Skip to main content
Log in

Effect of pre-deformation enhanced thermal aging on precipitation and microhardness of a reactor pressure vessel steel

  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

Microstructure evolution in neutron irradiated Reactor Pressure Vessel (RPV) steels was experimentally simulated through an improved degradation procedure in this study. The degradation procedure includes austenitizing at 1 150 °C and water quench, deformation 10% and 30% respectively, and then thermal aging at 500 °C for different period of time. The microstructure of the specimens was analyzed in details using transmission electron microscopy (TEM). The micro-hardness test results showed that all the hardness curves of undeformed, 10% pre-deformed and 30% pre-deformed specimens have two micro-hardness peaks with the first peak value corresponding to different thermal aging time of 1 hour, 5 hours and 10 hours, respectively. It was revealed that the hardness curves were influenced by the precipitation of Cu-rich precipitates (CRPs) and carbides, deposition of martensite and work hardening.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Reference

  1. Pareige P J, Russell K F, Miller M K. APFIM Studies of the Phase Transformations in Thermally Aged Ferritic FeCuNi Alloy: Comparison with Aging under Neutron Irradiation [J]. Applied Surface Science, 1996, 67: 362–369

    Article  Google Scholar 

  2. Pareige P J, Auger P, Bas P, et al. Direct Observation of Copper Precipitation in Neutron Irradia Ted Fe-Cu Alloys by 3D a Tomictom Ography[J]. Scripta Metal., 1995, 33: 1 033–1 036

    CAS  Google Scholar 

  3. Worrall G M, Buswell J T, English C A, et al. A Study of the Precipitation of Copper Particles in a Ferrite Matrix[J]. J. Nucl. Mater., 1987, 148: 107–114

    Article  CAS  Google Scholar 

  4. Auger P, Pareige P J, Akamatsu M. Microstructural Characterization of Atom Clusters in Irradiated Pressure Vessel Steels and Model Alloys [J]. J. Nucl. Mater., 1995, 225: 192–195

    Article  Google Scholar 

  5. Mathon M H, Barbu A. Experimental Study and Modeling of Copper Precipitation under Electron Irradiation in Dilute FeCu Binary Alloys [J]. J. Nucl. Mater., 1997, 245: 224–237

    Article  CAS  Google Scholar 

  6. Pareige P J, Miller M K. Characterisation of Neutron-induced Cuenriched Clusters in Nuclear Pressure Vessel Steel Weld: An APFIM Study[J]. Appl. Surf. Sci., 1996, 94/95: 370–377

    Article  CAS  Google Scholar 

  7. Miller M K, Russell K F, Pareige P, et al. Low Temperature Copper Solubilities in Fe-Cu-Ni[J]. Mater. Sci. Eng. A, 1998, 250: 47–51

    Google Scholar 

  8. Zhang Ruiqian, Hong Xiaofeng, Peng Qian. The Effect of Cu-rich Cluster on the Mechanical Properties of Reactor Pressure-Vessel Steels[J]. Nucl. Power. Eng., 2010, 31(1): 4–7

    Google Scholar 

  9. Yasuhiro Kamada, Seiki Takahashi, Hiroaki Kikuchi, et al. Effect of Pre-deformation on the Precipitation Process and Magnetic Properties of Fe-Cu Model Alloys[J]. J. Mater. Sci., 2009, 44: 949–953

    Article  CAS  Google Scholar 

  10. Krishnadev M R. Study of the Microstructure Basis for Strength and Toughness Properties of Water-quenched and Air-cooled HSLA-100 with Increased Copper, and a ULCB Steels[D]. California: Naval Postgraduate School, 1991

    Google Scholar 

  11. Pigrova G D. Kinetics of Carbide Reactions in Cr-Mo-V Steels[J]. Matal. Sci. Eng., 1996, 38(7–8): 320–324

    Google Scholar 

  12. Wu S J, Knott J F. Effects of Degradation on the Mechanical Properties and Fracture Toughness of a Steel Pressure-Vessel Weld Metal[J]. Int. J. Pres. Ves. Pip., 2003, 80: 807–815

    Article  CAS  Google Scholar 

  13. Ghosh A, Chatterjee S. Ageing Behavior of a Cu-bearing Ultrahigh Strength Steel[J]. Matal. Sci. Eng., 2008, 486(1):152–157

    Article  Google Scholar 

  14. Kimura Y, Takaki S. Effect of Cold Work on the Precipitation of Copper from Alpha-Iron[J]. ISIJ Inter., 1997, 37: 284–290

    Article  Google Scholar 

  15. Othen P J, Jenkins M L, Smith G, et al. Transmission Electron Microscope Investigations of the Structure of Copper Precipitates in Thermally-aged Fe-Cu and Fe-Cu-Ni[J]. Philosophical Magazine Letters, 1991, 64(6): 383–391

    Article  CAS  Google Scholar 

  16. ORIANI R A, SPEICH G R. The Rate of Coarsening of Copper Precipitate in an Alpha-iron Matrix[J]. Trans. Metall. Soc. AIME, 1965, 233(4):623–630

    Google Scholar 

  17. Zhang C, Enomoto M, Yamashita T, et al. Cu Precipitation in a Prestrained Fe-1.5 wt pct Cu Alloy During Isothermal Aging[J]. Metall. Mater. Trans. A, 2004, 35(4):1 263–1 272

    Google Scholar 

  18. Krishnadev M R. Development and Characterization of a New Family of Copper Containing HSLA Steels[J]. Tech. Appli. OH, 1984:128–130

    Google Scholar 

  19. Guen Chul Hwang. Effect of Direct Quenching on Microstructure and Mechanical Properties of Copper-bearing High-strength Alloy Steels[J]. Matal. Sci. Eng., 1998, A252: 256–268

    Article  CAS  Google Scholar 

  20. Tomita Y, Haze T, Saito N, et al. Development of 590-MPa Class High Tensile Strength Steel with Superior HAZ Toughness by Copper Precipitation Hardening[J]. ISIJ International, 1994, 34(10): 834–837

    Google Scholar 

  21. Baker R G, Nutting J. The Tempering of 2.25 Cr%-1% Mo Steel after Quenching and Normalizing[J]. J. Iron Steel Inst., 1959, 202:257–268

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Sujun Wu  (吴素君).

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wu, S., Liu, B., Cao, L. et al. Effect of pre-deformation enhanced thermal aging on precipitation and microhardness of a reactor pressure vessel steel. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 28, 592–597 (2013). https://doi.org/10.1007/s11595-013-0736-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11595-013-0736-z

Key words

Navigation