Skip to main content

Advertisement

Log in

Hydrothermal Synthesis of Zn2SnO4/Few-Layer Boron Nitride Nanosheets Hybrids as a Visible-Light-Driven Photocatalyst

  • Advanced Materials
  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

Zn2SnO4/few-layer boron nitride nanosheets (FBNNS) hybrids were synthesized via a one-step hydrothermal method. The structures, morphology, optical properties, electron transformation and separation of the as-prepared products were characterized by X-ray diffraction, transmission electrical microscopy, UV-vis diffuse reflectance spectroscopy and electrochemical impedance spectroscopy, respectively. Rhodamine B was used to evaluate the photocatalytic activities of the as-prepared samples under visible light illumination. The photocatalytic mechanism was also explored. Experimental results showed that the degradation efficiency of rhodamine B was firstly increased and then decreased with increasing the usage amount of FBNNS. When it was 9 wt% based on the weight of Zn2SnO4, the degradation efficiency of the as-prepared Zn2SnO4/FBNNS-9 wt% composites reached to the maximum of 97.5% in 180 min, which was higher than 39.2 % of pure Zn2SnO4. Moreover, the holes played mainly active roles in photocatalytic reaction process. In addition, the as-prepared hybrids could enhance the separation efficiency of photoexcited carriers compared to pure Zn2SnO4.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Tong H, Ouyang S, Bi Y, et al. Nanophotocatalytic Materials: Possibilities and Challenges[J]. Adv. Mater., 2012, 24(2): 229–251

    Article  Google Scholar 

  2. Zhou P, Yu J, Jaroniec M. All-Solid-State Z-Scheme Photocatalytic Systems[J]. Adv. Mater., 2014, 26(29): 4 920–4 935

    Article  Google Scholar 

  3. Yang M, Jin X Q. Visible Light-Induced Cr-Doped SrTiO3-g-C3N4 Composite for Improved Photocatalytic Performance[J]. J. Wuhan Univ. Technol.-Mater. Sci. Ed., 2014, 29(6): 1 111–1 116

    Article  Google Scholar 

  4. Wu X F, Zhang J, Sun Y, et al. Solvothermal Preparation of Zinc Oxide/Reduced Graphene Oxide Composites for Rapid Removal of Methylene Blue[J]. J. Nanosci. Nanotechno., 2017, 17(1): 517–523

    Article  Google Scholar 

  5. Wang Y, Zu X, Yi G, et al. Gap-Plasmon of Fe3O4@Ag Core-Shell Nanostructures for Highly Enhanced Fluorescence Detection of Rhodamine B[J]. J. Wuhan Univ. Technol.-Mater. Sci. Ed., 2017, 32(2): 264–271

    Article  Google Scholar 

  6. Zhang Z, Zhou C, Huang L, et al. Synthesis of Bismuth Sulfide/Reduced Graphene Oxide Composites and Their Electrochemical Properties for Lithium Ion Batteries[J]. Electrochim. Acta, 2013, 114: 88–94

    Article  Google Scholar 

  7. Wu X F, Li H, Sun Y, et al. One-Step Hydrothermal Synthesis of In2.77S4 Nanosheets with Efficient Photocatalytic Activity under Visible Light[J]. Appl. Phys. A-Mater., 2017 https://doi.org/10.1007/s00339-017-1016-0

  8. Jia Z M, Chen W, Liu T Y, et al. Biomolecule-Assisted Solvothermal Synthesis and Enhanced Visible Light Photocatalytic Performance of Bi2S3/BiOCl Composites[J]. J. Wuhan Univ. Technol.-Mater. Sci. Ed., 2016, 31(4): 765–772

    Article  Google Scholar 

  9. Mo Y P, F Chen, Y Y Yun, et al. Fabrication and Photocatalytic Activity of Ag3PO4-TiO2 Heterostructural Nanotube Arrays[J]. J. Wuhan Univ. Technol.-Mater. Sci. Ed., 2016, 31(2): 236–241

    Article  Google Scholar 

  10. Wu X F, Sun Y, Li H, et al. In-Situ Synthesis of Novel p-n Junction of Ag2CrO4-Bi2Sn2O7 Hybrids for Visible-Light-Driven Photocatalysis[J]. J. Alloy. Compd., 2018, 740: 1 197–1 203

    Article  Google Scholar 

  11. Georgekutty R, Seery M K, Pillai S C. A Highly Efficient Ag-ZnO Photocatalyst: Synthesis, Properties, and Mechanism[J]. J. Phys. Chem. C, 2008, 112(35): 13 563–13 570

    Article  Google Scholar 

  12. Zhao Q, Ju D, Song X, et al. Polyhedral Zn2SnO4: Synthesis, Enhanced Gas Sensing and Photocatalytic Performance[J]. Sensor. Actua. b-Chem., 2016, 1229: 627–634

    Article  Google Scholar 

  13. Zhao Y, Hu L, Liu H, et al. Band Gap Tunable Zn2SnO4 Nanocubes through Thermal Effect and Their Outstanding Ultraviolet Light Photoresponse[J]. Sci. Rep.-Uk, 2014, 4: 6 847–6 853

    Article  Google Scholar 

  14. Alpucheaviles M A, Wu Y. Photoelectrochemical Study of the Band Structure of Zn2SnO4 Prepared by the Hydrothermal Method[J]. J. Am. Chem. Soc., 2009, 131(9): 3 216–3 224

    Article  Google Scholar 

  15. Zhang L, Wang X, Nong Q, et al. Enhanced Visible-Light Photoactivity of g-C3N4 via Zn2SnO4 Modification[J]. Appl. Surf. Sci., 2015, 329: 143–149

    Article  Google Scholar 

  16. Sun Y, Wu X F, Zhang J, et al. Solvent-Mediated Preparation of Zinc Ferrite-Reduced Graphene Oxide Nanocomposites and Its Application in Removal of Methylene Blue[J]. J. Nanosci. Nanotechno., 2017, 17(4): 2 520–2 524

    Article  Google Scholar 

  17. Yan J, Gu J, Wang X, et al. Design of 3D WO3/h-BN Nanocomposites for Efficient Visible-Light-Driven Photocatalysis[J]. Rsc. Adv., 2017, 7(40): 25 160–25 170

    Article  Google Scholar 

  18. Li W, Wang Q, Huang L, et al. Synthesis and Characterization of BN/Bi2WO6 Composite Photocatalysts with Enhanced Visible-Light Photocatalytic Activity[J]. Rsc. Adv., 2015, 5(108): 88 832–88 840

    Article  Google Scholar 

  19. Song Y, Xu H, Wang C, et al. Graphene-Analogue Boron Nitride/Ag3PO4 Composite for Efficient Visible-Light-Driven Photocatalysis[J]. Rsc. Adv., 2014, 4(100): 56 853–56 862

    Article  Google Scholar 

  20. Choi J, Reddy D A, Kim T K. Enhanced Photocatalytic Activity and Anti-Photocorrosion of AgI Nanostructures by Coupling with Graphene-Analogue Boron Nitride Nanosheets[J]. Ceram. Int., 2015, 41(10): 13 793–13 803

    Article  Google Scholar 

  21. Wu X F, Li H, Su J Z, et al. Full Spectrum Responsive In2.77S4/WS2 P-N Heterojunction as an Efficient Photocatalyst for Cr(VI) Reduction and Tetracycline Oxidation[J]. Appl. Surf. Sci., 2019, 473: 992–1 001

    Article  Google Scholar 

  22. Wu X F, Zhao Z H, Sun Y, et al. Few-Layer Boron Nitride Nanosheets: Preparation, Characterization and Application in Epoxy Resin[J]. Ceram. Int., 2017, 43(2): 2 274–2 278

    Article  Google Scholar 

  23. Lv X, Wang J, Yan Z, et al. Design of 3D h-BN Architecture as Ag3VO4 Enhanced Photocatalysis Stabilizer and Promoter[J]. J. Mol. Catal. A-Chem., 2016, 418(419): 146–153

    Article  Google Scholar 

  24. Wu X F, Li H, Sun Y, et al. One-Sep Hydrothermal Synthesis of In2.77S4 Nanosheets with Efficient Photocatalytic Activity under Visible Light[J]. Appl. Phys. A-Mater., 2017 https://doi.org/10.1007/s00339-017-1016-0

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Xiangfeng Wu  (吴湘锋).

Additional information

Funded by Natural Science Foundation of Hebei Province, China (No. E2013210011)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, Y., Wu, X., Zhao, Z. et al. Hydrothermal Synthesis of Zn2SnO4/Few-Layer Boron Nitride Nanosheets Hybrids as a Visible-Light-Driven Photocatalyst. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 34, 563–567 (2019). https://doi.org/10.1007/s11595-019-2088-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11595-019-2088-9

Key words

Navigation