Skip to main content
Log in

Microstructure Transition and Grain Refinement Mechanism of Undercooled Alloys

  • Metallic Materials
  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

The solidification microstructures of undercooled Ni90Cu10 alloys under different undercoolings were studied systematically by means of melt coating and cyclic superheating. In the obtained undercooling range, the solidification structures of the two undercooled alloys have similar transformation processes, and there are two kinds of grain refinement structures under the conditions of low undercooling and high undercooling, respectively. The microstructures of the two grain refinement processes were analyzed in more detail by electronic backscattering diffraction technique. Under the condition of small undercooling, dendrite remelting is considered to be the main reason of grain refinement. However, under the condition of high undercooling, the existence of annealing twins and obvious migration of grain boundary are important evidences for the occurrence of recrystallization process.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Fan Z, Gao F, Wang Y, Men H, Zhou L. Effect of Solutes on Grain Refinement[M]. Progress in Materials Science, 2021

  2. Jiang A, Wang X. Dendritic and Seaweed Growth of Proeutectic Scandium Tri-aluminide in Hypereutectic Al-Sc Undercooled Melt[J]. Acta Materialia, 2020, 200: 56–65

    Article  CAS  Google Scholar 

  3. Grgac P, Mesárošová J, Behúlová M, Martinkovič M. Experimental Determination of the Nuclei Number in the Deeply Undercooled and rapidly Solidified Powder Particles of High-alloyed Steel[J]. Journal of Alloys and Compounds, 2019, 798: 204–209

    Article  CAS  Google Scholar 

  4. Li J, Jie W, Yang G. Solidification Structure Formation in Undercooled Fe-Ni Alloy[J]. Acta Materialia, 2002, 50(7): 1 797–1 807

    Article  CAS  Google Scholar 

  5. Liu X, Yang G, Ping F. Solidification Behavior of Decagonal Quasicrystal in the Undercooled Al 72 Ni 12 Co 16 Alloy Melt[J]. Journal of Materials Science, 2003, 38(5): 885–889

    Article  CAS  Google Scholar 

  6. Shang Z, Wei X, Song D, Zou J, Liang S, Liu G, et al. Microstructure and Mechanical Properties of a New Nickel-based Single Crystal Superalloy[J]. Journal of Materials Research and Technology, 2020, 9(5): 11 641–11 649

    Article  CAS  Google Scholar 

  7. Xu XL, Chen YZ, Liu F. Evolution of Solidification Microstructure in Undercooled Co80Pd20 Alloys[J]. Materials Science and Technology, 2013, 28(12): 1 492–1 498

    Article  Google Scholar 

  8. Xu XL, Liu F. Crystal Growth Due to Recrystallization upon Annealing Rapid Solidification Microstructures of Deeply Undercooled Single Phase Alloys Quenched before Recalescence[J]. Crystal Growth and Design, 2014, 14(5): 2 110–2 114

    Article  CAS  Google Scholar 

  9. Xu XL, Zhao YH, Hou H. Observation of Dendrite Growth Velocity and Microstructure Transition in Highly Undercooled Single Phase Alloys[J]. Materials Characterization, 2019, 155

  10. Zhang D, Prasad A, Bermingham MJ, Todaro CJ, Benoit MJ, Patel MN, et al. Grain Refinement of Alloys in Fusion-Based Additive Manufacturing Processes[J]. Metallurgical and Materials Transactions A, 2020, 51(9): 4341–4359

    Article  CAS  Google Scholar 

  11. Li J, Liu Y, Lu Y, Yang G, Zhou Y. Structural Evolution of Undercooled Ni-Cu Alloys[J]. Journal of Crystal Growth, 1998, 192: 462–470

    Article  CAS  Google Scholar 

  12. Wang H, Liu F, Yang G. Experimental Study of Grain Refinement Mechanism in Undercooled Ni-15at%Cu Alloy[J]. Journal of Materials Research, 2011, 25(10): 1 963–1 974

    Article  Google Scholar 

  13. Willnecker R, Herlach DM, Feuerbacher B. Grain Refinement Induced by a Critical Crystal Growth Velocity in Undercooled Melts[J]. Applied Physics Letters, 1990, 56(4): 324–326

    Article  CAS  Google Scholar 

  14. Mullis AM, Cochrane RF. Grain Refinement and the Stability of Dendrites Growing into Undercooled Pure Metals and Alloys[J]. Journal of Applied Physics. 1997, 82(8): 3 783–3 790

    Article  CAS  Google Scholar 

  15. Jones B, Weston G. Grain Refinement in Undercooled Copper[J]. J. Aust. Inst. Met., 1970, 15: 3 167

    Google Scholar 

  16. Karma A. Model of Grain Refinement in Solidification of Undercooled Melts[J]. International Journal of Non-Equiulibrium Processing, 1998, 11(2): 201–223

    CAS  Google Scholar 

  17. Liu F, Yang G. Stress-induced Recrystallization Mechanism for Grain Refinement in Highly Undercooled Superalloy[J]. Journal of Crystal Growth, 2001, 231: 295–305

    Article  CAS  Google Scholar 

Download references

Funding

Funded by the Basic Applied Research Projects in Shanxi Province(No. 201801D221151), and the Key R & D and Promotion Projects in Henan Province(No. 212102210267)

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Hongen An  (安红恩).

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Li, H., Siambun, N.J., Chuab, BL. et al. Microstructure Transition and Grain Refinement Mechanism of Undercooled Alloys. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 36, 922–926 (2021). https://doi.org/10.1007/s11595-021-2488-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11595-021-2488-5

Key words

Navigation