Skip to main content
SpringerLink
Log in

Preparation and characterization of low density Poly (Imino Imino Ketone) foam

  • Organic Materials
  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

Poly(Imino Ketone) (PIK) is a group of novel high performance polymer material with excellent thermal properties and dissolubility. Aiming at the requirements of inertial confined fusion (ICF) studies on low density polymer foams, we firstly synthesized poly(imino imino ketone) (PIIK) by palladium catalyzed C-N cross-coupling reaction, and successfully prepared the PIIK foam material with a density of 80-300 mg/cm3 by using PIIK as the raw material with thermal-induced phase separation and lyophilization technique. Mercury injection method was used to determine the structure of PIIK foams, and the results indicated that the mean pore diameter was lower than 5 μm and it had relatively high voidage and specific surface area.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Huang P, Reinhall P G, Shen I Y. Use of Microcellular Foam Materials in Constrained Layer Damping Treatments[J]. Cell. Polym., 2001, 20: 101–114

    Google Scholar 

  2. Gromov A I, Borisenko N G, Guskov S Y. Fabrication and Monitoring of Advanced Low-density Medial for ICF Targets[J]. Laser Part. Beams., 1999, 17: 661–670

    Article  Google Scholar 

  3. Flory P J. Principles of Polymer Chemistry[M]. New York: Cornell University Press, 1953

    Google Scholar 

  4. Coudevile A, Eyharts P. Coating Laser Microspheres with Homogeneous Low Density Foams[J]. J. Vac. Sci. Technol., 1981, 18: 1227–1230

    Article  Google Scholar 

  5. Aubert J H, Clough R L, Curro J G. Low Density Microcellular Foams[P]. United States Patent., US 4673695, 1987

    Google Scholar 

  6. Ding M X. Isomeric Polyimides[J]. Prog. Polym. Sci., 2007, 32: 623–668

    Article  Google Scholar 

  7. Camilo I, Erik S, Thein K. Polyimide Foams from Powder: Experimental Analysis of Competitive Diffusion Phenomena[J]. Polymer, 2005, 46: 9296–9303

    Article  Google Scholar 

  8. Ayman S A, Markus K. Poly(imino ketone)s as New High-Performance Polymers[J]. Macromolecules, 2004, 37: 8269–8277

    Article  Google Scholar 

  9. Chang G J, Yang L, Yang J X, et al. Facile Synthesis of Heat-resistant and Photoluminescent Poly(N-aryleneindole ether)s via Catalyst-free C–N/C–O Coupling Reaction[J]. J. Polym. Sci., Part A: Polym. Chem., 2014, 52, 313–320

    Article  Google Scholar 

  10. Chang G J, Yang L, Yang J X, et al. Synthesis of Poly(imino imino ketone) (PIIK) and Preparation of Heat Resistant PIIK Foam[J]. Polymer, 2013, 54, 5043–5049

    Article  Google Scholar 

  11. Chang G J, Yang L, Liu S Y, et al. Synthesis of Indole-based Functional Polymers with Well-defined Structures via a Catalyst-free C-N Coupling Reaction[J]. Rsc. Adv., 2014, 4, 30630–30637

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry and Chemical Engineering, Mianyang Normal University, Mianyang, 621000, China

    Siman Liu  (刘思曼)

  2. State Key Laboratory Cultivation Base for Nonmetal Composite and Functional Materials & School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang, 621010, China

    Guanjun Chang  (常冠军)

  3. Key Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu, 610064, China

    Meiming Luo

Authors
  1. Siman Liu  (刘思曼)
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Guanjun Chang  (常冠军)
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Meiming Luo
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Guanjun Chang  (常冠军).

Additional information

Funded by the National Natural Science Foundation of China (No.11447215); Scientific Research Project of Mianyang Normal University (No.2013A02) and Research Fund of Education Department of Sichuan Province (No.13ZB0118)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liu, S., Chang, G. & Luo, M. Preparation and characterization of low density Poly (Imino Imino Ketone) foam. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 31, 700–704 (2016). https://doi.org/10.1007/s11595-016-1432-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11595-016-1432-6

Key words

Search

Navigation