Skip to main content
Log in

Development of grouting materials with application to the protection of the geological relics of the Weng’an Biota

  • Published:
Journal of Mountain Science Aims and scope Submit manuscript

Abstract

The Weng’an Biota, a fossil Konservat-Lagerstätte in South China that is c. 570 – 609 myr old, preserves the world’s oldest zoolite and provides a unique empirical record for studying animal origins and early evolution. Due to geological disasters caused by the exploitation of the local phosphate mine, part of the fossilized records and the geological sections of the Weng’an Biota have been seriously damaged. Protection of this unique fossil area is urgently required. In this research, an innovative scheme for the protection of the geological relics of the Weng’an Biota is proposed by backfilling the mine cavity with specially formulated grouting materials. In view of the shortcomings of the current grouting materials, such as the high proportion of water separation, the low stone percentage and high cost, newly developed grout materials consisting of mixtures of cement-fly ash-expansion agent (C-F-E) were systematically studied by a combined method of theoretical analysis and experimental study. Firstly, new grouting materials (C-F-E) were developed using selected proportions of (1) Portland cement (P·O 32.5), (2) external admixture (Fly ash), (3) expansion agent (NV) and (4) admixture (DFZ). Then, the properties of new grouting materials (C-F-E), such as stability, stone percentage, rheology, fluidity, setting time and compressive strength were evaluated by laboratory tests. Finally, a new model of the hydration process was proposed for these newly developed grouting materials based on a detailed scanning electron microscopy (SEM) study of their microstructural development. These research results will provide an effective solution to the protection of the geological relics of the Weng’an Biota. Additionally, these grouting materials may prove suitable for solving similar problems in the management of most mine cavities requiring stabilization in the future.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Anagnostopoulos CA (2007) Cement-clay grouts modified with acrylic resin or methyl methacrylate ester: physical and mechanical properties. Construction & Building Materials 21(2): 252–257. https://doi.org/10.1016/j.conbuildmat.2005.12.007

    Article  Google Scholar 

  • Anagnostopoulos CA (2014) Effect of different superplasticisers on the physical and mechanical properties of cement grouts. Construction & Building Materials 50(1): 162–168. https://doi.org/10.1016/j.conbuildmat.2013.09.050

    Article  Google Scholar 

  • Azadi MR, Taghichian A, Taheri A (2017) Optimization of cement-based grouts using chemical additives. Journal of Rock Mechanics and Geotechnical Engineering 9(4): 623–637. https://doi.org/10.1016/j.jrmge.2016.11.013

    Article  Google Scholar 

  • Celik F, Canakci H (2015) An investigation of rheological properties of cement-based grout mixed with rice husk ash (rha). Construction & Building Materials 91(2015): 187–194. https://doi.org/10.1016/j.conbuildmat.2015.05.025

    Article  Google Scholar 

  • Chen L, Xiao S, Pang K, et al. (2014) Cell differentiation and germ-soma separation in ediacaran animal embryo-like fossils. Nature 516(7530): 238–241. https://doi.org/10.1038/nature13766

    Article  Google Scholar 

  • Dornbos S, Bottjer D, Chen JY, et al. (2006) Environmental controls on the taphonomy of phosphatized animals and animal embryos from the neoproterozoic doushantuo formation, southwest china. Palaios 21(1): 3–14. https://doi.org/10.2110/palo.2004.p04-37

    Article  Google Scholar 

  • El-Gamal SMA, Abo-El-Enein SA, Ahmed NED, et al. (2019) Effect of novel binaphthol derivative admixture on the hydration characteristics, rheological and mechanical properties of ordinary portland cement pastes. Advances in Cement Research 31(7): 331–342. https://doi.org/10.1680/jadcr.17.00051

    Article  Google Scholar 

  • Fu X, Wang Z, Tao W, et al. (2002) Studies on blended cement with a large amount of fly ash. Cement and Concrete Research 32(7): 1153–1159. https://doi.org/10.1016/S0008-8846 (02)00757-3

    Article  Google Scholar 

  • Hagadorn JW, Xiao S, Donoghue PCJ, et al. (2006) Cellular and subcellular structure of Neoproterozoic animal embryos. Science 314(5797): 291–294. https://doi.org/10.1126/science.1133129

    Article  Google Scholar 

  • He W, Fatehi P (2015) Preparation of sulfomethylated softwood kraft lignin as a dispersant for cement admixture. Rsc Advances 5(58): 47031–47039. https://doi.org/10.1039/C5RA04526F

    Article  Google Scholar 

  • Lasheras-Zubiate M, Navarro-Blasco I, J. M. Fernández, et al. (2011) Studies on chitosan as an admixture for cement-based materials: assessment of its viscosity enhancing effect and complexing ability for heavy metals. Journal of Applied Polymer Science 120(1): 242–252. https://doi.org/10.1002/app.33048

    Article  Google Scholar 

  • Li CW, Chen JY, Hua TE (1998) Precambrian sponges with cellular structures. Science 279(5352): 879–882. https://doi.org/10.1126/science.279.5352.879

    Article  Google Scholar 

  • Liu CY, Yang JX, Wu FF (2015) A proposed method of coal pillar design, goaf filling, and grouting of steeply inclined coal seams under water-filled strata. Mine Water & the Environment 34(1): 87–94. https://doi.org/10.1007/s10230-014-0314-4

    Article  Google Scholar 

  • Mirza J, Mirza MS, Roy V, et al. (2002) Basic rheological and mechanical properties of high-volume fly ash grouts. Construction & Building Materials 16(6): 353–363. https://doi.org/10.1016/S0950-0618 (02)00026-0

    Article  Google Scholar 

  • Sha F, Li S, Liu R, et al. (2018) Experimental study on performance of cement-based grouts admixed with fly ash, bentonite, superplasticizer and water glass. Construction & Building Materials 161: 282–291. https://doi.org/10.1016/j.conbuildmat.2017.11.034

    Article  Google Scholar 

  • Sugiarto L, Mavin KC (1986) The effects of a set retarding admixture on the dry density and compressive strength of a soil cement mix following delayed compaction. Thermochimica Acta 390(1–2): 83–91.

    Google Scholar 

  • Tong LY, Pan S, Qiu Y, et al. (2002) Experimental study on filling material with large dosage of fly ash. Journal of Southeast University (natural science edition) 32(4): 643–647. (In Chinese) https://doi.org/10.3321/j.issn:10010505.2002.04.024

    Google Scholar 

  • Twardowska I, Szczepanska J (2002) Solid waste: terminological and long-term environmental risk assessment problems exemplified in a power plant fly ash study. Science of the Total Environment 285(1): 29–51. https://doi.org/10.1016/S0048-9697(01)00893-2

    Article  Google Scholar 

  • Wang GY, Jiang ZQ (2017) Research and application of xanthan gum, a synchronic grouting material in shield tunnel. Modern Tunnel Technology 54(6): 223–226. (In Chinese) https://doi.org/10.13807/j.cnki.mtt.2017.06.030

    Google Scholar 

  • Yin Z, Cunningham JA, Vargas K, et al. (2017) Nuclei and nucleoli in embryo-like fossils from the Ediacaran Weng’an biota. Precambrian Research 301: 145–151. https://doi.org/10.1016/j.precamres.2017.08.009

    Article  Google Scholar 

  • Yin Z, Zhu M, Tafforeau P, et al. (2013) Early embryogenesis of potential bilaterian animals with polar lobe formation from the Ediacaran Weng’an Biota, south china. Precambrian Research 225(1): 44–57. https://doi.org/10.1016/j.precamres.2011.08.011

    Article  Google Scholar 

  • Yin ZJ, Zhu MY, Davidson EH, et al. (2015) Sponge grade body fossil with cellular resolution dating 60 myr before the cambrian. Proc Natl Acad Sci USA 112(12): 1453–1460. https://doi.org/10.1073/pnas.1414577112

    Google Scholar 

  • Zhang Z, Shimada H (2018) Numerical study on the effectiveness of grouting reinforcement on the large heaving floor of the deep retained goaf-side gateroad: a case study in China. Energies 11(4): 1001. https://doi.org/10.3390/en11041001

    Article  Google Scholar 

  • Zhou C, Li XH, Xiao S, et al. (2017) A new sims zircon u–pb date from the ediacaran doushantuo formation: age constraint on the weng’an biota. Geological Magazine 154: 1–9. https://doi.org/10.1017/s0016756816001175

    Article  Google Scholar 

Download references

Acknowledgments

This paper was supported by the National Natural Science Foundation of China (Grant No. 41672362) and the Key projects of Sichuan Provincial Department of Education (Grant No.16ZA0099) and the State Key Laboratory of Geohazard Prevention and Geoenvironment Protection (Grant No. SKLGP2017Z011).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Sheng Wang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, S., Shu, Zh., Guo, Kb. et al. Development of grouting materials with application to the protection of the geological relics of the Weng’an Biota. J. Mt. Sci. 16, 1962–1974 (2019). https://doi.org/10.1007/s11629-019-5394-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11629-019-5394-y

Keywords

Navigation