Abstract
Polytetrafluoroethylene (PTFE) is a commonly used seal material for oil-free engine that is well known for its excellent tribological properties. In this work, the nano-ZrO2 particles were used as the friction modifiers to improve the friction and wear performance of PTFE-PPS composites. The friction and wear characteristics of PTFE/PPS-nano-ZrO2 composites were investigated by a block-on-ring tester under dry friction sliding condition. The worn surfaces, counterpart transfer films and wear debris were studied by scanning electron microscopy and X-ray photoelectron spectroscopy. It was found that the increase of nano-ZrO2 content could effectively reduce the coefficient of friction and enhance the anti-wear ability of PTFE-PPS composites. Especially, the best tribological properties of the composites were obtained when the particle content of nano-ZrO2 was 10 vol%, the anti-wear performance of composite is 195 times better than that of the unfilled PTFE-PPS composite. Under different conditions, the coefficient of friction of PTFE/PPS-nano-ZrO2 composites was more affected by the applied load while the wear rate was more affected by the sliding velocity.
Similar content being viewed by others
References
Friedrich K, Lu Z, Hager A M. Recent Advances in Polymer Composites’ Tribology[J]. Wear, 1995, 190(2): 139–144
Zhang S W. State-of-the-art of Polymer Tribology[J]. Tribol. Int., 1998, 31(1): 49–60
Friedrich K, Chang L, Haupert F. Current and Future Applications of Polymer Composites in the Field of Tribology[M]. Composite Materials, London: Springer, 2011
Tanaka K, Uchiyama Y, Toyooka S. The Mechanism of Wear of Polytetrafluoroethylene[J]. Wear, 1973, 23(2): 153–172
Burris D L, Sawyer W G. A Low Friction and Ultra Low Wear Rate PEEK/PTFE Composite[J]. Wear, 2006, 261(3): 410–418
Cho M H, Bahadur S, Anderegg J W. Design of Experiments Approach to the Study of Tribological Performance of Cu-concentrate-filled PPS Composites[J]. Tribol. Int., 2006, 39(11): 1 436–1 446
Chen B, Wang J, Yan F. Microstructure of PTFE-based Polymer Blends and Their Tribological Behaviors under Aqueous Environment[J]. Tribol. Lett., 2012, 45(3): 387–395
Zuo Z, Song L, Yang Y. Tribological Behavior of Polyethersulfone-reinforced Polytetrafluoroethylene Composite under Dry Sliding Condition[J]. Tribol. Int., 2015, 86: 17–27
Li F, Hu K, Li J, et al. The Friction and Wear Characteristics of Nanometer ZnO Filled Polytetrafluoroethylene[J]. Wear, 2001, 249(10): 877–882
Sawyer W G, Freudenberg K D, Bhimaraj P, et al. A Study on the Friction and Wear Behavior of PTFE Filled with Alumina Nanoparticles[J]. Wear, 2003, 254(5): 573–580
Qiao H B, Guo Q, Tian A G, et al. A Study on Friction and Wear Characteristics of Nanometer Al2O3/PEEK Composites under the Dry Sliding Condition[J]. Tribol. Int., 2007, 40(1): 105–110
Su F H, Zhang Z Z, Liu W M. Tribological Behavior of Hybrid Glass/PTFE Fabric Composites with Phenolic Resin Binder and Nano-TiO2 Filler[J]. Wear, 2008, 264(7): 562–570
Su F H, Zhang Z, Liu W. Friction and Wear Behavior of Hybrid Glass/PTFE Fabric Composite Reinforced with Surface Modified Nanometer ZnO[J]. Wear, 2008, 265(3): 311–318
Beckford S, Wang Y A, Zou M. Wear-resistant PTFE/SiO2 Nanoparticle Composite Films[J]. Tribol. Trans., 2011, 54(6): 849–858
Wang Q, Xue Q, Liu H, et al. The Effect of Particle Size of Nanometer ZrO2 on the Tribological Behaviour of PEEK[J]. Wear, 1996, 198(1–2): 216–219
Wang J, Hu X G, Tian M, et al. Study on Mechanical and Tribological Property of Nanometer ZrO2-filled Polyoxymethylene Composites[J]. Polym-Plast. Technol., 2007, 46(5): 469–473
Song H J, Zhang Z Z. Investigation of the Tribological Properties of Polyfluo Wax/polyurethane Composite Coating Filled with Nano-SiC or Nano-ZrO2[J]. Mater. Sci. Eng., A, 2006, 426(1): 59–65
Wu Y, Zeng M, Jin H, et al. Effects of Glass-to-rubber Transition on the Friction Properties of ZrO2 Reinforced Polybenzoxazine Nanocomposites[J]. Tribol. Lett., 2012, 47(3): 389–398
Wu Y, Jin H, Hou S, et al. Effects of Glass-to-rubber Transition on the Temperature, Load and Speed Sensitivities of Nano-ZrO2 Reinforced Polybenzoxazine[J]. Wear, 2013, 297(1): 1 025–1 031
Wang Y, Gong J, Yang D, et al. Tribological Behavior of Nano-Al2O3-Reinforced PPS-PTFE Composites[J]. Tribol. Trans., 2014, 57(2): 173–181
Yu L, Yang S, Wang H, et al. An Investigation of the Friction and Wear Behaviors of Micrometer Copper particle- and Nanometer Copper Particle-filled Polyoxymethylene Composites[J]. J. Appl. Polym. Sci., 2000, 77(11): 2 404–2 410
Agag T, Koga T, Takeichi T. Studies on Thermal and Mechanical Properties of Polyimide-clay Nanocomposites[J]. Polymer, 2001, 42(8): 3 399–3 408
Zhao L, Zheng L, Zhao S. Tribological Performance of Nano-Al2O3 Reinforced Polyamide 6 Composites[J]. Mater. Lett., 2006, 60(21): 2 590–2 593
Author information
Authors and Affiliations
Corresponding authors
Additional information
Funded by the National Natural Science Foundation of China (Nos.51165022, 51675509)
Rights and permissions
About this article
Cite this article
Cao, W., Gong, J., Qi, Y. et al. Tribological Behavior of Nano-ZrO2 Reinforced PTFE-PPS Composites. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 34, 527–533 (2019). https://doi.org/10.1007/s11595-019-2083-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11595-019-2083-1