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Self-cementing mechanism of CFBC coal ashes at early ages

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Abstract

The self-cementing mechanism at early ages of circulating fluidized bed combustion (CFBC) coal ashes was studied by X-ray diffraction (XRD), infrared (IR) spectroscopy and chemical method. The results indicate that the amorphous phase is predominant in CFBC coal ashes. The polymerization degree of [SiO4] and [AlO6] of CFBC desulphurization coal ashes is lower than that of those without desulphurization. The contents of the components with fast hydration rate of CFBC desulphurization coal ashes are significantly greater than those of the ashes without desulphurization. This work confirms that the amorphous minerals with high chemical activity are the main causes of the self-cementing property of CFBC desulphurization coal ashes at early ages.

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References

  1. Odler I, Zysk K H. Hydraulic Properties of Fluidized Bed Combustion Ashes[J]. Mater. Res. Soc. Symp. Proc., 1990, 178: 169–196

    Google Scholar 

  2. Wang Z. Study on Properties and Utilization in Building Materials of Bottom Ashes from Circulating Fluidized Bed Combustion[D]. Chongqing: Chongqing University, 2002: 49–51

    Google Scholar 

  3. Iribarne J, Iribarne A, Blondin J, et al. Hydration of Combustion Ashes-A Chemical and Physical Study[J]. Fuel, 2001, 80(6): 773–784

    Article  CAS  Google Scholar 

  4. Wu Y H, Anthony E J, Jia L F. Steam Hydration of CFBC Ash and the Effect of Hydration Conditions on Reactivation[J]. Fuel, 2004, 83(10):1 357–1 370

    Article  CAS  Google Scholar 

  5. Guan J S. The Pozzolanic Activity of Coal Ashes[J]. J. Chin. Ceram. Soc., 1980, 8(4):425–429

    CAS  Google Scholar 

  6. Spears D A. Role of Clay Minerals in UK Coal Combustion[J]. Applied Clay Science, 2000, 16(1–2):87–95

    Article  CAS  Google Scholar 

  7. Lecuyer I, Bicocchi S, Ausset P. Physico-chemical Characterization and Leaching of Desulphurization Coal Fly Ash[J]. Waste. Manage. Res., 1996, 14(1):15–28

    CAS  Google Scholar 

  8. Zhou J H, Cheng J, Cao X Y, et al. Experimental Research on Two-ages Desulfurization Technology in Traveling Grate Boilers[J]. Energy, 2001, 26(8):759–774

    Article  CAS  Google Scholar 

  9. Sheng C D, Xu M H, Zhang J, et al. Comparison of Sulphur Retention by Coal Ash in Different Types of Combustors [J]. Fuel Processing Technology, 2000, 64(1–3):1–11

    Article  CAS  Google Scholar 

  10. Peng W S, Liu G k. Infrared Spectra of Minerals[M]. Beijing: Science Press, 1982:11–12

    Google Scholar 

  11. State Technique Administration. Quantitative Measurement of Cement Composition (S). China Standard, GB/T 12960-1996, 1996

Download references

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Correspondence to Jueshi Qian  (钱觉时).

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Funded by the National Natural Science Foundation of China (No. 50572127)

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Song, Y., Qian, J., Wang, Z. et al. Self-cementing mechanism of CFBC coal ashes at early ages. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 23, 338–341 (2008). https://doi.org/10.1007/s11595-007-3338-9

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  • DOI: https://doi.org/10.1007/s11595-007-3338-9

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