Effect of Graphene Surface Functional Groups on the Mechanical Property of PMMA Microcellular Composite Foams

  • Meijuan Li (李美娟)
  • Ping Cheng
  • Cheng Liu
  • Qiang Shen (沈强)Email author
  • Lianmeng Zhang
Organic Materials


The functional groups on graphene sheets surface affect their dispersion and interfacial adhesion in polymer matrix. We compared the mechanical property of polymethymethacrylate (PMMA) microcellular foams reinforced with graphene oxide (GO) and reduced graphene oxide (RGO) to investigate this influence of functional groups. RGO sheets were fabricated by solvent thermal reduction in DMF medium. UV-Vis, FT-IR and XPS analyses indicate the difference of oxygen-containing groups on GO and RGO sheets surface. The observation of SEM illustrates that the addition of a smaller number of GO or RGO sheets causes a fine cellular structure of PMMA foams with a higher cell density(about 1011 cells/cm3) and smaller cell sizes (about 1–2 µm) owing to their remarkable heterogeneous nucleation effect. Compared to GO reinforced foams, the RGO/PMMA foams own lower cell density and bigger cell size in their microstructure, and their compressive strength is lower even when the reinforcement contents are the same and the foam bulk density is higher. These results indicate that the oxygen-containing groups on GO sheets’ surface are beneficial to adhere CO2 to realize a larger nucleation rate, and their strong interaction with PMMA matrix improves the mechanical property of PMMA foams.

Key words

graphene surface functional groups PMMA microcellular composite foams mechanical property 


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Copyright information

© Wuhan University of Technology and Springer-Verlag GmbH Germany, Part of Springer Nature 2019

Authors and Affiliations

  • Meijuan Li (李美娟)
    • 1
  • Ping Cheng
    • 1
  • Cheng Liu
    • 1
  • Qiang Shen (沈强)
    • 2
    Email author
  • Lianmeng Zhang
    • 2
  1. 1.School of Chemistry, Chemical Engineering and Life SciencesWuhan University of TechnologyWuhanChina
  2. 2.State Key Laboratory of Advanced Technology for Materials Synthesis and ProcessingWuhan University of TechnologyWuhanChina

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