Abstract
The inclusion complex of β-cyclodextrin (β-CD) and sulfurized isobutylene (T321) was prepared with a co-precipitation method. The tribological properties of the complex with different concentrations were investigated by a four-ball tester in the solution of polyethylene glycol-600 (PEG-600). The experimental results suggest that the complex exhibits better anti-friction and anti-wear properties than β-CD under different load conditions. The tribo-system shows the least friction coefficient when the concentration of the complex is 0.8%. During the friction process, the complex was decomposed into various molecular fragments and the T321 molecules were released onto the friction interface to provide effective lubrication. The XPS analytical results on the worn surfaces reveal that sulfide film formed by the released T321 plays a major role, and the iron alkoxide and carbon deposition films formed by the β-CD fragments have better anti-friction effect on the sulfide film surface. The interactions of different films result in the formation of a mixed boundary lubrication film.
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Szejtli J. Introduction and General Over View of Cyclodextrin Chemistry[J]. Chem. Rev., 1998, 98: 1 743–1 753
Hbaieb S, Kalfat R, Chevalier Y, et al. Influence of the Substitution of ß-cyclodextrins by Cationic Groups on the Complexation of Organic Anions[J]. Mater. Sci. Eng., C, 2008, 28: 697–704
Abou-Okeil A, Amr A, Abdel-Mohdy FA. Investigation of Silver Nanoparticles Synthesis Using Aminated ß-cyclodextrin [J]. Carbohydr. Polym., 2012, 89:1–6
Arun R, Ashok KC, Sravanthi VV. Cyclodextrins as Drug Carrier Molecule: A review[J]. Scripta Mater., 2008, 76: 567–598
Astray G, Gonzalez-Barreiro C, Mejuto JC, et al. A Review on the Use of Cyclodextrins in Foods[J]. Food Hydrocolloid, 2009, 23: 1 631–1 640
Lesilie RR. Lubricant Additives: Chemistry and Applications[M]. Taylor & Francis Group LLC, 2010, 150–156
Mortier RM, Fox MF, Orszulik ST. Chemistry and Technology of Lubricants [M]. Springer-Verlag, 2010, 15–30
Kamiyama T, Satoh M, Tateishi T, et al. Effects of Modified ß-cyclodextrin on Thermal Stability and Conformation of Lysozyme[J]. Thermochim. Acta, 2012, 20: 10–14
Su J, Chen J, Li L, et al. Formation of ß-cyclodextrin Inclusion Enhances the Stability and Aqueous Solubility of Natural Borneol[J]. J. Food Sci., 2012, 6: 658–664
Álvarez C, Calero J, Menéndez JC, et al. Effects of Hydroxypropylbeta- cyclodextrin on the Chemical Stability and the Aqueous Solubility of Thalidomide Enantiomers[J]. Int. J. Ph. Sci., 2008, 63: 511–513
Shin JS, Wei SF, Chin LT, et al. Polymer-based Self-lubricating Material [J]. J. Appl. Polym. Sci., 2001, 80: 1 514–1 519
Fusaro RL. Self-lubricating Polymer Composites and Polymer Transfer Film Lubrication for Space Applications[J]. Tribol. Int., 1990, 23: 105–122
Qi XW, Jia ZN, Yang YL. Influence of the Dispersion of Nano Titanium Dioxide on the Tribological Performance of Fabric Self-lubricating Liner[J]. J. Appl. Polym. Sci., 2013, Published online: 16, May
Forbes ES. The Load-carrying Action of Organo-sulphur Compounds-a Review[J]. Wear, 1970, 15: 87–96
Plaza S, Mazurkiewicz B, Gruzinski R. Thermal Decomposition of Dibenzyl Disulphide and Its Load-carrying Mechanism[J]. Wear, 1994, 174: 209–216
Xue QJ, Liu WM. Tribochemistry and the Development of AW and EP Oil Additive-a Review[J]. Lubr. Sci., 1994, 10: 81–92
Kajdas C. On a Negative-Ion Concept of EP Action of Organo-Sulfur Compounds[J]. ASLE Transactions, 1985, 28: 21–30
Lara J, Blunt T, Kotvis P, et al. The Surface Chemistry and Extremepressure Lubricant Properties of Dimethyl Disulfide[J]. J. Chem. Phys., 1998, B102: 1 703–1 709
Spikes HA. Additive and Additive-surface Interactions in Lubricants[J]. Lubr. Sci., 1989, 2:3–23
Gao F, Kotvis PV, Tysoe WT. The Surface and Tribological Chemistry of Chlorine- and Sulfur-containing Lubricant Additives[J]. Tribol. Int., 2004, 37: 87–92
Choudhary RB, Jha MK. Action mechanisms of Boundary Lubrication Additives - A Review, Part II[J]. Lubr. Sci., 2004, 17: 75–93
Bowden FP. The Friction and Lubrication of Solids[M]. Oxford University Press, 1950, 178–196
Beltzer M, Jahanmir S. Effect of Additive Molecular Structure on Friction[ J]. Lubr. Sci., 1998, 1: 3–26
Hu YH, Liu WM. Tribological Properties of Alcohols as Lubricating Additives for Aluminum-on-steel Contact[J]. Wear, 1998, 218: 244–249
Fischer DA, Hu ZS, Hsu SM. Tribochemical and Thermochemical Reactions of Stearic Acid on Copper Surfaces in Air as Measured by Ultrasoft X-ray Absorption Spectroscopy[J]. Tribol. Lett., 1997, 3: 35–40
Liviu EM, Daniela R, Vasile P. New Unsymmetrical Complex Diesters of Adipic Acid Considered as Tribological Fluids[J]. Lubr. Sci., 2010, 22: 341–354
Wu YX, Li WM, Zhang M, et al. Oxidative Degradation of Synthetic Ester and Its Influence on Tribological Behavior[J]. Tribol. Int., 2013, 64:16–23
Jimenez MC, Miranda MA, Tormos R. Photodecar Ylation of 2-phenylpropionic Acid in Solution and Included Within ß-cyclodextrin [J]. Tetrahedron, 1995, 51: 2 953–2 958
Schneider, H-J, Hacket F, Rudiger V. NMR Studies of Cyclodextrins and Cyclodextrin Complexes[J]. Chem. Rev., 1998, 98: 1 755–1 785
Pionto LM, Fraceto LF, Santana MH, et al. Physico-chemical Characterization of Benzocaine-beta-cyclodextrin Inclusion Complexes[J]. J. Pharm. Biomed. Anal., 2005, 39: 956–963
Fernandes CM, Teresa Vieira M, Veiga FJ. Physicochemical Characterization and in vitro Dissolution Behavior of Nicardipinecyclodextrins Inclusion Compounds[J]. J. Pharm. Sci., 2002, 15:79–88
Kaltchev M, Kotvis PV, Blunt TJ, et al. A Molecular Beam Study of the Tribological Chemistry of Dialkyl Disulfides[J]. Tribol. Lett., 2001, 10: 45–50
Briggs D. Surface analysis of polymers by XPS and static SIMS[M]. Cambridge University Press, London, 1998, 35–52
Hsu SM, Zhang J, Yin ZF. The Nature and Origin of Tribochemistry[J]. Tribol. Lett., 2002, 13: 131–139
Kajdas C. A Novel Approach to Tribochemical Reactions: Generalized NIRAM-HSAB Action Mechanism[C]. In: Proc. Int. Trib. Conf. Yokohama-Satellite Forum on Tribochemistry, 1995, 31–35
Kajdas C, Furey MJ, Ritter, et al. Triboemission as a Basic Part of the Boundary Friction Regime: A Review[J]. Lubr. Sci., 2002, 14: 223–254
Kajdas C. Importance of the Triboemission Process for Tribochemical Reaction[J]. Tribol. Int., 2005, 38: 337–353
Kajdas C. Importance of Anionic Reactive Intermediates for Lubricant Component Reactions with Friction Surfaces[J]. Lubr. Sci., 1994, 6: 203–228
Bowden FP, Moore AC. Physical and Chemical Adsorption of Long Chain Compounds on Radio Active Metals [J]. Transactions of the Faraday Society, 1951, 47: 900–908
Jahanmir S. Chain Length Effects in Boundary Lubrication[J]. Wear, 1985, 102: 331–349
Yi HL, Wu H, Zeng XQ, et al. X-ray Absorption Near-edge Structure Spectroscopy of Tribochemical/Thermal Films Generated from Serial Alkyl Polysulfides[J]. Acta Physica Sinica, 2006, 22: 1 473–1 477
Han N, Shui L, Liu WM, et al. Study of the Lubrication Mechanism of Olefin Sulfide[J]. Tribology, 2002, 22: 49–53
Buckley DH. Surface Effects in Adhesion, Friction, Wear, and Lubrication[M]. Elsevier Scientific Pub. Co., Amsterdam, 1981: 121–145
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Funded by the National Natural Science Foundation of China (No. 51075366)
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Guan, J., Xu, X., Hu, J. et al. Preparation and action mechanism of inclusion complex of β-cyclodextrin and sulfurized isobutylene as additives in solution of polyethylene glycol-600. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 30, 859–867 (2015). https://doi.org/10.1007/s11595-015-1237-z
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DOI: https://doi.org/10.1007/s11595-015-1237-z