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Development of rutin sensor based on graphene quantum dots@nano-carbon ionic liquid electrode

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Abstract

A graphene quantum dots@nano-carbon ionic liquid electrode was prepared (GQDs@nano-CILE) to detect rutin sensitively. The graphene quantum dots were characterized by transmission electron microscopy (TEM) and infrared spectroscopy (IR). The surface morphology of the modified electrode was studied by scanning electron microscope (SEM). Cyclic voltammetry (CV) was used to investigate the electrochemical properties and the effective surface area of the modified electrodes. The effects of solution pH value, accumulation potential, and time on peak current were also discussed. Compared with nano-carbon paste electrode (nano-CPE), the peak current of rutin on GQDs@nano-CILE increased significantly using differential pulse voltammetry (DPV). The linear range of rutin ranging from 5 × 10−9 to 1 × 10−5 mol L−1 was obtained under the optimized conditions. The detection limit was 2 × 10−9 mol L−1 (S/N = 3). The modified electrode could be used for rutin analysis in rutin tablets and urine samples, and the recovery was between 95.2 and 101.4%.

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Funding

This research was supported by the Natural Science Foundation of Ningxia, China (No. 2022AAC03147).

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Authors and Affiliations

  1. School of Basic Medical Sciences, Ningxia Medical University, Yinchuan, 750004, People’s Republic of China

    Xinsheng Liu

  2. School of Public Health, Ningxia Medical University, Yinchuan, 750004, People’s Republic of China

    Wenli Qiao, Mengjun Chang, Yan Wang & Yonghong Li

  3. Key Laboratory of Environmental Factors and Chronic Disease Control, Yinchuan, 750004, People’s Republic of China

    Yonghong Li

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  1. Xinsheng Liu
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  2. Wenli Qiao
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  3. Mengjun Chang
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  4. Yan Wang
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  5. Yonghong Li
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Contributions

Xinsheng Liu: visualization, writing—original draft preparation; Wenli Qiao: methodology, software, validation; Mengjun Chang: visualization, investigation; Yan Wang: software and editing, investigation; Yonghong Li: writing—reviewing, supervision.

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Correspondence to Yonghong Li.

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Liu, X., Qiao, W., Chang, M. et al. Development of rutin sensor based on graphene quantum dots@nano-carbon ionic liquid electrode. Ionics 29, 3385–3392 (2023). https://doi.org/10.1007/s11581-023-04993-1

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  • DOI: https://doi.org/10.1007/s11581-023-04993-1

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