Skip to main content
Log in

The variation of free gas distribution within the seeping seafloor hydrate stability zone and its link to hydrate formations in the Qiongdongnan Basin

  • Research Article - Applied Geophysics
  • Published:
Acta Geophysica Aims and scope Submit manuscript

Abstract

China geological survey has conducted two hydrate expeditions for two gas chimney structures (GC1, GC2) in the Qiongdongnan Basin, South China Sea, where the fluid migrations vary significantly. Although massive hydrates were recovered both in the seepage pathways above GC1 and GC2, the free gas distributions in seeping seafloor hydrate stability zone (HSZ) remain controversial. Previous studies confirm that structure I (sI) and structure II (sII) hydrates occur through the whole seepage pathways, and free gas accumulates below the base of methane hydrate stability zone (BHSZ). In fact, free gas and gas hydrates coexist in the whole seepage-gas chimney system. The quantitative estimation of the fluid distribution is significant for studying the heterogeneous fluid migration in the seepages. In this study, Archie formula and three-phase Biot-type equation are modified to invert fluid concentrations for the whole well sections, in which brine, free gas, gas hydrate and matrix are considered as separate phases. The results indicate that the bottom simulating reflector is the boundary of an increasing gas concentration and a decrease hydrate concentration, instead of the interfaces of the hydrate and free gas in most areas. And hydrate occurrence is closely related to the micro-fault in the gas chimney. By comparing the fluid distribution between GC1 and GC2, more free gas associated with gas hydrates is accumulated in the seepage pathways in HSZ in GC1 where less free gas occurred below the BHSZ. Gas-bearing fluids in GC1 are considered to be very active in historic time, but they nearly stop flowing now, and the remaining gas cannot form hydrates in the hydrate-saturated pores, while the fluids in GC2 tend to convert to hydrates till now, and it is an active or younger fluid system. Free gas is the important intermediate medium for revealing this phase transition and exerts a significant control on the timescales associated with phase equilibrium variation processes. It is the first study revealing the relationship between the fluid distribution and the mobility of the seepage-gas chimney system in the study area, which also provide a new insight for estimating hydrate resource.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig.5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15
Fig. 16
Fig. 17
Fig. 18
Fig. 19
Fig. 20

Similar content being viewed by others

Data availability

The data that support the findings of this study are available from the corresponding author, [Deng Wei, hahens@163.com], upon reasonable request.

Code availability

Not applicable.

References

  • Aki K, Richards PG (2002) Quantitative seismology.

  • Archie GE (1942) The electrical resistivity log as an aid in determining some reservoir characteristics. Transact AIME 146(01):54–62

    Article  Google Scholar 

  • Arps JJ (1953) The effect of temperature on the density and electrical resistivity of sodium chloride solutions. Pet Transact AIME 5(10):17–20

    Google Scholar 

  • Boswell R (2009) Is gas hydrate energy within reach? Science 325:957–958

    Article  Google Scholar 

  • Boswell R, Collett T, Frye M, Shedd W, McConnell D, Shelander D (2012) Subsurface gas hydrates in the northern Gulf of Mexico. J Mar Pet Geol 34(1):4–30

    Article  Google Scholar 

  • Boswell R, Schoderbek D, Collett TS et al (2017) The iġnik sikumi field experiment, alaska north slope: design, operations, and implications for CO2–CH4 exchange in gas hydrate reservoirs. Energy Fuel 31(1):140–153

    Article  Google Scholar 

  • Boswell R, Collett TS, Cook AE et al (2020) Introduction to special issue: gas hydrates in green canyon block 955, deep-water Gulf of Mexico: part I. AAPG Bull 104:1843–1846

    Article  Google Scholar 

  • Carcione JM, Tinivella U (2000) Bottom-simulating reflectors: seismic velocities and AVO effects. Geophys 65:54–67

    Article  Google Scholar 

  • Cathles L, Chen D (2004) A compositional kinetic model of hydrate crystallization and dissolution. J Geophys Res Solid Earth 109:B08102

  • Chen F, Zhou Y, Su X et al (2011) Gas hydrate saturation and its relation with grain size of the hydrate-bearing sediments in the Shenhu area of northern South China Sea. Mar Geol Quat Geol 31(5):95–100

    Article  Google Scholar 

  • Chen D et al (2003) A kinetic model for the pattern and amounts of hydrate precipitated from a gas steam: application to the bush hill vent site, green canyon block 185, Gulf of Mexico. J Geophys Res Solid Earth 108(B1):2058

  • Dai S, Seol Y (2014) Water permeability in hydrate-bearing sediments: a porescale study. Geophys Res Lett 41(12):4176–4184

    Article  Google Scholar 

  • Daigle H (2016) Relative permeability to water or gas in the presence of hydrates in porous media from critical path analysis. J Pet Sci Eng 146(2016):526–535

    Article  Google Scholar 

  • Daigle H, Bangs NL, Dugan B (2011) Transient hydraulic fracturing and gas release in methane hydrate settings: a case study from southern hydrate ridge. Geochem Geophys Geosyst 12:Q12022

    Article  Google Scholar 

  • Deng W, Liang J, He YL et al (2020) Rock-physics-based estimation of quartz content in the Shenhu area South China Sea. Acta Geophys 68:1619–1641

    Article  Google Scholar 

  • Deng W, Liang J, Zhang W et al (2021) Typical characteristics of fracture-filling hydrate-charged reservoirs caused by heterogeneous fluid flow in the Qiongdongnan Basin, northern South China Sea. Mar Pet Geol 124:104810

    Article  Google Scholar 

  • Dickens GR, Quinby HMS (1994) Methane hydrate stability in seawater. Geophys Res Lett 21(19):2115–2118

    Article  Google Scholar 

  • Dvorkin J, Nur A (1993) Rock physics for characterization of gas hydrates. US Geol Surv Prof Pap 1570:293–298

    Google Scholar 

  • Ecker C, Dvorkin J, Nur AM (2000) Estimating the amount of gas hydrate and free gas from marine seismic data. Geophys 65:565–573

    Article  Google Scholar 

  • Gong ZS, Li ST (1997) Continental margin basin analysis and hydrocarbon accumulation of the northern South China Sea. Science Press, Beijing, pp 193–256

    Google Scholar 

  • Guan JA, Liang DQ, Wu NY, Fan SS (2009) The methane hydrate formation and the resource estimate resulting from free gas migration in seeping seafloor hydrate stability zone. J Asian Earth Sci 36(2009):277–288

    Article  Google Scholar 

  • Hamilton EL (1980) Geoacoustic modeling of the sea floor. J Acoust Soc Am 68:1313–1340

    Article  Google Scholar 

  • Helgerud MB, Dvorkin J, Nur A, Sakai A, Collett T (1999) Elastic wave velocity in marine sediments with gas hydrates: effective medium modeling. Geophys Res Lett 26:2021–2024

    Article  Google Scholar 

  • Helgerud MB, Waite WF, Kirby SH, Nur A (2009) Elastic wave speeds and moduli in polycrystalline ice Ih, sI methane hydrate, and sII methane-ethane hydrate. J Geophys Res 114:B02212

    Google Scholar 

  • Hesse R (2003) Pore water anomalies of submarine gas-hydrate zones as tool to assess hydrate abundance and distribution in the subsurface-what have we learned in the past decade. Earth Sci Rev 61:149–179

    Article  Google Scholar 

  • Hill R (1952) The elastic behaviour of a crystalline aggregate. Proc Phys Soc 65(5):349

    Article  Google Scholar 

  • Huang B, Xiao X, Li X (2003) Geochemistry and origins of natural gases in the Yinggehai and Qiongdongnan Basins, offshore South China Sea. Org Geochem 34:1009–1025

    Article  Google Scholar 

  • Jakobsen M, Hudson JA, Minshull TA, Singh SC (2000) Elastic properties of hydrate-bearing sediments using effective medium theory. J Geophys Res 105:561–577

    Article  Google Scholar 

  • Kida M, Khlystov O, Zemskaya T et al (2006) Coexistence of sI and II gas hydrates in lake Baikal suggesting gas sources from microbial and thermogenic origin. Geophys Res Lett 33(24):L24603

    Article  Google Scholar 

  • Klapp SA, Bohrmann G, Kuhs WF et al (2010) Microstructures of sI and II gas hydrates from the Gulf of Mexico. Mar Pet Geol 27(1):116–125

    Article  Google Scholar 

  • Kleinberg RL, Flaum C, Griffin DD et al (2003) Deep sea NMR: methane hydrate growth habit in porous media and its relationship to hydraulic permeability, deposit accumulation, and submarine slope stability. J Geophys Res 108(B10):2508

    Google Scholar 

  • Kondo W, Ohtsuka K, Ohmura R et al (2014) Clathrate-hydrate formation from a hydrocarbon gas mixture. Appl Energy 113(1):864–871

    Article  Google Scholar 

  • Kvenvolden KA (1988) Methane hydrate—a major reservoir of carbon in the shallow geosphere? Chem Geol 71:41–51

    Article  Google Scholar 

  • Kvenvolden KA (1993) Gas hydrates: geological perspective and global change. Rev Geophys 31:173–187

    Article  Google Scholar 

  • Lai H, Fang Y, Kuang Z, Ren J, Xing C (2021) Geochemistry, origin and accumulation of natural gas hydrates in the Qiongdongnan Basin, South China Sea: implications from site GMGS5-W08. Mar Pet Geol 123:104774

    Article  Google Scholar 

  • Lee MW, Collett TS (2001) Elastic properties of gas hydrate-bearing sediments. Geophys 66:763–771

    Article  Google Scholar 

  • Lee MW, Collett TS (2009) Gas hydrate saturations estimated from fractured reservoir at Site NGHP-01-10, Krishna-Godavari Basin, India. J Geophys Res Solid Earth 114(B07102)

  • Lee MW, William FW (2008) Estimating pore-space gas hydrate saturations from well log acoustic data. Geochem Geophy Geosyst 9(7):Q07008

    Article  Google Scholar 

  • Lee MW, Hutchinson DR, Collett TS, Dillon WP (1996) Seismic velocities for hydrate-bearing sediments using weighted equation. J Geophys Res 101:20347–20358

    Article  Google Scholar 

  • Lee MW (2005) Proposed moduli of dry rock and their application to predicting elastic velocities of sandstones. US Geological Survey, Reston, pp 1–14

    Google Scholar 

  • Lee MW (2007) Velocities and attenuations of gas hydrate-bearing sediments. US Department of the Interior US Geological Survey

    Book  Google Scholar 

  • Li JF, Ye JL, Qin XW et al (2018) The first offshore natural gas hydrate production test in South China Sea. China Geol 1(1):5–16

    Article  Google Scholar 

  • Liang JQ, Fu SY, Chen F (2017) Submarine methane leakage and hydrate accumulation in the northeastern South China Sea. Nat Gas Geos 28(5):761–770

    Google Scholar 

  • Liang J, Zhang W, Lu JA, Wei J, Kuang Z, He Y (2019) Geological occurrence and accumulation mechanism of natural gas hydrates in the eastern Qiongdongnan Basin of the South China Sea: Insights from site GMGS5-W9-2018. Mar Geol 418:106042

    Article  Google Scholar 

  • Liu X, Flemings PB (2006) Passing gas through the hydrate stability zone at southern hydrate ridge, offshore oregon. Earth Planet Sci Lett 241(1–2):211–226

    Article  Google Scholar 

  • Liu X, Flemings PB (2007) Dynamic multiphase flow model of hydrate formation in marine sediments. J Geophys Res 112:B03101

    Google Scholar 

  • Liu X, Flemings PB (2011) Capillary effects on hydrate stability in marine sediments. J Geophys Res 116:B07102

    Google Scholar 

  • Lu H, Seo YT, Lee JW et al (2007) Complex gas hydrate from the Cascadia margin. Nature 445(7125):303–306

    Article  Google Scholar 

  • Macdonald SIR (1994) Evidence of structure H hydrate, Gulf of Mexico continental slope. Org Geochem 22:1029–1032

    Article  Google Scholar 

  • Milkov AV (2005) Molecular and stable isotope compositions of natural gas hydrates: a revised global dataset and basic interpretations in the context of geological settings. Org Geochem 36(5):681–702

    Article  Google Scholar 

  • Milkov AV, Dickens GR, Claypool GE (2004) Co-existence of gas hydrate, free gas, and brine within the regional gas hydrate stability zone at hydrate ridge (Oregon margin): evidence from prolonged degassing of a pressurized core. Earth Planet Sci Lett 222:829–843

    Article  Google Scholar 

  • Miller JJ, Lee MW, von Huene R (1991) An analysis of a seismic reflection from the base of a gas hydrate zone, offshore peru. AAPG Bull 75:910–924

    Google Scholar 

  • Mindlin RD (1949) Compliance of elastic bodies in contact. J Appl Mech ASME 16:259–268

    Article  Google Scholar 

  • Paganoni M, Cartwright JA, Fosch IM et al (2016) sII gas hydrates found below the bottom-simulating reflector. Geophys Res Lett 43(11):5696–5706

    Article  Google Scholar 

  • Pandey L, Sain K, Joshi AK (2019) Estimate of gas hydrate saturations in the Krishna-Godavari Basin, eastern continental margin of India, results of expedition NGHP-02. Mar Pet Geol 108:581–594

    Article  Google Scholar 

  • Pride SR, Berryman JG, Harris JM (2004) Seismic attenuation due to wave-induced flow. J Geophys Res Solid Earth 109(B1):B01201

    Article  Google Scholar 

  • Qian J, Wang X, Collett TS et al (2018) Downhole log evidence for the coexistence of sII gas hydrate and free gas below the bottom simulating reflector in the South China Sea. Mar Pet Geol 98:662–674

    Article  Google Scholar 

  • Riedel M, Collett TS, Kumar P, Sathe AV, Cook A (2010) Seismic imaging of a fractured gas hydrate system in the Krishna-Godavari Basin offshore India. J Mar Pet Geol 27:1476–1493

    Article  Google Scholar 

  • Ryu B, Collett TS, Riedel M et al (2013) Scientific results of the second gas hydrate drilling expedition in the Ulleung basin (UBGH2). Mar Pet Geol 47:21–29

    Article  Google Scholar 

  • Sava D, Hardage B, Murray P et al (2008) Rock-physics joint inversion of resistivity-log and seismic velocity for hydrate characterizationC/SEG technical program expanded abstracts 15 Dec 2008, Houston

  • Sen MK (2006) Seismic inversion. Society of Petroleum Engineers publications

    Book  Google Scholar 

  • Sloan ED, Subramanian S, Matthews PN et al (1998) Quantifying hydrate formation and kinetic inhibition. Ind Eng Chem Res 37(8):3124–3132

    Article  Google Scholar 

  • Smith DH, Seshadri K, Uchida T et al (2004) Thermodynamics of methane, propane, and carbon dioxide hydrates in porous glass. Aiche J 50(7):1589–1598

    Article  Google Scholar 

  • Su M, Sha ZB, Qiao SH et al (2015) Sedimentary evolution since quaternary in the Shenhu hydrate drilling area, northern South China Sea. Chin J Geophys 58(8):2975–2985

    Google Scholar 

  • Subramanian S, Ballard AL, Kini RA et al (2000) Structural transitions in methane + ethane gas hydrates-part I: upper transition point and applications. Chem Eng Sci 55(23):5763–5771

    Article  Google Scholar 

  • Uchida T, Moriwaki M, Takeya S et al (2004) Two-step formation of methane–propane mixed gas hydrates in a batch-type reactor. Aiche J 50(2):518–523

    Article  Google Scholar 

  • Wang XJ, Hutchinson DR, Wu SG et al (2011) Elevated gas hydrate saturation within silt and silty clay sediments in the Shenhu area South China Sea. J Geophys Res 116:B05102

    Google Scholar 

  • Wei J, Liang J, Lu J, Zhang W, He Y (2019) Characteristics and dynamics of gas hydrate systems in the northwestern South China Sea-results of the fifth gas hydrate drilling expedition. Mar Pet Geol 110:287–298

    Article  Google Scholar 

  • Wei J, Wu T, Zhu L et al (2021) Mixed gas sources induced co-existence of sI and sII gas hydrates in the Qiongdongnan Basin, South China Sea. Mar Pet Geol 128:105024

    Article  Google Scholar 

  • Wood WT, Stoffa PL, Shipley TH (1994) Quantitative detection of methane hydrate through high-resolution seismic velocity analysis. J Geophys Res 99:9681–9695

    Article  Google Scholar 

  • Wu SG, Zhang GX, Huang YY et al (2005) Gas hydrate occurrence on the northern slope of the northern South China Sea. Mar Petrol Geol 22(3):403–412

    Article  Google Scholar 

  • Wu NY, Yang SX, Wang HB (2009) Fluid transport system for gas hydrate accumulation in the Shenhu area of the northern slope of the South China Sea. Chin J Geophys 52(6):1641–1650

    Google Scholar 

  • Ye JL, Qin XW, Xie WW et al (2020) The second natural gas hydrate production test in the South China Sea. China Geol 3:197–209

    Article  Google Scholar 

  • Zhang Z, Mcconnell DR, Han DH (2012) Rock physics-based seismic trace analysis of unconsolidated sediments containing gas hydrate and free gas in green canyon 955, northern Gulf of Mexico. Mar Pet Geol 34(1):119–133

    Article  Google Scholar 

  • Zhang W, Liang J, Lu JA et al (2017) Accumulation features and mechanisms of high saturation natural gas hydrate in Shenhu Area, northern South China Sea. Petrol Explor Dev 44(5):708–719

    Article  Google Scholar 

  • Zhu WL, Zhang GC, Gao L (2008) Geological characteristics and exploration objectives of hydrocarbons in the northern continental margin basin of South China Sea. Acta Petrol Sin 29(1):1–9

    Google Scholar 

  • Zhu WL, Huan GB, Mi L et al (2009) Geochemistry, origin, and deep-water exploration potential of natural gases in the pearl river mouth and Qiongdongnan basins, South China Sea. AAPG Bull 93(6):741–761

    Article  Google Scholar 

  • Zhu WL, Zhong K, Li Y et al (2012) Characteristics of hydrocarbon accumulation and exploration potential of the northern South China Sea deepwater basins. Sci Bull 57(24):3121–3129

    Article  Google Scholar 

Download references

Acknowledgements

The authors would like to acknowledge the funding by China Geological Survey Project (No. DD20190217) and Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) (No. GML2019ZD0102).

Funding

The authors would like to acknowledge the funding by China Geological Survey Project (No. DD20190217), Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (No. GML2019ZD0102) and Guangdong Major project of Basic and Applied Basic Research (No.2020B0301030003).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Deng Wei or Kuang Zenggui.

Ethics declarations

Conflict of interest

No conflict of interest exits in the submission of this manuscript, and manuscript is approved by all authors for publication.

Additional information

Edited by Dr. Liang Xiao (ASSOCIATE EDITOR) / Prof. Michał Malinowski (CO-EDITOR-IN-CHIEF).

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary file1 (DOCX 325 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wei, D., Jinqiang, L., Zenggui, K. et al. The variation of free gas distribution within the seeping seafloor hydrate stability zone and its link to hydrate formations in the Qiongdongnan Basin. Acta Geophys. 70, 1115–1136 (2022). https://doi.org/10.1007/s11600-022-00763-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11600-022-00763-1

Keywords

Navigation