Abstract
In order to make clear the interaction mechanism of single component epoxy in cementitious environment, the interaction between epoxy resin and active silanol, epoxy resin and alkali was investigated From solid-state 13C NMR and FT-IR tests, it is confirmed that silanol group can initiate epoxy resin. Test results have also revealed that alkali as the dominant product of cement hydration can open the epoxide ring making epoxy harden.
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References
Sepideh Khoee, Narges Hassani. Adhesion Strength Improvement of Epoxy Resin Reinforced with Nanoelastomeric Copolymer[J]. Materials Science and Engineering: A, 2010, 527: 6562–6567
Deng Shuanghui, Zhou Xiaodong, Fan Chuanjie, et al. Release of Interfacial Thermal Stress and Accompanying Improvement of Interfacial Adhesion in Carbon Fiber Reinforced Epoxy Resin Composites: Induced by Diblock Copolymers[J]. Composites Part A: Applied Science and Manufacturing, 2012, 43: 990–996
Andrea Saccani, Vittorio Magnaghi. Durability of Epoxy Resin-Based Materials for the Repair of Damaged Cementitious Composites[J]. Cement and Concrete Research, 1999, 29: 95–98
Gulnare Ahmetli, Huseyin Deveci, Ulku Soydal, et al. Coating, Mechanical and Thermal Properties of Epoxy Toluene Oligomer Modified Epoxy Resin/Sepiolite Composites[J]. Progress in Organic Coatings, 2012, 75: 97–105
Muhammad Aamer, Rafique Bhutta. Effects of Polymer-cement Ratio and Accelerated Curing on Flexural Behavior of Hardener-free Epoxymodified Mortar Panels[J]. Materials and Structures, 2010, 43: 429–439
Ohama Y, Demura K, Uchiyama T. Weatherability of Polymer Modified Mortars after Ten-Year Outdoor Exposure in Koriyama and Sappro, Polymer in Concrete[C]. In: Proc. of the Second East Asia Symp on Polymer in Concrete, Koriyama, Japan, 1997
Ohama Y, Demura K, Endo T. Properties of Polymer-Modified Mortars Using Epoxy Resin without Hardener, Polymer-Modified Hydraulic-Cement Mixtures[R]. STP 1176, ASTM, Philadelphia, 1993
Jo YK. Development of Epoxy-Modified Mortar and Concrete without Hardener[D]. Japan: Nihon University; 1995 (in Japanese)
Jo YK, Soh YS. A Study on the Hardening of Epoxy Resin in Epoxy Modified Cementitious Composites[J]. J. Architect. Inst. Korea, 1996, 12:238–247 (in Korean)
Y K Jo. Basic Properties of Epoxy Cement Mortars without Hardener after Outdoor Exposure[J]. Construction and Building Materials, 2008, 22: 911–920
ZHU Jipeng, LI Zongjin, YANG Ruochong, et al. Organic Additive Implantation onto Cement Hydration Products[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2014(3): 527–533
ZHU Jipeng, LI Zongjin, YANG Ruochong, et al. Mutual Interaction Relationship in Polymer Modified Cementitious System[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2015(1): 122–128
Sabina Alessi, Alberto Spinella, Eugenio Caponetti, et al. Structural Investigation of E-Beam Cured Epoxy Resins Through Solid-state NMR[J]. Radiation Physics and Chemistry, 2012, 81: 1328–1331
Benard F, Campistro I, Laguerre A, et al. Influence of Silica Fillers During the Electron Irradiations of DGEBA/TETA Epoxy Resins, Part I: Study of the Chemical Modication on Model Compounds[J]. Polymer Degradation and Stability, 2006, 91: 2110–2118
Benard F, Buzare J Y, Campistron I, et al. Influence of Silica Fillers During the Electron Irradiation of DGEBA/TETA Epoxy Resins, Part III: Solid-state NMR Investigations[J]. Polymer Degradation and Stability, 2007, 92: 785–794
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Funded by the National Natural Science Founda-tion of China (No. 51578290)
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Zhu, J., Li, Z. & Zhang, Y. Initiation of single-part epoxy in cementitious system. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 31, 713–716 (2016). https://doi.org/10.1007/s11595-016-1434-4
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DOI: https://doi.org/10.1007/s11595-016-1434-4