Journal of Mountain Science

, Volume 15, Issue 10, pp 2236–2246 | Cite as

Deposition of atmospheric pollutant and their chemical characterization in snow pit profile at Dokriani Glacier, Central Himalaya

  • Shipika SundriyalEmail author
  • Tanuj Shukla
  • Lekhendra Tripathee
  • Dwarika Prashad Dobhal
  • Sameer Kumar Tiwari
  • Uday Bhan


The uncertainty in assessing the numerous atmospheric pollutants transported via wind from arid and semi-arid regions is affecting the glacial ecosystem. In our study area due to the complexity of the system, a prominent seasonal difference noticed among major ions (Ca2+, Mg2+, SO42−, and NO3). There is a need for understanding the ions cycling as a whole and the directionality of the feedback loops in the system. Therefore, we provide an appraisal of our current hypothesis for seasonal difference in major ion concentration from snow samples for two corresponding years (2013 and 2015) at Dokriani Glacier. A systematic study of chemical compositions in the shallow snow pit from Dokriani Glacier was undertaken for the pre-monsoon season to understand the cycling of major ions from atmosphere to solute acquisition process. The intimating connections of ions cycling in snow and its temporal behavior was observed and analyzed through various statistical tests. Among major ions, the SO42− has the highest concentration among anions on an average considered as 14.21% in 2013 and 29.46% in 2015. On the other side Ca2+ is the dominant cation contributing 28.22% in 2013 and 15.3% in 2015 on average. The average ratio of Na+/Cl was higher in 2013 whereas lower in 2015. The backward trajectory analysis suggests the possible sources of the ions transported from Central Asia through the Western Disturbance (WD) as a prominent source of winter precipitation mainly in the Central Himalaya. Ionic concentration of Ca2+ in cations was highly dominated while in anion SO42− played the major role. Factor analysis and correlation matrix suggested that, the precipitation chemistry is mostly influenced by anthropogenic, crustal, and sea salt sources over the studied region. The elemental cycling through ocean, atmosphere and biosphere opens up new ways to understand the geochemical processes operating at the glacierized catchments of the Himalaya. Moreover, increasing the field-based studies in the coming decades would also have the certain advantage in overcoming the conceptual and computational geochemical modelling difficulties.


Western disturbance Central Himalaya Factor analysis Correlation analysis Snow Stratigraphy Atmospheric pollutants 


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Authors are grateful to the Director, Wadia Institute of Himalayan Geology, Dehradun and National Institute of Hydrology, Roorkee for providing necessary facilities. This research was funded by the Department of Science and Technology, Government of India, New Delhi. Author would also like to thank Dr Sukesh Kumar Bartartya, Scientist and technical staff of Ion Chromatography laboratory for chemical analysis and the entire field party members who helped during sample collection.


  1. Anderson SP, Drever JI, Humphrey NF (1997) Chemical weathering in glacial environments. Geology 25(5): 399–402.<0399:CWIGE>2.3.CO;2 CrossRefGoogle Scholar
  2. Benn DI, Owen LA (1998) The role of the Indian summer monsoon and the mid–latitude westerlies in Himalayan glaciation: review and speculative discussion. Journal of the Geological Society 155(2): 353–363. CrossRefGoogle Scholar
  3. Bookhagen B, Burbank DW (2010) Toward a complete Himalayan hydrological budget: Spatiotemporal distribution of snowmelt and rainfall and their impact on river discharge. Journal of Geophysical Research Earth Surface 115(F3): F03019. Google Scholar
  4. Budhavant KB, Rao PSP, Safai PD, et al. (2009) Chemistry of monsoon and post–monsoon rains at a high altitude location, Sinhagad, India. Aerosol and Air Quality Research 9(1): 65–79. CrossRefGoogle Scholar
  5. Carrico CM, Bergin MH, Shrestha AB, et al (2003) The importance of carbon and mineral dust to seasonal aerosol properties in the Nepal Himalaya. Atmospheric Environment 37(20): 2811–2824. CrossRefGoogle Scholar
  6. Das R, Das SN, Misra VN (2005) Chemical composition of rainwater and dustfall at Bhubaneswar in the east coast of India. Atmospheric Environment 39(32): 5908–5916. CrossRefGoogle Scholar
  7. Dalai TK, Krishnaswami S, Sarin MM (2002) Major ion chemistry in the headwaters of the Yamuna river system: Chemical weathering, its temperature dependence and CO2 consumption in the Himalaya. Geochimica et Cosmochimica Acta 66(19): 3397–3416. CrossRefGoogle Scholar
  8. Dobhal DP, Gergan JT, Thayyen RJ (2008) Mass balance studies of the Dokriani Glacier from to, Garhwal Himalaya, India. Bulletin of Glaciological Research 25: 9–17.Google Scholar
  9. Draxler RR (2010) Hysplit (hybrid single–particle lagrangian integrated trajectory) model access via NOAA ARL ready website. Available online at: (Accessed at 20 October, 2017)Google Scholar
  10. Garg PK, Shukla A, Jasrotia AS (2017) Influence of topography on glacier changes in the central Himalaya, India. Global and Planetary Change 155(2017): 196–212. CrossRefGoogle Scholar
  11. Gobre T, Salve PR, Krupadam RJ et al. (2010) Chemical composition of precipitation in the coastal environment of India. Bulletin of Environmental Contamination and Toxicology 85(1): 48–53. CrossRefGoogle Scholar
  12. Granat L, Suksomsankh K, Simachaya S, et al. (1996) Regional background acidity and chemical composition of precipitation in Thailand. Atmospheric Environment 30(10): 1589–1596. CrossRefGoogle Scholar
  13. Hasnain SI, Thayyen RJ (1999) Controls on the major–ion chemistry of the Dokriani glacier meltwaters, Ganga basin, Garhwal Himalaya, India. Journal of Glaciology 45(149): 87–92. CrossRefGoogle Scholar
  14. He Y, Yao T, Theakstone WH (1999) Analysis of climatic and environmental records in an alpine temperate glacier. Journal of Glaciology and Geocryology 21(3): 257–263.Google Scholar
  15. He Y, Yao T, Yang M (2000) Spatial features of glacial hydrochemistry and recent variations of a Chinese temperate glacier in Mt. Yulong. Journal of Mountain Science 18(6): 481–488. (In Chinese)Google Scholar
  16. He Y, Yao T, Cheng GC, et al. (2001) Preliminary analysis of climatic and environmental signals of a shallow ice–core from a Chinese temperate glacier in Mt. Yulong. Journal–Lanzhou University Natural Sciences 37(4): 118–124.Google Scholar
  17. Huang C, Duan K, Li Y (1998) Study on anions and cations of ice core from Xixiabangma, Tibetan Plateau. Environmental Chemistry 17(5): 500–502. Google Scholar
  18. Jacobson MZ (2002) Atmospheric pollution: history, science, and regulation. Cambridge University Press. ISBN–13: 978–0511802287CrossRefGoogle Scholar
  19. Jenkins MD, Drever JI, Reider RG, et al. (1987) Chemical composition of fresh snow on Mount Everest. Journal of Geophysical Research: Atmospheres 92(D9): 10999–11002. Google Scholar
  20. Jones JAA (1999) Climate change and sustainable water resources: placing the threat of global warming in perspective. Hydrological Sciences Journal 44(4): 541–557. CrossRefGoogle Scholar
  21. Kang S, Mayewski PA, Qin D, et al. (2004) Seasonal differences in snow chemistry from the vicinity of Mt. Everest, central Himalayas. Atmospheric Environment 38(18): 2819–2829. CrossRefGoogle Scholar
  22. Kaltenborn BP, Nellemann C, Vistnes II (2010) High mountain glaciers and climate change: challenges to human livelihoods and adaptation. United Nations Environment Programme, Arendal.Google Scholar
  23. Kaser G, Großhauser M, Marzeion B (2010) Contribution potential of glaciers to water availability in different climate regimes. Proceedings of the National Academy of Sciences 107(47): 20223–20227. CrossRefGoogle Scholar
  24. Kumar A, Verma A, Dobhal DP, et al. (2014) Climatic control on extreme sediment transfer from Dokriani Glacier Garhwal Himalaya. Journal of Earth System Science 123(1): 109–120. Lara LBLSCrossRefGoogle Scholar
  25. Artaxo P, Martinelli LA, et al. (2001) Chemical composition of rainwater and anthropogenic influences in the Piracicaba River Basin, Southeast Brazil. Atmospheric Environment 35(29): 4937–4945. CrossRefGoogle Scholar
  26. Li C, Kang S, Zhang Q, et al. (2007) Major ionic composition of precipitation in the Nam Co region, Central Tibetan Plateau. Atmospheric Research 85(3): 351–360. CrossRefGoogle Scholar
  27. Li ZX, He YQ, Pan HX, et al. (2009) Environmental significance of snowpit chemistry in the typical monsoonal temperate glacier region, Baishui glacier no. 1, Mt Yulong, China. Environmental Geology 58(6): 1319–1328. CrossRefGoogle Scholar
  28. Likens GE, Bormann FH, Johnson NM (1977) Interactions between major biogeochemical cycles in terrestrial ecosystems. In: Likens GE (ed.), Some Perspectives of the Major Biogeochemical Cycles, Chapter 6, pp 93–112.Google Scholar
  29. Liu B, Kang S, Sun J, et al. (2013) Wet precipitation chemistry at a high–altitude site (3,326 m a.s.l) in the southeastern Tibetan Plateau. Environmental Science and Pollution Research 20(7): 5013–5027. CrossRefGoogle Scholar
  30. Luo H, Yanai M (1983) The large–scale circulation and heat sources over the Tibetan Plateau and surrounding areas during the early summer of 1979. Part I: Precipitation and kinematic analyses. Monthly Weather Review 111(5): 922–944.<0922:TLSCAH>2.0.CO;2 Google Scholar
  31. Lyons WB, Mayewski PA, Ahmad N (1981) Acidity of recent Himalayan snow. Eastern Snow Conference.Google Scholar
  32. Mayewski PA, Lyons WB, Ahmad N (1983) Chemical composition of a high altitude fresh snowfall in the Ladakh Himalayas. Geophysical Research Letters 10(1): 105–108. CrossRefGoogle Scholar
  33. Mayewski PA, Lyons WB, Spencer MJ, et al. (1986) Snow chemistry from Xixabangma peak, Tibet. Google Scholar
  34. Murakami T (1987) Effects of the Tibetan Plateau; In Monsoon Meteorology, edited by Chang CP and Krishnamurti TN, 235–270. Oxford University Press, New York.Google Scholar
  35. Nijampurkar VN, Bhandari N, Ramesh R, et al. (1986) Climatic significance of D/H ratios of a temperate glacier in Sikkim. Current Science 55(18): 910–912.Google Scholar
  36. Nijampurkar VN, Sarin MM, Rao DK (1993) Chemical composition of snow and ice from iShigri glacier, Central Himalaya. Journal of Hydrology 151(1): 19–34. CrossRefGoogle Scholar
  37. Norman M, Das SN, Pillai AG, et al. (2001) Influence of air mass trajectories on the chemical composition of precipitation in India. Atmospheric Environment 35(25): 4223–4235. CrossRefGoogle Scholar
  38. Pratap B, Dobhal DP, Mehta M, et al. (2015) Influence of debris cover and altitude on glacier surface melting: a case study on Dokriani Glacier, central Himalaya, India. Annals of Glaciology 56(70): 9–16. CrossRefGoogle Scholar
  39. Pratap B, Dobhal DP, Bhambri R, et al. (2016) Four decades of glacier mass balance observations in the Indian Himalaya. Regional Environmental Change 16(3): 643–658. CrossRefGoogle Scholar
  40. Rodhe H, Dentener F, Schulz M (2002) The global distribution of acidifying wet deposition. Environmental Science & Technology 36(20): 4382–4388. CrossRefGoogle Scholar
  41. Safai PD, Rao PSP, Momin GA, et al. (2004) Chemical composition of precipitation during 1984–2002 at Pune, India. Atmospheric Environment 38(12): 1705–1714. CrossRefGoogle Scholar
  42. Sequeira R, Kelkar D (1978) Geochemical implications of summer monsoonal rainwater composition over India. Journal of Applied Meteorology 17(9): 1390–1396.<1390:GIOSMR>2.0.CO;2 CrossRefGoogle Scholar
  43. Shrestha AB, Wake CP, Dibb JE (1997) Chemical composition of aerosol and snow in the high Himalaya during the summer monsoon season. Atmospheric Environment 31(17): 2815–2826. CrossRefGoogle Scholar
  44. Shrestha AB, Wake CP, Dibb JE, et al. (2000) Seasonal variations in aerosol concentrations and compositions in the Nepal Himalaya. Atmospheric Environment 34(20): 3349–3363. CrossRefGoogle Scholar
  45. Shukla T, Mehta M, Jaiswal MK, et al., (2018). Late Quaternary glaciation history of monsoon–dominated Dingad basin, central Himalaya, India. Quaternary Science Reviews 181: 43–64. CrossRefGoogle Scholar
  46. Singh P, Ramasastri KS, Kumar N, et al. (2003) Suspended sediment transport from the Dokriani Glacier in the Garhwal Himalayas. Hydrology Research 34: 221–244.CrossRefGoogle Scholar
  47. Souchez RA, MM Lemmens (1987) Solutes. In: Gurnell AM, Clark MJ (eds.) Glacio–fluvial sediment transfer. Wiley, Chichester, pp 285–303.Google Scholar
  48. Thayyen RJ, JT Gergan (2010) Role of glaciers in watershed hydrology: a preliminary study of a ‘Himalayan catchment’. Cryosphere 4(1): 115–128.CrossRefGoogle Scholar
  49. Torres MA, Moosdorf N, Hartmann J, et al. (2017) Glacial weathering, sulfide oxidation, and global carbon cycle feedbacks. PNAS 114(33): 8716–8721. CrossRefGoogle Scholar
  50. Torres MA, West AJ, Li G (2014) Sulphide oxidation and carbonate dissolution as a source of CO2 over geological timescales. Nature 507(7492): 346. CrossRefGoogle Scholar
  51. Tripathee L, Kang S, Huang J, et al. (2014a) Ionic composition of wet precipitation over the southern slope of central Himalayas, Nepal. Environmental Science and Pollution Research 21(4): 2677–2687. CrossRefGoogle Scholar
  52. Tripathee L, Kang S, Huang J, et al. (2014b) Concentration of trace elements in wet precipitation over the central Himalayas, Nepal. Atmospheric environment 95: 231–238. CrossRefGoogle Scholar
  53. Tripathee L, Kang S, Rupakheti D, et al. (2016) Water–Soluble Ionic Composition of Aerosols at Urban Location in the Foothills of Himalaya, Pokhara Valley, Nepal. Atmosphere 7(8): 102. CrossRefGoogle Scholar
  54. Tripathee L, Kang S, Rupakheti D, et al. (2017). Chemical characteristics of soluble aerosols over the central Himalayas: insights into spatiotemporal variations and sources. Environmental Science and Pollution Research 24(31): 24454–24472. CrossRefGoogle Scholar
  55. Wake CP, Mayewski PA, Ping W, et al. (1992) Anthropogenic sulfate and Asian dust signals in snow from Tien Shan, northwest China. Annals of Glaciology 16: 45–52. CrossRefGoogle Scholar
  56. Wake CP, Dibb JE, Mayewski PA, et al. (1994) The chemical composition of aerosols over the eastern Himalayas and Tibetan Plateau during low dust periods. Atmospheric Environment 28(4): 695–704. CrossRefGoogle Scholar
  57. Wake CP, Mayewski PA, Spencer MJ (1990) A review of central Asian glaciochemical data. Annals of Glaciology 14(1): 301–306. CrossRefGoogle Scholar
  58. Williams MW, Tonnessen KA, Melack JM, et al. (1992) Sources and spatial variation of the chemical composition of snow in the Tien Shan, China. Annals of Glaciology 16: 25–32. CrossRefGoogle Scholar
  59. Yalcin K, Wake CP, Dibb JE, et al. (2006) Relationships between aerosol and snow chemistry at King Col, Mt. Logan Massif, Yukon, Canada. Atmospheric Environment 40(37): 7152–7163. CrossRefGoogle Scholar
  60. Yuanqing H, Tandong Y, MeixueY (2000) Spatial features of glacial hydro–chemistry and recent variations of a Chinese temperate glacier in Mt. Yulong. Journal of Mountain Science 18(6): 481–488.Google Scholar
  61. Yuanqing H, Tandong Y, Guodong C, et al. (2001) Preliminary analysis of climatic and environmental signals of a shallow ice–core from a Chinese temperate glacier in Mt. Yulong. Journal–Lanzhou University Natural Sciences 37(4): 118–124.Google Scholar
  62. Zemp M, Frey H, Gärtner–Roer I, et al. (2015) Historically unprecedented global glacier decline in the early 21st century. Journal of Glaciology 61(228): 745–762. CrossRefGoogle Scholar
  63. Zhang XY, Gong SL, Shen ZX, et al. (2003) Characterization of soil dust aerosol in China and its transport and distribution during 2001 ACE–Asia: 1. Network observations. Journal of Geophysical Research: Atmospheres 108(D9). Google Scholar
  64. Zhang X, Edwards R (2011) Anthropogenicsulfate and nitrate signals in snow from Bogda Glacier, eastern Tianshan. Journal of Earth Science 22(4): 490–502. CrossRefGoogle Scholar
  65. Zhang Y, Kang S, Li C, et al. (2012) Wet deposition of precipitation chemistry during 2005–2009 at a remote site (Nam Co Station) in central Tibetan Plateau. Journal of Atmospheric Chemistry 69(3): 187–200. CrossRefGoogle Scholar

Copyright information

© Science Press, Institute of Mountain Hazards and Environment, CAS and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Centre for GlaciologyWadia Institute of Himalayan GeologyDehradunIndia
  2. 2.National Institute of HydrologyRoorkeeIndia
  3. 3.Indian Institute of TechnologyKanpurIndia
  4. 4.State Key Laboratory of Cryospheric Science, Northwest Institute of Eco-Environment and ResourcesChinese Academy of SciencesLanzhouChina
  5. 5.Wadia Institute of Himalayan GeologyDehradunIndia
  6. 6.University of Petroleum and Energy StudiesBidholi, DehradunIndia

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