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Constructing a potential electrocatalyst: highly multi-porous Co3O4 nanostructures to enhance electrocatalytic oxygen evolution reactions

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Abstract

In order to advance sustainable energy technologies like fuel cells and metal-air batteries, it is crucial to use an electrocatalyst that is very efficient for the process of oxygen evolution. The production of Co3O4 nanostructures led to the creation of a multiporous nanostructure. The research used an approach that utilised a simple, cost-effective, and low-temperature synthesis procedure. The catalytic activity of Co3O4 nanostructures, which have a high degree of porosity and include mesoporous nanostructures, was shown to be substantial. The catalyst has the ability to enhance the highly reactive oxygen reactions at the anode, hence increasing the combined effect of charge transfer at the interface and the porous structure of Co3O4 nanostructures. The results of this study demonstrate that Co3O4 nanostructures exhibit a significant overpotential value of 321 mV at 10 mA/cm2, a Tafel slope of 72 mV Dec−1, and excellent stability when used as electrocatalysts for the oxygen evolution process (OER) in real-world situations.

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Acknowledgements

AM acknowledges the Tatung University and S K Porwal College, Nagpur, India. The authors are also grateful to the instrument facility of SAIF Kochin, Kerala, India. The authors would like to thank the Researchers Supporting Project number (RSPD2024R1041), King Saud University, Riyadh, Saudi Arabia, for the financial support.

Funding

This project was financially supported by the Researchers Supporting Project (RSPD2024R1041), King Saud University, Riyadh, Saudi Arabia.

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Authors and Affiliations

  1. Department of Chemistry, Government College of Engineering, Sengi Patti, Thanjavur, Tamil Nadu, 613402, India

    S. A. T. Shanmugapriya

  2. Mechanical Engineering Department, IIMT College of Engineering, Greater Noida, Delhi, 201310, India

    Anand Prakash Singh

  3. Post Graduate Department of Chemistry, Seth Kesarimal Porwal College of Arts, And Science and Commerce, Kamptee, 441001, India

    Ratiram Gomaji Chaudhary, Sudip Mondal, Pranali Hadole & Aniruddha Mondal

  4. Department of Physics and Astronomy, College of Science, King Saud University, 11451, Riyadh, Saudi Arabia

    Amanullah Fatehmulla

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Contributions

Dr. Aniruddha Mondal implemented the Original draft preparation/Data curation/Investigation/Validation/Formal analysis Dr. S A T Shanmugapriya and Aniruddha Mondal wrote the initial manuscript. Dr Amanullah Fatehmulla, Pranali Hadole, and Dr. Aniruddha Mondal have analysed the XPS and electrochemical experiment and analysis Dr. Anand Prakash Singh, Ratiram Gomaji Chaudhary, Dr. Sudip Mondal, Dr. Amanullah Fatehmulla, and Pranali Hadole has done Visualization/Reviewing and Editing

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Correspondence to Aniruddha Mondal.

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Shanmugapriya, S.A.T., Singh, A.P., Chaudhary, R.G. et al. Constructing a potential electrocatalyst: highly multi-porous Co3O4 nanostructures to enhance electrocatalytic oxygen evolution reactions. Ionics (2024). https://doi.org/10.1007/s11581-024-05576-4

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