
Martignier L, Verrecchia EP (2013) Weathering processes in superficial deposits (regolith) and their influence on pedogenesis: A case study in the Swiss Jura Mountains. Geomorphology 189: 26–40. https://doi.org/10.1016/j.geomorph.2012.12.038
Martignier L, Nussbaumer M, Adatte T, et al. (2015) Assessment of a locally-sourced loess system in Europe: the Swiss Jura Mountains. Aeolian Research 18: 11–21. https://doi.org/10.1016/j.aeolia.2015.05.003
Migoń P, Kacprzak A (2014) Lateral diversity of regolith and soils under a mountain slope - implications for interpretation of hillslope materials and processes, Central Sudetes, SW Poland. Geomorphology 221: 69–82. https://doi.org/j.geomorph.2014.06.003
Mücher H, van Steijn H, Kwaad F (2010) Colluvial and mass wasting deposits. In: Stoops G, Marcelino V, Mees F. (eds.), Interpretation of Micromorphological Features of Soils and Regoliths. Elsevier, Amsterdam 37–48. https://doi.org/10.1016/j.catena.2013.12.016 https://doi.org/10.1016/C2009-0-18081-9
Muhs DR (2018) The geochemistry of loess: Asian and North American deposits compared. Journal of Asian Earth Sciences 155: 81–115. https://doi.org/10.1016/j.jseaes.2017.10.032
Munsell (1975) Standard Soil Color Charts.
Musztyfaga E, Kabała C (2015) Lithological discontinuity in Glossic Planosols (Albeluvisols) of Lower Silesia (SW Poland). Soil Science Annual 66(4): 180–190. https://doi.org/10.1515/ssa-2015-0035
Otrębska-Starklowa B, Hess M, Olecki Z, et al. (1995) Karpaty Polskie. In: Warszyńska J (Eds.) Klimat. Uniwersytet Jagielloński 31–48. (In Polish)
Oszczypko N (1995) Karpaty Polskie. In: Warszyńska J (Eds.), Budowa geologicnza. Uniwersytet Jagielloński 15–22 (in Polish).
Palumbo B, Angelone M, Bellanca A, et al. (2000) Influence of inheritance and pedogenesis on heavy metal distribution in soils of Sicily, Italy. Geoderma 95: 3–4, 247–266. https://doi.org/10.1016/S0016-7061(99)00090-7
Phillips JD (2004) Geogenesis, Pedogenesis, and multiple Causality in the Formation of Texture-Contrast Soils. - Catena 58(2): 275–295. https://doi.org/10.1016/j.catena.2004.04.002
Philips JD (2007) Development of texture contrast soils by a combination of bioturbation and translocation, Catena 70: 92–104. https://doi.org/10.1016/j.catena.2006.08.002
Pike AS, Scatena FN, Wohl EE (2010) Lithological and fluvial controls on the geomorphology of tropical montane stream channels in Puerto Rico. Earth Surface Processes and Landforms 35(12): 1402–1417. https://doi.org/10.1002/esp.1978
Polish Standard (1998) Soil and mineral soil materials — sampling and determination of particle size distribution. PNR-04032. Polish Committee for Standardization, Warszawa (In Polish).
Priori S, Costantini EAC (2010) Geographic relevance of Late Pleistocene and Middle Holocene aeolian deposits in Central Tuscany (Italy). 19th World Congress of Soil Science, Soil Solutions for a Changing World Brisbane, Australia 9-12.
Sauer D, Schülli-Maurer I, Wagner S,, et al. (2015) Soil development over millennial timescales-a comparison of soil chronosequences of different climates and lithologies. IOP Conference Series: Earth and Environmental Science 25(1): 12009. https://doi.org/10.1088/1755-1315/25/1/012009
Schaetzl RJ (1998) Lithologic Discontinuities in some soils on Drumlins: theory, detection, and application. Soil Science 163(7): 570–590.
Schaetzl R, Anderson S (2005) Soils, Genesis and Geomorphology. Cambridge (Cambridge University Press), 817.
Schaetzl RJ (2008) The distribution of silty soils in the Grayling Fingers region of Michigan: evidence for loess deposition onto frozen ground. Geomorphology 102: 287–296.
Scheib AJ, Birke M, Dinelli E, et al. (2014) Geochemical evidence of aeolian deposits in European soils. Boreas 43: 175–192. https://doi.org/10.1111/bor.12029
Scheib AJ, Lee J (2010) Mapping Late Pleistocene and Holocene aeolian sediments in East Anglia, UK: the application of regionalscale geochemical data. Quaternary Newsletter 120: 5–14.
Sha LK, Chappelle BW (1999) Apatite chemical composition, determined by electron microprobe laser ablation inductively coupled plasma mass spectrometry, as a probe into granite petrogenesis. Geochimica et Cosmochimica Acta 63: 3861–3881. https://doi.org/10.1016/S0016-7037(99)00210-0
Semmel A, Terhorst B (2010) The concept of periglacial cover beds in central Europe: A review. Quaternary International 222: 120–128. https://doi.org/10.1016/j.quaint.2010.03.010
Skiba S (1995) Karpaty Polskie. In: Warszyńska J (Eds.), Pokrywa glebowa. Uniwersytet Jagielloński 69–76 (In Polish).
Stoops G (2003) Guidelines for analysis and description of soil and regolith thin sections. Soil Science Society of America, Inc. Madison, Wisconsin, USA, 184. https://doi.org/10.1017/S002185960322339X
Stoops G, Marcelino V, Mees F (2010) Micromorphological Features and Their Relation to Processes and Classification: General Guidelines and Keys. In: Stoops G, Marcelino V, Mees F (Eds.) Interpretation of Micromorphological Features of Soils and Regoliths. Elsevier, Amsterdam 15–36. https://doi.org/10.1016/C2009-0-18081-9
Towpasz K, Zemanek B (1995) Karpaty Polskie. In: Warszyńska J (Eds.), Szata Roślinna. Uniwersytet Jagielloński 77–94. (In Polish).
Waroszewski J, Kabała C, Koszelnik K (2013) Litological discontinuities in Podzols developed from Upper Cretaceous sandstones in the Stołowe Mountains, Geographic Works. pp 87–100.
Waroszewski J, Malkiewicz M, Mazurek R, et al. (2015) Lithological discontinuities in Podzols developed from sandstone cover beds in the Stolowe Mountains (Poland). Catena 126: 11–19. https://doi.org/10.1016/j.catena.2014.10.034
Waroszewski J, Egli M, Kabała C, et al. (2016) Mass fluxes and clay mineral formation in soils developed on slope deposits of the Kowarski Grzbiet (Karkonosze Mountains, Czech Republic/Poland). Geoderma 264: 363–378. https://doi.org/10.1016/j.geoderma.2015.08.044
Waroszewski J, Sprafke T, Kabała C, et al. (2018a) Aeolian silt contribution to soils on mountain slopes (Mt. Ślęża, southwest Poland). Quaternary Research 89(3):1–16. https://doi.org/10.1017/qua.2017.76
Waroszewski J, Egli M, Brandová D, et al. (2018b) Identifying slope processes over time and their imprint in soils of medium-high mountains of Central Europe (the Karkonosze Mountains, Poland). Earth Surface Processes and Landforms 43: 1195–1212. https://doi.org/10.1002/esp.4305
Waroszewski J, Sprafke T, Kabała C, et al. (2019) Tracking textural, mineralogical and geochemical signatures in soils developed from basalt-derived materials covered with loess sediments (SW Poland). Geoderma 337: 983–997. https://doi.org/10.1016/j.geoderma.2018.11.008
Waroszewski J, Sprafke T, Kabała C, et al. (2020) Chronostratigraphy of silt-dominated Pleistocene periglacial slope deposits on Mt. Ślęża (SW, Poland): Palaeoenvironmental and pedogenic significance. Catena 190: 104549. https://doi.org/10.1016/j.catena.2020.104549
Warszyńska J (1995) Karapty Polskie. Przyroda, człowiek i jego działalność. Uniwersytet Jagielloński, Kraków (in Polish).
Weindorf DC, Chakraborty S, Abdalsatar A et al. T (2015) Lithologic discontinuity assessment in soils via portable X-ray fluorescence spectrometry and visible near-infrared diffuse reflectance spectroscopy. Soil Science Society of America Journal 79(6): 1704–1716. https://doi.org/10.2136/sssaj2015.04.0160
Wicik B (1986) Asynchronicity of the weathering and sedimentation processes in the lakes of the Tatra and Karkonosze Mountains in the Post-Glacial period. Przeglad Geograficzny 58: 809–823 (in Polish, with English abstract).
Yang F et al. (2016) Pedogenetic interpretations of particle-size distribution curves for an alpine environment. Geoderma 282: 9–15. https://doi.org/10.1016/j.geoderma.2016.07.003
Zamanian K, Pustovoytov K, Kuzyakov Y (2016) Pedogenic carbonates: Forms and formation processes. Earth-Science Reviews 157: 1–17. https://doi.org/10.1016/j.earscirev.2016.03.003
Acknowledgements
This research was financed by the National Science Centre (Poland) (PRELUDIUM 14 project no. 2017/27/N/ST10/00342) and Ministry of Science and Higher Education of the Republic of Poland, No. BM–4112/17 and BM–2120/18. The authors are indebted to the reviewers for their constructive remarks and comments on an earlier version of the manuscript.
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Kowalska, J.B., Kajdas, B. & Zaleski, T. Lithological indicators of discontinuities in mountain soils rich in calcium carbonate in the Polish Carpathians. J. Mt. Sci. 17, 1058–1083 (2020). https://doi.org/10.1007/s11629-019-5842-8
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DOI: https://doi.org/10.1007/s11629-019-5842-8