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Influence Mechanism of Sulfide Ions during Manganese Electrodeposition

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Abstract

Influence mechanism of sulfide ions (S2-) during manganese electrodeposition from sulphate electrolyte was investigated. Under the experimental conditions, S2- ion concentration and electrolyte pH represented significant multiple effects on the cathode current efficiency. Scanning electron microscope (SEM) indicated that electrodeposition manganese layer (EML) became refinement as S2- ion concentration was increased. X-ray Diffraction (XRD) displayed that S2- ion had negligible influence on the preferred orientation of the crystalline layer of the EML. S2- ion had no influence on the chemical composition of EML. S2- ion could improve the corrosion resistance of EML. The interaction mechanism of S2- ion with manganese electrodeposition was systematically explored by analysing E-pH diagram, cyclic voltammetry curve, cathode polarization curve and electrochemical impedance method.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, 411201, China

    Jianrong Xue  (薛建荣)

  2. College of Chemistry and Chemical Engineering, Hunan Provincial Key Laboratory of Efficient and Clean Utilization of Manganese Resources, Central South University, Changsha, 410083, China

    Jianrong Xue  (薛建荣), Hong Zhong & Shuai Wang

  3. Intelligent Manufacturing Institute of HNUST, Hunan University of Science and Technology, Xiangtan, 411201, China

    Dongping Long

Authors
  1. Jianrong Xue  (薛建荣)
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  2. Hong Zhong
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  3. Shuai Wang
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  4. Dongping Long
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Correspondence to Jianrong Xue  (薛建荣).

Additional information

Funded partly by the National Natural Science Foundation of China (No. 21376273), the National Science and Technology Support Program of China(No. 2015BAB17B01), and the Open Research Fund of Hunan Provincial Science and the Technology Plan Project (No. MN2017K05), China

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Xue, J., Zhong, H., Wang, S. et al. Influence Mechanism of Sulfide Ions during Manganese Electrodeposition. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 34, 1451–1459 (2019). https://doi.org/10.1007/s11595-019-2212-x

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  • DOI: https://doi.org/10.1007/s11595-019-2212-x

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