Skip to main content
Log in

Simple Fabrication of Hierarchical Micro/Nanostructure Superhydrophobic Surface with Stable and Superior Anticorrosion Silicon Steel via Laser Marking Treatment

  • Metallic Materials
  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

To improve the weak corrosion resistance of silicon steel to acid solution and alkaline solution with high temperature, a stable hierarchical micro/nanostructure superhydrophobic surface with myriad irregular micro-scale hump and sheet-like nanostructure was successfully prepared on silicon steel by a simple, efficient and facile operation in large-area laser marking treatment. The morphology, composition, wettability of the as-prepared surface were studied. The superhydrophobic performance of the surface was investigated as well. Additionally, the corrosion resistance of the superhydrophobic surface to acidic solutions at room temperature and alkaline solutions at high temperature (80 °C) was carefully explored. The corrosion resistance mechanism was clarified. Moreover, considering the practical application of the surface in the future, the hardness of the hierarchical micro/nanostructure superhydrophobic surface was studied. The experimental results indicate that the hierarchical micro/nanostructure surface with texture spacing of 100 µm treated at laser scanning speed of 100 mms/presents superior superhydrophobicity after decreasing surface energy. The contact angle can be as high as 156.6°. Additionally, the superhydrophobic surface provide superior and stable anticorrosive protection for silicon steel in various corrosive environments. More importantly, the prepared structure of the surface shows high hardness, which ensures that the surface of the superhydrophobic surface cannot be destroyed easily. The surface is able to maintain great superhydrophobic performance when it suffers from slight impacting and abrasion.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Takajo S, Hiratani T, Okubo T, et al. Effect of Silicon Content on Iron Loss and Magnetic Domain Structure of Grain-oriented Electrical Steel Sheet[J]. Ieee. T. Magn., 2018, 54(1): 1–6

    Article  Google Scholar 

  2. Huang YH, Wu LW, Chen CH. Fracture Prediction of Electromagnetic Silicon Steel in Reheating Furnace[J]. J. Therm. Stresses., 2016, 39(5): 571–588

    Article  Google Scholar 

  3. Karafyllias G, Galloway A, Humphries E. The Effect of Low pH in Erosion-corrosion Resistance of High Chromium Cast Irons and Stainless Steels[J]. Wear, 2019, 420: 79–86

    Article  CAS  Google Scholar 

  4. Hebda M, Debecka H, Kazior J. Influence of Silicon Addition on the Mechanical Properties and Corrosion Resistance of Low-alloy Steel[J]. B. Mater. Sci., 2015, 38(7): 1 687–1 692

    Article  CAS  Google Scholar 

  5. Zorba V, Stratakis E, Barberoglou M, et al. Biomimetic Artificial Surfaces Quantitatively Reproduce the Water Repellency of a Lotus Leaf[J]. Adv. Mater., 2008, 20(21): 4 049–4 054

    Article  CAS  Google Scholar 

  6. Liu M, Hou Y, Li J, et al. Inorganic Adhesives for Robust, Self-healing, Superhydrophobic Surfaces[J]. Journal of Materials Chemistry A, 2017, 5(36): 19 297–19 305

    Article  CAS  Google Scholar 

  7. Shelemin A, Nikitin D, Choukourov A, et al. Preparation of Biomimetic Nano-structured Films with Multi-scale Roughness[J]. J. Phys. D. Appl. Phys., 2016, 49(25): 254 001

    Article  CAS  Google Scholar 

  8. Wu Y, Zhao W, Wang W, et al. Fabricating Binary Anti-corrosion Structures Containing Superhydrophobic Surfaces and Sturdy Barrier Layers for Al Alloys[J]. Rsc Advances, 2016, 6(6): 5 100–5 110

    Article  CAS  Google Scholar 

  9. Zheng S, Li C, Fu Q, et al. Fabrication of a Micro-nanostructured Superhydrophobic Aluminum Surface with Excellent Corrosion Resistance and Anti-icing Performance[J]. Rsc Advances, 2016, 6(83): 79 389–79 400

    Article  CAS  Google Scholar 

  10. Zhao E, Li Y, Gao L, et al. Anti-corrosion Properties of a Bioinspired Superhydrophobic Surface on Stainless Steel[J]. International Journal of Electrochemical Science, 2017, 12(10): 9 855–9 864

    Article  CAS  Google Scholar 

  11. Watson GS, Green DW, Schwarzkopf L, et al. A Gecko Skin Micro/nano Structure-A Low Adhesion, Superhydrophobic, Anti-wetting, Self-cleaning, Biocompatible, Antibacterial Surface[J]. Acta Biomaterialia, 2015, 21: 109–122

    Article  CAS  Google Scholar 

  12. Ta DV, Dunn A, Wasley TJ, et al. Nanosecond Laser Textured Super-hydrophobic Metallic Surfaces and Their Chemical Sensing Applications[J]. Appl. Surf. Sci., 2015, 357: 248–254

    Article  CAS  Google Scholar 

  13. Kavalenka MN, Hopf A, Schneider M, et al. Wood-based Microhaired Superhydrophobic and Underwater Superoleophobic Surfaces for Oil/water Separation[J]. Rsc Advances, 2014, 4(59): 31 079–31 083

    Article  CAS  Google Scholar 

  14. Francisco R, Tiemblo P, Hoyos M, et al. Multipurpose Ultra and Superhydrophobic Surfaces Based on Oligodimethylsiloxane-modified Nanosilica[J]. Acs Appl. Mater. Interfaces, 2014, 6(21): 18 998–19 010

    Article  CAS  Google Scholar 

  15. Yan W, Liu H, Zhu W. Preparation of Anti-corrosion Superhydrophobic Coatings by an Fe-based Micro/Nano Composite Electro-brush Plating and Blackening Process[J]. Rsc Advances, 2015, 5(125):103 000–103 012

    Article  CAS  Google Scholar 

  16. Qiao JH, Jin X, Qin JH, et al. A Super-hard Superhydrophobic Fe-Based Amorphous Alloy Coating[J]. Surf. Coat. Technol., 2018, 334: 286–291

    Article  CAS  Google Scholar 

  17. Dey S, Chatterjee S, Singh BP, et al. Development of Superhydrophobic Corrosion Resistance Coating on Mild Steel by Electrophoretic Deposition[J]. Surf. Coat. Technol., 2018, 341: 24–30

    Article  CAS  Google Scholar 

  18. Hu T, Hu L. Tribological Properties of Lubricating Films on the Al-Si Alloy Surface via Laser Surface Texturing[J]. Tribol. T., 2011, 54(5): 800–805

    Article  CAS  Google Scholar 

  19. Vorobyev AY, Guo CL. Optical and Wetting Properties of Femtosecond Laser Nanostructured Materials[J]. Journal of Nano Research, 2011, 14: 57–67

    Article  CAS  Google Scholar 

  20. Ghadim EE, Rashidi N, Kimiagar S, et al. Pulsed Laser Irradiation for Environment Friendly Reduction of Graphene Oxide Suspensions[J]. Appl. Surf. Sci., 2014, 301: 183–188

    Article  CAS  Google Scholar 

  21. Xu Y, Peng Y, Dearn KD, et al. Fabrication and Tribological Characterization of Laser Textured Boron Cast Iron Surfaces[J]. Surf. Coat. Technol., 2017, 313: 391–401

    Article  CAS  Google Scholar 

  22. Hussein HT, Kadhim A, Al-Amiery AA, et al. Enhancement of the Wear Resistance and Microhardness of Aluminum Alloy by Nd: YaG Laser Treatment[J]. Scientific World Journal, 2014, 2014: 1–5

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Mingkai Tang  (汤名锴) or Qiaoxin Zhang  (章桥新).

Additional information

Funded by the National Natural Science Foundation of China (No. 51875425)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Fu, J., Tang, M. & Zhang, Q. Simple Fabrication of Hierarchical Micro/Nanostructure Superhydrophobic Surface with Stable and Superior Anticorrosion Silicon Steel via Laser Marking Treatment. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 35, 411–417 (2020). https://doi.org/10.1007/s11595-020-2272-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11595-020-2272-y

Key words

Navigation