Abstract
Pitting corrosion of 316L stainless steel (316L SS) under various stress was studied by potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and Mott-Schottky (M-S) analysis in 3.5% NaCl solution. The results of polarization curves show that, with the increase of the stress, the pitting potentials and the passive current density markedly decrease fi rstly (180 MPa), and then increase greatly (200 MPa). The corresponding surface morphologies of the samples after the polarization test well correspond to the results. Mott-Schottky analysis proved the least Cl− adsorbed to the surface of passive fi lm with more positive fl at potential, indicating that a moderate stress could increase the pitting corrosion resistance of 316L SS in 3.5% NaCl solution.
Similar content being viewed by others
References
Vinoy TV, Shaikh H, Khatak HS, et al. Metallurgical Analysis of a Failed Containment Building Door Bellows of a Nuclear Reactor[J]. Practical Metallography, 1997, 34(10):527
Chen CL, Yang W. Effect of Ray Irradiation on SCC of Type 316 Stainless Steel in High Temperature Water [J]. Corros. Sci. Prot. Technol., 1997, 9(1): 1
Nishimura R, Maeda Y. SCC Evaluation of Type 304 and 316 Austenitic Stainless Steels in Acidic Chloride Solutions Using the Slow Strain Rate Technique[J]. Corro. Sci., 2004, 46:769
Khatak HS, Muraleedharan P, Gnanamoorthy JB, et al. Evaluation of the Stress Corrosion Resistance of Cold Rolled Aisi Type 316 Stainless Steel Using Constant Load and Slow Strain Rate Tests[J]. Mater., 1989, 168:157
Nishimura R. Characterization and Perspective of Stress Corrosion Cracking of Austenitic Stainless Steels (type 304 and type 316) in Acid Solutions Using Constant Load Method[J]. Corro. Sci., 2007, 49: 81
Anita T, Pujar MG, Shaikh H, et al. Assessment of Stress Corrosion Crack Initiation and Propagation in AISI Type 316 Stainless Steel by Electrochemical Noise Technique[J]. Corro. Sci., 2006, 48(9):2689
Cheng YF, Luo JL. Electronic Structure and Pitting Susceptibility of Passive Film on Carbon Steel[J]. Electrochim. Acta, 1999, 44: 2947
Liu Y, Meng GZ, Cheng YF. Electronic Structure and Pitting Behavior of 3003 Aluminum Alloy Passivated under Various Conditions[J]. Electrochim. Acta, 2009, 54:4155
Sikoral E, Ikora J, MacDonald DD. A New Method for Estimating the Diffusivities of Vacancies in Passive Films[J]. Electrochim. Acta., 1996, 41(6):783
Hakiki NE, Da Cunha Belo M, Simoes AMP, et al. Semiconducting Properties of Passive Films on Stainless Steels[J]. J. Electrochem. Soc., 1998, 145(11): 3821
Stimming U, Electrochim. Photoelectrochemical Studies of Passive Films[J]. Electrochim. Acta., 1986, 31(4):415
Schmuki P, Bohni H. Metastable Pitting and Semiconductive Properties of Passive Films[J]. J. Electrochem.Soc., 1992, 139(7):1908
Dong CF, Fu AQ, Li XG, et al. Localized EIS Characterization of Corrosion of Steel at Coating Defect under Cathodic Protection[J]. Electrochim. Acta., 2008, 54: 628
Cheng XQ, Li XG, Yang LX. Corrosion Resistance of 316L Stainless Steel in Acetic Acid by EIS and Mott-Schottky[J]. J. Wuhan Univ. Technol., 2008, 23(4):574
Meng GZ, Shao YW, Zhang T. Synthesis and Corrosion Property of Pure Ni with a High Density of Nanoscale Twins[J]. Electrochim. Acta., 2008, 53(20):5923
Vázquez G, Vázquez G, Sikora J, MacDonald DD, et al. Diffusivity of Anion Vacancies in WO3 Passive Films[J]. Electrochim. Acta., 2007, 52: 6771
Dewald JF. The Charge Distribution at the Zinc Oxide-electrolyte Interface[J]. J. Chem. Solid., 1960, 14(C):155
Wilson HW. A Model for the Current-voltage Curve of Photoexcited Semiconductor Electrodes[J]. J. Appl. Phys., 1977, 48: 4292
Macdonald DD. Point Defect Model for the Passive State[J]. J. Electrochem. Soc., 1992, 139(12): 3434
Macdonald DD. Passivity-the Key to Our Metals-based Civilization[J]. Pure Appl. Chem., 1999, 71(6): 951
Bockris JO’M, Khan SUM. Surface Electrochemistry: A Molecular Level Approach[M]. New York: Plenum Press, 1993:170, 179, 486
Author information
Authors and Affiliations
Corresponding author
Additional information
Funded by the National Natural Science Foundation of China(No.50871020)
Rights and permissions
About this article
Cite this article
Lü, S., Cheng, X. & Li, X. Pitting corrosion of 316L stainless steel under low stress below yield strength. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 27, 238–241 (2012). https://doi.org/10.1007/s11595-012-0444-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11595-012-0444-0