Skip to main content
SpringerLink
Log in

High Temperature Decomposition Behavior of CaZrO3 Coating on Graphite for TiNi Alloy Melting

  • Metallic Materials
  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

In order to restrain the carbon pollution, the feasibility of CaZrO3 coating was studied. The precursor powder was synthesized via solid-state reaction using metal calcium as a raw material. The protective coating on graphite was prepared by impregnation sintering method, and the effects of slurry viscosity, graphite density and coating thickness for coating were compared. The phase composition and microstructure of coatings were characterized, and the thermodynamic process was analyzed when the coating composition changed from CaZrO3 to ZrC. The results show that vacuum sintering can result in the decomposition of CaZrO3 and an intact ZrC coating with beautiful porous structure can be obtained.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Li D Y. Titanium Industry in China[J]. Non-Ferrous Smelting, 2000, 29(3): 1–6

    Google Scholar 

  2. Miyazaki S, Melton K N, Way-man C M. Engineering Applications of Shape Memory Alloys[M]. Landon: Butter-worth-Heinemann, 1990

    Google Scholar 

  3. Boyer R R. Overview on the Use of Titanium in the Aerospace Industry[J]. Mater. Sci. Eng. A, 1996, 213(1–2): 103–114

    Article  Google Scholar 

  4. Cheng J W. Present Status of Technology and Theory of Ti Alloy Smelting[J]. Special Casting & Nonferrous Alloys, 2001, 2: 70–72

    Google Scholar 

  5. Chen R R, Guo J J, Ding H S. Status Cold Crucible Casting Technology Research and Development[J]. Foundry, 2007, 56(5): 443–450

    CAS  Google Scholar 

  6. Chronister D J, Scott S W, Stickle D R, et al. Induction Skull Melting of Titanium and Other Reactive Alloys[J]. JOM, 1986, 38(9): 51–54

    Article  CAS  Google Scholar 

  7. Gao Y H, Li C H, Guo Z M, et al. Investigation on Refractories for Melting TiNi Alloy[J]. The Chinese Journal of Process Engineering, 2010, 10(S1): 63–67

    Google Scholar 

  8. Sadrnezhaad S K, Ahmadi E, Malekzadeh M. Mechanism of Reaction of Molten NiTi with EBM Graphite Crucible[J]. Materials Science and Technology, 2009, 25(6): 699–706

    Article  CAS  Google Scholar 

  9. Jia Q, Cui Y Y, Yang R. Ceramic Shell Mould Based on Stabilized ZrO2 for Titanium Alloy Investment Casting[J]. Acta Metallurgica Sinica, 2004, 40(11): 1170–1174

    CAS  Google Scholar 

  10. Zhang Q, Zhou X, Liu H B. Interaction Between Boron Nitride and the Melted TiNi Alloy[J]. Journal of Shanghai University, 2008, 14(5): 537–540

    Article  CAS  Google Scholar 

  11. Frenzel J, Zhang Z, Neuking K, et al. High Quality Vacuum Induction Melting of Small Quantities of NiTi Shape Memory Alloys in Graphite Crucibles[J]. Journal of Alloys and Compounds, 2004, 385(1–2): 214–223

    Article  CAS  Google Scholar 

  12. Zhang Z, Frenzel J, Neuking K. On the Reaction between NiTi Melts and Crucible Graphite during Vacuum Induction Melting of NiTi Shape Memory Alloys[J]. Acta Materialia, 2005, 53(14): 3971–3985

    Article  CAS  Google Scholar 

  13. You J G, Zhang G D, Jin Y L, et al. Effect of SiO2 on Structure and Properties of CaZrO3 Material[J]. Journal of Synthetic Crystals, 2014, 43(5): 1280–1285

    CAS  Google Scholar 

  14. Wang K, Li C H, Gao Y H, et al. Thermodynamic Reassessment of ZrO2-CaO System[J]. Journal of the American Ceramic Society, 2009, 92(5): 1098–1104

    Article  CAS  Google Scholar 

  15. Yang B, Zhu K L, Lu X G, et al. Preparation of TiFe Based Alloy Melted by CaZrO3 Crucible and Its Hydrogen Storage Properties[J]. The Chinese Journal of Process Engineering, 2012, 12(5): 850–856

    Google Scholar 

  16. Kim M G, Kim S K, Kim Y J. Effect Mold Material Binder on Metal-mold Interfacial Reaction for Investment Casting of Titanium Alloys[J]. Materials Transactions, 2002, 43(4): 745–750

    Article  CAS  Google Scholar 

  17. Gao Y H, Pang W, Li C H, et al. Preparation of Calcium Zirconate and Its Interfacial Reaction with Molten Titanium Alloys[J]. Journal of the Chinese Ceramic Society, 2009, 37(12): 2007–2011

    CAS  Google Scholar 

  18. Deng Y L, Zhang X M, Wei L Q, et al. Improvement in Anti-oxidation of Two-step Dipping Graphite with Different Solutions[J]. The Chinese Journal of Process Engineering, 2012, 12(1): 160–165

    CAS  Google Scholar 

  19. Liu B, Xiong X, Yi M Z, et al. Investigation on Coating of Resistance to High-temperature Oxidation for Common Graphite[J]. Hunan Metallurgy, 1999, 6: 10–12

    Google Scholar 

  20. Chen H Y, Li Z H, Wei L X. Enhance of Antioxidation of Graphite Rotator by Coating[J]. Carbon Techniques, 2008, 27(2): 30–32

    Google Scholar 

  21. Heimann R B, Vu T A. Effect of CaO on Thermal Decom-position During Sintering of Composite Hydroxyapatite-zirconia Mixtures for Monolithic Bioceramic Implants[J], Journal of Materials Science Letters, 1997, 16: 437–439

    Article  CAS  Google Scholar 

  22. Ali N, Bashir M, Batool S, et al. Structural and Optical Properties of Zirconia Thin Films[J]. Materials Today: Proceedings, 2015, 2: 5771–5776

    Google Scholar 

  23. Wu M B, Guo X P, Wu X J. High Temperature Reaction of Nb-based Ultrahigh Temperature Alloy Melt with Ceramic Crucibles[J]. Rare Metals and Cemented Carbides, 2007, 35(4): 9–13

    Google Scholar 

  24. Xia W. Research on Synthesis of Calcium Zirconium Oxide Material[D]. Dalian: University of Science and Technology Liaoning, 2014

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Materials, China Academy of Engineering Physics, Mianyang, 621907, China

    Bin Zhan  (詹斌), Yue Zhang, Caifen Wang & Xiaoying Wang

Authors
  1. Bin Zhan  (詹斌)
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yue Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Caifen Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Xiaoying Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Bin Zhan  (詹斌).

Additional information

Funded by the National Natural Science Foundation of China (No. 51702299)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhan, B., Zhang, Y., Wang, C. et al. High Temperature Decomposition Behavior of CaZrO3 Coating on Graphite for TiNi Alloy Melting. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 35, 980–985 (2020). https://doi.org/10.1007/s11595-020-2345-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11595-020-2345-y

Key words

Search

Navigation