Abstract
The Cu-15Cr in-situ fiber-reinforced composites sheets were prepared by cold drawing combined with cold rolling process. The evolution process of Cr fibers was studied, and when cold rolling reduction ε = 95%, the morphology of Cr fiber at different annealing temperature and the thermal stability of Cu-15Cr alloy were studied. Microstructure was also studied by scanning electron microscopy (SEM). Meanwhile, the tensile strength of the alloy was tested by means of a precision universal tester, and the resistance value of the alloy was determined by using a digital micro-Euclidean instrument. The experimental results show that, with the increase of deformation, Cr dendrites evolve into homogeneous and parallelly arranged Cr fibers, and the cross-section of Cr fibers undergoes a "V" shape transition to "一" shape. In addition, spheroidization of the Cr fibers occurs on edges and extends to the center as annealing temperature rises. Moreover, the Cr fibers remains stable when the annealing temperature is below 550 °C. Furthermore, the tensile strength of Cu-15Cr alloy decreases gradually as the annealing temperature increases, while the electrical conductivity maximizes when annealing at 550 °C. Our study also shows that Cu-15Cr alloy has obtained a better comprehensive performance with tensile strength of 656 MPa and electrical conductivity of 82%IACS after annealing at 450 °C.
Similar content being viewed by others
References
Filgueria M, Pinatti DP. In situ Diamond Wires Part I. The Cu-15vol%Nb High Strength Cable[J]. Journal of Material Processing Technology, 2002, 128: 191–195
Vidal V, Thilly L, Van-Petegem S, et al. Plasticity of Nanostructured Cu-Nb-based Wires: Strengthening Mechanisms Revealed by In situ Deformation under Neutrons[J]. Scrpta Materialia, 2009, 60(3): 171–174
Liu JB, Zeng YW, Meng L. Crystal Structure and Morphology of a Rare-earth Compound in Cu-12wt% Ag[J]. Jounal of Alloys and Compounds, 2009, 468 (1-2): 73–76
Han K, Vasquez AA, Xin Y, et al. Microstructure and Tensile Properties of Nanostructured Cu-25wt%Ag[J]. Acta Materialia, 2003, 51: 767–780
Deng JQ, Zhang XQ, Shang SZ, et al. Effect of Zr Addition on the Microstructure and Properties of Cu-10Cr In situ Composites[J]. Materials and Design, 2009, 30: 4444–4449
SHI Kunyu, XUE Lihong, YAN Youwei, et al. Preparation and Arc Erosion Characteristics of Ultrafine Crystalline CuCr50 Alloy by MASPS[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2016, 31(5): 1081–1085
Spitzig W A, Chumbley L S, Verhoeven J D, et al. Effect of Temperature on the Strength and Conductivity of a Deformation Processed Cu-20%Fe Composite[J]. J. Mater. Sci., 1992, 27: 2005–2011
Chen XH, Liu P, Tian BH. Thermal Stability of Cr Fibers in Cu-Cr in-situ Composites[J]. The Chinese Journal of Nonferrous Metals, 2009, 19(2): 328–333
Bi Liming, Liu P, Chen XH, et al. Effect of Alloying and Intermediate Annealing on Microstructure and Properties of Cu-Cr Deformation Processed In situ Composites[J]. Rare Metal and Engineering, 2013, 42: 1085–1090
Sakai Y, Inoue K, Maeda H. New High-strength, High-conductivity Cu-Ag Alloy Sheets[J]. Acta Metallurgica et Materialia, 1995, 43(4): 1517–1522
Bi Liming, Liu Ping, Cheng Xiaohong, et al. Effect of Deformation Ways on Microstructure and Properties of Deformation-processed Cu-8.3Fe-1Ag in-situ Composites[J]. Transactions Of Materials And Heat Treatment, 2012, 33(3): 28–34
Hong SI, Hill MA, Sakai Y, et al. On the Stability of Cold Drawn, Twophase Wires[J]. Acta Metallurgica et Materialia, 1995, 43(9): 3313–3323
Sharma G, Ramanujan RV, Tiwari GP. Instability Mechanisms in Lamellar Microstructures[J]. Acta Materialia, 2000, 48(4): 875–889
Pang Y, Xia CD, Wang MP, et al. Effects of Zr and (Ni, Si) Additions on Properties and Microstructure of Cu-Cr Alloy[J]. Journal of Alloys and Compounds, 2014, 582: 786–792
Ning YT, Zhang XH, Zhang J. Stability of Heavy Deformed Cu-Ag Alloy In situ Fiber Composites[J]. The Chinese Journal of Nonferrous Metals, 2005, 4: 506–512
Jha SC, Delagi RG, Forster JA, et al. High-strength High-conductivity Cu-Nb Microcomposite Sheet Fabricatedvia Multiple Roll Bonding[J]. Metallurgical Transactions A, 1993, 24(1):15–20
Kampe JCM, Courtney TH, Leng Y. Shape Instabilities of Plate-like Structures-I. Experimental Observations in Heavily Cold Worked In situ Composites[J]. Acta Metallurgica, 1989, 37(7): 1735–1745
Whiting M, Tsakiropoulos P. Morphological Evolution of Lamellar Structures: The Cu-Al Eutectoid[J]. Acta Materialia, 1997, 45(5): 2027–2042
Hong SI, Hill MA. Microstructural Stability of Cu-Nb Microcomposite Wires Fabricated by the Bundling and Drawing Process[J]. Materials Science and Engineering A, 2000, 281(1/2): 189–197
Zhang Y, Chai Z, Volinsky A A, et al. Processing Maps for the Cu-Cr-Zr-Y Alloy Hot Deformation Behavior[J]. Materials Science & Engineering A, 2016, 662: 320–329
Shi KY, Xue LH, Yan YW, et al. Effects of Mechanical Alloying Parameters on the Microstructures of Nanocrystalline Cu-5wt% Cr Alloy[J]. Wuhan University of Tech. -Mat. Sci. Ed., 2013, 28(1): 192–195
Hong SI, Kim HS, Hill MA. Strength and Ductility of Heavily Drawn Bundled Cu-Nb Fiber Microcomposite Wires with Various Nb Contents[J]. Metallurgical and Materials Transactions A, 2000, 31(10): 2457–2462
Author information
Authors and Affiliations
Corresponding author
Additional information
Funded by the Key Project of the Ministry of Education of China(No.109061), the National Natural Science Foundation of China(No.10874118), and the “SMC Young Star” Scientist Program of Shanghai Jiao Tong University
Rights and permissions
About this article
Cite this article
Tian, W., Bi, L. & Du, J. Microstructure evolution and thermal stability of Cu -15Cr in -situ composites. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 33, 185–192 (2018). https://doi.org/10.1007/s11595-018-1804-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11595-018-1804-1