Abstract
Copper nitride (Cu3N) thin films were successfully deposited on glass substrates by reactive radio frequency magnetron sputtering. The effects of sputtering parameters on the structure and properties of the films were studied. The experimental results show that with increasing of RF power and nitrogen partial pressure, the preferential crystalline orientation of Cu3N film is changed from (111) to (100). With increasing of substrate temperature from 70 °C to 200 °C, the film phase is changed from Cu3N phase to Cu. With increasing sputtering power from 80 W to 120 W, the optical energy decreases from 1.85 eV to 1.41 eV while the electrical resistivity increases from 1.45 ×102 Ω · cm to 2.99 × 103 Ω · cm, respectively.
Similar content being viewed by others
References
T Maruyama, T Morishita. Copper Nitride and Tin Nitride Thin Films for Write-once Optical Recording Media[J]. Appl. Phys. Lett., 1996, 69(7): 890–891
M Asano, K Umeda and A Tasaki. Cu3N Thin Film for a New Light Recording Media[J]. Jpn. J. Appl. Phys., 1990, 29(10): 1985–1986
D M Borsa, D O Boerma. Growth, Structural and Optical Properties of Cu3N Films[J]. Surf. Sci., 2004, 548: 95–105
J Pierson, F D Horwat. Addition of Silver in Copper Nitride Films Deposited by Reactive Magnetron Sputtering[J]. Scripta Materialia, 2008, 58: 568–570
X Y Fan, Z G Wu, G A Zhang, et al. Ti-doped Copper Nitride Films Deposited by Cylindrical Magnetron Sputtering[ J]. J. Alloys and Compounds, 2007, 440: 254–258
U Hahn, W Weber. Electronic Structure and Chemical-bonding Mechanism of Cu3N, Cu3NPd, and Related Cu.I. Compounds.[J]. Phys. Rev. B, 1996, 53(19): 12684–12693
M G Moreno-Armenta, A Martínez-Ruiz. Ab Initio Total Energy Ealculations of Copper Nitride: the Effect of Lattice Parameters and Cu Content in the Electronic Properties[J]. Solid State Sciences, 2004, 6: 9–14
L Maya. Deposition of Crystalline Binary Nitride Films of Titanium, Copper, and Nickel by Reactive Sputtering[J]. J. Vac. Sci. Technol. A, 1993, 11(3): 604–608
T Nosaka, M Yoshitake, A Okamoto, et al. Copper Nitride Thin Films Prepared by Reactive Radio-frequency Magnetron Sputtering[J]. Thin Solid Films, 1999, 348: 8–13
K J Kim, J H Kim, J H Kang. Structural and Optical Characterization of Cu3N Films Prepared by Reactive RF Magnetron Sputtering[J]. J. Cryst. Growth, 2001, 222: 767–772
J Tauc, R Grigorovici, A Vancu. Optical Properties and Electronic Structure of Amorphous Germanium[J]. Phys. State. Sol., 1966, 15: 627–637
Author information
Authors and Affiliations
Corresponding author
Additional information
Funded by the National Natural Science Foundation of China (No. 60571010)
Rights and permissions
About this article
Cite this article
Qian, X., Huang, Z., Cui, Z. et al. Effect of the sputtering parameters on the structure and properties of Cu3N thin film materials. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 25, 935–937 (2010). https://doi.org/10.1007/s11595-010-0123-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11595-010-0123-y