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FTIR vibrational and 13C NMR spectroscopic study of the effect on ionic transport behavior of NaClO4 in N,N-dimethylacetamide and its binary mixtures with 2-aminoethanol

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Abstract

This study explores the vibrational and nuclear magnetic resonance spectra of free ions as well as those coordinated with sodium ions, which are commonly utilized to study ion-ion and ion-solvent interactions in electrolytic solutions of dipolar aprotic solvents. The spectral investigations suggested the origin of new bands due to solvent shell of sodium ions. The ion-solvent interactions were confirmed by the carbonyl symmetric stretch ring deformation bands in N,N-dimethylacetamide. The probability of new contact ion pairs between sodium and perchlorate ions with N,N-dimethylacetamide (DMA) increases on enhancing the increase in electrolytic concentration of sodium perchlorate in binary solvent mixtures. FTIR vibrational spectra and 13C-NMR spectra of several electrolytic concentration solutions of sodium perchlorate (NaClO4) were studied in pure DMA and its binary mixture with 2-aminoethanol (AE). The study investigates the vibrational spectra of free ions as well as those coordinated with Na+ ions, which are widely used to study ion-ion and ion-solvent interactions in electrolytic solutions of dipolar aprotic solvents. The solutions of the salt at different concentrations were prepared in the molar ratio of NaClO4/AE/DMA (4:4:4) from 0.25 to 1.0 m. The vibrational spectroscopic and 13C-NMR studies suggested the origin of new bands due to solvent shell of Na+ ions, which is due to O=C–N deformation behavior. The study revealed that the Na+ ions interacted through the coordinate bond to both N-atom of NH4+ structure as well as oxygen atom of the C=O (carbonyl group) of amide. The interaction between Na+ ions and solvent suggests preferential solvated by DMA in the binary solvent mixtures. The ion-solvent interactions were confirmed by the carbonyl symmetric stretch ring deformation bands in DMA. The new contact ion-pairs between Na+ and ClO4− ions are more probable with increase in the concentration of sodium perchlorate in binary solvent mixtures.

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Acknowledgements

Mr. Suresh Kumar is thankful to the Department of Chemistry, Kurukshetra University, Kurukshetra (Haryana), for conducting the IR and NMR spectroscopy research work.

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  1. Department of Chemistry, Kurukshetra University, Kurukshetra, 136119, India

    Suresh Kumar & Hardeep Anand

  2. Markanda National College, Shahabad Markanda, Kurukshetra, 136135, India

    Suresh Kumar

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Kumar, S., Anand, H. FTIR vibrational and 13C NMR spectroscopic study of the effect on ionic transport behavior of NaClO4 in N,N-dimethylacetamide and its binary mixtures with 2-aminoethanol. Ionics 29, 3143–3154 (2023). https://doi.org/10.1007/s11581-023-05069-w

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