Skip to main content

Advertisement

Log in

Optimization of the content of tricalcium silicate of high cementing clinker

  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

Optimization of the content of tricalcium silicate (C3S) of high cementing clinker was investigated. The content of free-CaO(f-CaO), mineral composite, the content of C3S in the clinker and the hydration product were analyzed by chemical analysis and X-ray diffraction (XRD). “K Value” method of QXRD was selected as a quantitative analysis way to measure the content of C3S, and the strength of cement paste was determined. The results show that at a water cement ratio of 0.29, the strength of cement paste with 73% C3S can be up to 97.5 MPa at 28 days age. The strength at 28 d of cement with 73% C3S is 16% higher than that with 78% C3S at water requirement for normal consistency. The relationship between the strength of high cementing Portland cement and the content of C3S in the clinker is nonlinear. According to the strength of cement paste, the optimal content of C3S in cement clinker is around 73% in this paper.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. G H HOU, X D SHEN, Z Z XU. Composition Design for High C3S Cement Clinker and Its Mineral Formation[J]. J. Wuhan University of Technology-Mater. Sci. Ed., 2007,22(1): 56–60

    Article  CAS  Google Scholar 

  2. K Kolovos, S Tsivilis, G Kakali. The Effect of Foreign Ions on the Reactivity of the CaO-SiO2-Al2O3-Fe2O3 System: Part II: Cations[J]. Cement and Concrete Research, 2002,32(3):463–469

    Article  CAS  Google Scholar 

  3. A De la Torre, R De Vera, A Cuberos, et al. Crystal Structure of Low Magnesium-Content Alite: Application to Rietveld Quantitative Phase Analysis[J]. Cement and Concrete Research, 2008,38(11):1 261–1 269

    Google Scholar 

  4. A Barros, D Espinosa, J Tenorio. Effect of Cr2O3 and NiO Additions on the Phase Transformations at High Temperature in Portland Cement[J]. Cement and Concrete Research, 2004, 34(10): 1 795–1 801

    Article  CAS  Google Scholar 

  5. K You, S Cheon, J Ahn. The Effects of P2O5 on the Synthesis of Tri-, Di-calcium Silicates, Tricalcium Aluminate and Ferrite Phase[J]. Geosystems Engineering, 2004, 7(3): 69–74

    CAS  Google Scholar 

  6. K Kolovos, P Loutsi, S Tsivilis, et al. The Effect of Foreign Ions on the Reactivity of the CaO-SiO2-Al2O3-Fe2O3 System: Part I: Anions[J]. Cement and Concrete Research, 2001,31(3):425–429

    Article  CAS  Google Scholar 

  7. X CHENG, L C LU, L G WANG, et al. Study on Mineral System of Alite Calcium Barium Sulphoaluminate with Good Binding Characteristic[J]. Journal of Chinese Ceramic Society, 2004,32(3): 321–326

    CAS  Google Scholar 

  8. L CHEN, X D SHEN, S H MA, et al. Effect of Barium Oxide on the Formation and Coexistence of Tricalcium Silicate and Calcium Sulphoaluminate[J]. J. Wuhan University of Technology-Mater. Sci. Ed., 2009, 24(3):457–461

    Article  CAS  Google Scholar 

  9. L CHEN, X D SHEN, S H MA, et al. Effect of Manganese Dioxide on Burning of Clinkering of Cement Containing 3CaO·3Al2O3·CaSO4 Mineral[J]. Bulletin of the Chinese Ceramic Society, 2007(3):529–532

  10. S H MA, X D SHEN, X P GONG, et al. Influence of CuO on the Formation and Coexistence of 3CaO·SiO2 and 3CaO·3Al2O3·CaSO4 Minerals[J]. Cement and Concrete Research, 2006,36(9):1 784–1 787

    Article  CAS  Google Scholar 

  11. Y L GAO, S Q ZHOU. Influence of Ultra-fine Fly Ash on Hydration Shrinkage of Cement Paste[J]. Journal of Central South University (Science and Technology), 2005,12(5): 596–600

    Article  CAS  Google Scholar 

  12. R Aldous. The Hydraulic Behavior of Rhombohedral Alite[J]. Cement and Concrete Research, 1983(13): 89–96

  13. A De La Torre, S Bruque, J Campo, et al. The Superstructure of C3S from Synchrotron and Neutron Powder Diffraction and Its Role in Quantitative Phase Analyses[J]. Cement and Concrete Research, 2002,32(9): 1 347–1 356

    Google Scholar 

  14. M Ichikawa, M Kanaya. Effects of Components and Heating Rates on the Fine Texture of Alite in Cement Clinker[J]. Cement and Concrete Research, 1997(27):1 123–1 129

  15. K Masaki, I Maki. Effect of Prolonged Heating at Elevated Temperatures on the Phase Composition and Textures of Portland Cement Clinker[J]. Cement and Concrete Research, 2002,32(6): 931–934

    Article  CAS  Google Scholar 

  16. Stanek T, Sulovsky P. The Influence of the Alite Polymorphism on the Strength of the Portland Cement[J]. Cement and Concrete Research, 2002(32): 1 169–1 175

  17. Maki I, Haba H. Effect of Recrystallization on the Characters of Alite in Portland Cement Clinker[J]. Cement and Concrete Research, 1983(13): 689–695

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Xiaodong Shen  (沈晓冬).

Additional information

Funded by National Basic Research Program of China (No. 2009CB623100), National Eleventh Five-Year Scientific and Technical Support Plans (No.2006BAF02A24), Natural Science Fund for Colleges and Universities in Jiangsu Province(No.08KJB430006), Open Fund for the Key Laboratory of Inorganical and Composite Materials in Jiangsu Province(No. wjjqfhxc1200801) and Innovation Fund of Doctoral Dissertation of Nanjing University of Technology (No.BSCX200705)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chen, L., Shen, X., Ma, S. et al. Optimization of the content of tricalcium silicate of high cementing clinker. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 26, 578–582 (2011). https://doi.org/10.1007/s11595-011-0271-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11595-011-0271-8

Key words

Navigation